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1,2-Epoxyhexane

1,2-Epoxyhexane Structure
CAS No.
1436-34-6
Chemical Name:
1,2-Epoxyhexane
Synonyms
BUTYLOXIRAN;BUTYLOXIRANE;HEXYLENEOXIDE;2-Butyloxirane;1,2-EPOXYHEXAN;1-HEXENE OXIDE;Epoxy-n-hexane;Hexene epoxide;n-butyloxirane;1,2-EPOXYHEXANE
CBNumber:
CB2236083
Molecular Formula:
C6H12O
Molecular Weight:
100.16
MOL File:
1436-34-6.mol
MSDS File:
SDS
Modify Date:
2024/3/8 15:50:23

1,2-Epoxyhexane Properties

Melting point 94°C
Boiling point 118-120 °C(lit.)
Density 0.833 g/mL at 20 °C(lit.)
refractive index n20/D 1.406
Flash point 60 °F
storage temp. 2-8°C
solubility Difficult to mix.
form Liquid
Specific Gravity 0.831
color Clear colorless
BRN 102568
InChI InChI=1S/C6H12O/c1-2-3-4-6-5-7-6/h6H,2-5H2,1H3
InChIKey WHNBDXQTMPYBAT-UHFFFAOYSA-N
SMILES O1CC1CCCC
LogP 1.950
CAS DataBase Reference 1436-34-6(CAS DataBase Reference)
EPA Substance Registry System Oxirane, butyl- (1436-34-6)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS07
Signal word  Danger
Hazard statements  H225-H302-H315-H319-H335
Precautionary statements  P210-P301+P312+P330-P302+P352-P305+P351+P338
Hazard Codes  F,Xn
Risk Statements  11-22-36/37/38
Safety Statements  26
RIDADR  UN 1993 3/PG 2
WGK Germany  3
RTECS  MO3630000
10-21
HazardClass  3
PackingGroup  III
HS Code  29109000
NFPA 704
3
2 1

1,2-Epoxyhexane price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 377171 1,2-Epoxyhexane 97% 1436-34-6 25G ₹3052.65 2022-06-14 Buy
Sigma-Aldrich 377171 1,2-Epoxyhexane 97% 1436-34-6 100G ₹7306.88 2022-06-14 Buy
Sigma-Aldrich(India) 377171 1,2-Epoxyhexane 97% 1436-34-6 100G ₹7306.88 2022-06-14 Buy
ALFA India ALF-L07609-22 1,2-Epoxyhexane, 96% 1436-34-6 100g ₹6835 2022-05-26 Buy
TCI Chemicals (India) E0445 1,2-Epoxyhexane min. 96.0 % 1436-34-6 25ML ₹2300 2022-05-26 Buy
Product number Packaging Price Buy
377171 25G ₹3052.65 Buy
377171 100G ₹7306.88 Buy
377171 100G ₹7306.88 Buy
ALF-L07609-22 100g ₹6835 Buy
E0445 25ML ₹2300 Buy

1,2-Epoxyhexane Chemical Properties,Uses,Production

Chemical Properties

clear colorless liquid

Uses

1,2-Epoxyhexane is used as chemical reagent, organic intermediates, fine chemicals, pharmaceutical research and development.

Application

1,2-Epoxyhexane could used as a passivating agent for core–shell aluminum nanoparticles with very high active aluminum content[1].

Synthesis

A method for preparing 1,2-epoxyhexane using a fixed-bed microchannel reaction device is as follows: dissolve 1-hexene in a solvent to prepare a 1-hexene solution, and then dissolve an oxidizing reagent in the solvent to prepare an oxidizing reagent solution. Add the solid catalyst into the fixed-bed microchannel reaction device. Pump the 1-hexene and oxidizing reagent solution configured above into the fixed-bed microchannel reaction device respectively, maintain the reaction residence time for 8-25 minutes, and the upper organic phase enters the continuous centrifuge. The product is obtained after continuous water washing.

storage

Keep container tightly closed. Store away from oxidizing agents.

Purification Methods

Purify it by fractional distillation through a 2ft helices-packed column at atmospheric pressure in a N2 atmosphere. [Pasto & Cumbo J Org Chem 30 1271 1965, Howarth et al. J Chem Soc 2433 1927, 13C NMR Davies & Witham J Chem Soc Perkin Trans 2 861 1975, Beilstein 17/1 V 103.]

References

[1] Paul A. Jelliss . “The use of 1,2-epoxyhexane as a passivating agent for core–shell aluminum nanoparticles with very high active aluminum content.” Solid State Sciences 23 (2013): Pages 8-12.

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BUTYLOXIRAN BUTYLOXIRANE 1-HEXENE OXIDE 1,2-HEXYLENE OXIDE 1,2-EPOXYHEXAN 1,2-EPOXYHEXANE 1,2-Hexene oxide 1,2-hexeneoxide 1-Hexene epoxide 1-hexeneepoxide 2-Butyloxirane 2-butyl-oxirane Epoxy-n-hexane Hexane, 1,2-epoxy- Hexene 1,2-oxide 1,2-EPOXYHEXANE 96+% 1,2-Hexane oxide Hexene epoxide n-butyloxirane HEXYLENEOXIDE 1,2-Epoxyhexane, GC 97% 1,2-Epoxyhexane, 97% 25ML 1,2-Epoxyhexane, 1-Hexene oxide 1-Hexene oxide, Butyloxirane 1,2-Epoxyhexane,97% 1,2-EPOXYHEXANE ISO 9001:2015 REACH Oxirane, 2-butyl- 1,2-Epoxyhexane> 1436-34-6 Simple 3-Membered Ring Compounds Oxiranes Epoxides Organic Building Blocks Oxygen Compounds Building Blocks Oxiranes Simple 3-Membered Ring Compounds