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t-BuBrettPhos Palladacycle Gen. 3

t-BuBrettPhos Palladacycle Gen. 3 Structure
  • ₹5783.1 - ₹85403.4
  • Product name: t-BuBrettPhos Palladacycle Gen. 3
  • CAS: 1536473-72-9
  • MF: C44H63NO5PPdS-
  • MW: 855.433481
  • EINECS:-0
  • MDL Number:MFCD25976528
  • Synonyms:Methanesulfonato 2-Di-t-butylphosphino-3,6-dimethoxy-2'-4' -6'-tri-i-propyl-1,1'-bipheny)(2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98%;METHANESULFONATO(2-(DI-T-BUTYLPHOSPHINO)-3,6-DIMETHOXY-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),DICHLOROMETHANEADDUCT,MIN.98%[T-BUBRETTPHOSPALLADACYCLEGEN.3];t-BuBrettPhos Palladacycle Gen. 3;Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II),[t-BuBrettPhos Palladacycle Gen. 3];Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), dichloromethane adduct, min. 98%[t-BuBrettPhos Palladacycle Gen.;Methanesulfonato[2-(di-t-butylphosphino)-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl](2’-amino-1,1’-biphenyl-2-yl)palladium(II);[2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC][[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]bis(1,1-dimethyle
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  • Sigma-Aldrich(India)

Package

  • 100MG
  • 500MG
  • 1G
  • 2G
  • 5G
  • ManufacturerSigma-Aldrich(India)
  • Product number745979
  • Product descriptiontBuBrettPhos Pd G3 96%
  • Packaging100MG
  • Price₹5783.1
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number745979
  • Product descriptiontBuBrettPhos Pd G3 96%
  • Packaging500MG
  • Price₹14818.5
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number745979
  • Product descriptiontBuBrettPhos Pd G3 96%
  • Packaging1G
  • Price₹34570
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number745979
  • Product descriptiontBuBrettPhos Pd G3 96%
  • Packaging2G
  • Price₹41935.8
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number745979
  • Product descriptiontBuBrettPhos Pd G3 96%
  • Packaging5G
  • Price₹85403.4
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 745979 tBuBrettPhos Pd G3 96% 100MG ₹5783.1 2022-06-14 Buy
Sigma-Aldrich(India) 745979 tBuBrettPhos Pd G3 96% 500MG ₹14818.5 2022-06-14 Buy
Sigma-Aldrich(India) 745979 tBuBrettPhos Pd G3 96% 1G ₹34570 2022-06-14 Buy
Sigma-Aldrich(India) 745979 tBuBrettPhos Pd G3 96% 2G ₹41935.8 2022-06-14 Buy
Sigma-Aldrich(India) 745979 tBuBrettPhos Pd G3 96% 5G ₹85403.4 2022-06-14 Buy

Properties

Melting point :119-131°C
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
form :solid
color :brown-green
InChIKey :VKLHIPFGYVFUGT-UHFFFAOYSA-N
CAS DataBase Reference :1536473-72-9

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
Precautionary statements:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P405 Store locked up.
P501 Dispose of contents/container to..…

Description

tBuBrettPhos Pd G3 has been used as a precatalyst for the N-arylation of amino acid esters with aryl triflates under mild reaction conditions and minimal racemization of the amino acid ester. It may also be used to catalyze the conversion of aryl halides to phenols in the presence of benzaldoxime as a hydroxide surrogate.

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