(+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE

(+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE Structure
CAS No.
824395-67-7
Chemical Name:
(+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE
Synonyms
(S,S)-Ph-BPE;(S,S)-Ph-BPE,BPE;1,2-Bis((2S,5S)-2,5-diphenylphospholan-1-yl)ethane;(+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE;(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane;1,2-Bis[(2S,5S)-2,5-diphenyl-1-phospholanyl]ethane;1,2-Bis[(2S,5S)-2,5-diphenyl-1-phospholanyl]ethane, 97+%;(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane, min. 98%;(2S,5S,2'S,5'S)-1,1'-ethane-1,2-diylbis(2,5-diphenylphosphol...;(2S,5S,2'S,5'S)-1,1'-ethane-1,2-diylbis(2,5-diphenylphospholane)
CBNumber:
CB2128267
Molecular Formula:
C34H36P2
Molecular Weight:
506.61
MOL File:
824395-67-7.mol
MSDS File:
SDS
Modify Date:
2023/9/1 17:37:15

(+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE Properties

Melting point 143-147 °C
alpha +182.7° (c 1.0, CH2Cl2)
Boiling point 654.2±55.0 °C(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility Sparingly Soluble (3.2E-5 g/L) (25°C).
form solid
color white
Sensitive Air Sensitive
CAS DataBase Reference 824395-67-7

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352-P305+P351+P338
WGK Germany  3
NFPA 704
1
0 0

(+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 667854 (+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane kanata purity 824395-67-7 100MG ₹11517.8 2022-06-14 Buy
Sigma-Aldrich(India) 667854 (+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane kanata purity 824395-67-7 500MG ₹26900.13 2022-06-14 Buy
Product number Packaging Price Buy
667854 100MG ₹11517.8 Buy
667854 500MG ₹26900.13 Buy

(+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE Chemical Properties,Uses,Production

Uses

It is a DuPhos and BPE ligands which are highly efficient privileged ligands. It is a chiral phosphine ligand used in the asymmetric hydrogenation of allylic sulfoxides.

General Description

Chiral Phosphine ligand used in the asymmetric hydrogenation of allylic sulfoxides

Dynamic Kinetic Resolution of Allylic Sulfoxides by Rh-Catalyzed Hydrogenation: A Combined Theoretical and Experimental Mechanistic Study

(+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE Preparation Products And Raw materials

Raw materials

Preparation Products

(+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE Suppliers

Global( 49)Suppliers
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(+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE (+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE, KANATA PURITY (+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane,min.98%(S,S)-Ph-BPE 1,2-Bis[(2S,5S)-2,5-diphenyl-1-phospholanyl]ethane, 97+% (S,S)-Ph-BPE,BPE (+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane, min. 98% (2S,5S,2'S,5'S)-1,1'-ethane-1,2-diylbis(2,5-diphenylphospholane) 1,2-Bis((2S,5S)-2,5-diphenylphospholan-1-yl)ethane Phospholane, 1,1'-(1,2-ethanediyl)bis[2,5-diphenyl-, (2S,2'S,5S,5'S)- (9CI) (+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane, min. 98%,99%ee (2S,5S,2'S,5'S)-1,1'-ethane-1,2-diylbis(2,5-diphenylphosphol... (+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane (S,S)-Ph-BPE 1,2-Bis[(2S,5S)-2,5-diphenyl-1-phospholanyl]ethane 824395-67-7 C34H36P2 New Products for Chemical Synthesis May/June 2007 Chiral Phosphine Chiral Catalysts, Ligands, and Reagents DuPhos/BPE Privileged Ligands and Complexes organophosphine ligand