1,1'-FERROCENEDICARBOXYLIC ACID

1,1'-FERROCENEDICARBOXYLIC ACID Structure
CAS No.
1293-87-4
Chemical Name:
1,1'-FERROCENEDICARBOXYLIC ACID
Synonyms
DK7513;1,1'-DICARBOXYFERROCENE;1,1'-Dicarboxyferrocene;1,1'-FerrocenedicarboxyL;1,1′-Biscarboxylferrocene;Ferrocene, 1,1'-dicarboxy-;1,1'-FERROCENDICARBONSAEURE;Ferrocene dicarboxylic acid;1,1-Ferrpemedocarboxylic Acid;1,1-Ferrocnedocarboxylic Acid
CBNumber:
CB1411720
Molecular Formula:
C12H10FeO410*
Molecular Weight:
274.05
MOL File:
1293-87-4.mol
MSDS File:
SDS
Modify Date:
2023/4/23 13:52:06

1,1'-FERROCENEDICARBOXYLIC ACID Properties

Melting point ≥300 °C(lit.)
storage temp. Inert atmosphere,Room Temperature
solubility DMSO, Ethyl Acetate (Very Slightly, Heated, Sonicated)
form crystal
color orange
Water Solubility Insoluble
Exposure limits ACGIH: TWA 1 mg/m3
NIOSH: TWA 1 mg/m3
Stability Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference 1293-87-4
NIST Chemistry Reference 1,1'-Ferrocenedicarboxylic acid(1293-87-4)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P305+P351+P338
Hazard Codes  Xi,Xn
Risk Statements  36/37/38-22
Safety Statements  26-36-37/39
WGK Germany  3
HS Code  29319090
NFPA 704
0
2 0

1,1'-FERROCENEDICARBOXYLIC ACID Chemical Properties,Uses,Production

Chemical Properties

dark brown powder

Uses

Reactant for preparation of:

  • Planar chiral ferrocene-based amido-phosphine ligands as catalysts for asymmetric allylic alkylation reactions
  • Potential antitumor agents
  • Isostructural ferrocenyl coordination polymer hollow microspheres with H2 storage properties
  • Prganometallic aromatic polyesters
  • Manganese-lanthanide-ferrocene clusters

Purification Methods

It crystallises in orange-yellow crystals from AcOH and sublimes above 230o. The monomethyl ester has m 147-149o [Nesmeyanov & Reutov Dokl Acad Nauk USSS 115 518 1957]. The dimethyl ester has m 114-115o [Woodward et al. J Am Chem Soc 74, 3458 1953]. The diacid chloride has m 92-93o when recrystallised from pet ether. [Nesmeyanov & Reutov Dokl Acad Nauk SSSR 120 1267 1958, Kazitsyna et al. Dokl Acad Nauk SSSR 127 333 1959, Beilstein 16 IV 1811.]

1,1'-FERROCENEDICARBOXYLIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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1,1'-FERROCENEDICARBOXYLIC ACID 1,1'-DICARBOXYFERROCENE 1,1-Ferrocnedocarboxylic Acid 1,1-Ferrpemedocarboxylic Acid FERROCENE-1,1'-DICARBOXYLIC ACID BIS(CARBOXYCYCLOPENTADIENYL)IRON Ferrocene dicarboxylic acid Ferrocene, 1,1'-dicarboxy- 1,1'-FERROCENDICARBONSAEURE 1,1'-Ferrocenedicarboxylicacid,min.96% 1,1''-FERROCENE DICARBOXYLIC ACID, MIN. 96% 1,1'-Ferrocenedicarboxylic acid, 96+% Bis(carboxycyclopentadienyl) Iron 1,1'-Dicarboxyferrocene 1,1'- twocarboxyltwoferrocene 1,1′-Biscarboxylferrocene 1,1′-Ferrocenedicarboxylic acid, >=98% 1,1'-FerrocenediCarbocylic acid 1,1'-Ferrocenedicarboxylic acid ,97% 1,1′-Ferrocenedicarboxylic acid 96% 1,1'-FerrocenedicarboxyL 1,1'-FerrocenedicarboxylicAcid> DK7513 1,1'-Ferrocenedicarboxylic Acid 1,1'-Dicarboxyferrocene 1293-87-4 1293-48-1 HOOCC5H42Fe C12H10FeO4 2C6H5O2Fe Catalysis and Inorganic Chemistry Ferrocenes Fe (Iron) Compounds Transition Metal Compounds Metallocenes Classes of Metal Compounds Classes of Metal Compounds Fe (Iron) Compounds Ferrocenes Metallocenes Transition Metal Compounds Miscellaneous Catalysis and Inorganic Chemistry Chemical Synthesis Industrial/Fine Chemicals