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(+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE

(+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE Structure
  • ₹11517.8 - ₹26900.13
  • Product name: (+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE
  • CAS: 824395-67-7
  • MF: C34H36P2
  • MW: 506.61
  • EINECS:
  • MDL Number:MFCD07369028
  • Synonyms:(+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE;(+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE, KANATA PURITY;(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane,min.98%(S,S)-Ph-BPE;1,2-Bis[(2S,5S)-2,5-diphenyl-1-phospholanyl]ethane, 97+%;(S,S)-Ph-BPE,BPE;(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane, min. 98%;(2S,5S,2'S,5'S)-1,1'-ethane-1,2-diylbis(2,5-diphenylphospholane);1,2-Bis((2S,5S)-2,5-diphenylphospholan-1-yl)ethane
2 prices
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Brand

  • Sigma-Aldrich(India)

Package

  • 100MG
  • 500MG
  • ManufacturerSigma-Aldrich(India)
  • Product number667854
  • Product description(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane kanata purity
  • Packaging100MG
  • Price₹11517.8
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number667854
  • Product description(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane kanata purity
  • Packaging500MG
  • Price₹26900.13
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 667854 (+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane kanata purity 100MG ₹11517.8 2022-06-14 Buy
Sigma-Aldrich(India) 667854 (+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane kanata purity 500MG ₹26900.13 2022-06-14 Buy

Properties

Melting point :143-147 °C
alpha :+182.7° (c 1.0, CH2Cl2)
Boiling point :654.2±55.0 °C(Predicted)
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
solubility :Sparingly Soluble (3.2E-5 g/L) (25°C).
form :solid
color :white
Sensitive :Air Sensitive
CAS DataBase Reference :824395-67-7

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

It is a DuPhos and BPE ligands which are highly efficient privileged ligands. It is a chiral phosphine ligand used in the asymmetric hydrogenation of allylic sulfoxides.

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