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BrettPhos Pd G3

BrettPhos Pd G3 Structure
  • ₹11521.8 - ₹125130.3
  • Product name: BrettPhos Pd G3
  • CAS: 1470372-59-8
  • MF: C48H66NO5PPdS
  • MW: 906.51
  • EINECS:
  • MDL Number:MFCD22572666
  • Synonyms:Methanesulfonato2-Dicyclohexylphosphino-3,6-dimethoxy-2'-4' -6'-tri-i-propyl-1,1'-bipheny)(2'-amino-1,1'-biphenyl-2-yl)palladium(II);BrettPhos Pd G3 95%;[2'-(Amino)[1,1'-biphenyl]-2-yl][dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine](methanesulfonato)palladium;Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladiu;[2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP](methanesulfonato-κO)palladium;Methanesulfonato(2-dicyclohexylphosphino-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% [BrettPhos Palladacycle];Methanesulfonato(2-dicyclohexylphosphino-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98%;BrettPhos Pd G3
Price4 Properties Safety Information Description
4 prices
Selected condition：

Brand

  • Sigma-Aldrich(India)

Package

  • 250MG
  • 1G
  • 5G
  • 10G
  • ManufacturerSigma-Aldrich(India)
  • Product number761605
  • Product descriptionBrettPhos Pd G3 98%
  • Packaging250MG
  • Price₹11521.8
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number761605
  • Product descriptionBrettPhos Pd G3 98%
  • Packaging1G
  • Price₹26300
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number761605
  • Product descriptionBrettPhos Pd G3 98%
  • Packaging5G
  • Price₹78699
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number761605
  • Product descriptionBrettPhos Pd G3 98%
  • Packaging10G
  • Price₹125130.3
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 761605 BrettPhos Pd G3 98% 250MG ₹11521.8 2022-06-14 Buy
Sigma-Aldrich(India) 761605 BrettPhos Pd G3 98% 1G ₹26300 2022-06-14 Buy
Sigma-Aldrich(India) 761605 BrettPhos Pd G3 98% 5G ₹78699 2022-06-14 Buy
Sigma-Aldrich(India) 761605 BrettPhos Pd G3 98% 10G ₹125130.3 2022-06-14 Buy

Properties

Melting point :150-193°C (decomposition)
storage temp. :under inert gas (nitrogen or Argon) at 2–8 °C
form :Powder
color :yellow to beige
InChIKey :ASZHREKEHVNFFW-UHFFFAOYSA-N
SMILES :P(C1CCCCC1)(C1CCCCC1)(C1C(=CC=C(OC)C=1C1C(=CC(C(C)C)=CC=1C(C)C)C(C)C)OC)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[O-]S(=O)(=O)C

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Description

BrettPhos Pd G3 may be used for the C-N coupling reaction between monosubstituted ureas and 1,2 dihaloaromatic system to form benzimidazolones.
It may be used in the synthesis of following compounds:
  • [Pd(cinnamyl)(BrettPhos)]OTf by reacting with [(cinnamyl)PdCl]2 and AgOTf.
  • [Pd(crotyl)(BrettPhos)]OTf by reacting with [(crotyl)PdCl]2 and AgOTf.
  • [Pd(allyl)(BrettPhos)]OTf by reacting with [(allyl)PdCl]2 and AgOTf.
  • Pd(allyl)(BrettPhos)Cl by reacting with [(allyl)PdCl]2.

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BrettPhos Pd G3
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BrettPhos Pd G3 CAS:1470372-59-8
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