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4-Iodobenzaldehyde

4-Iodobenzaldehyde  Structure
CAS No.
15164-44-0
Chemical Name:
4-Iodobenzaldehyde
Synonyms
NSC 84301;P-IODOBENZALDEHYDE;4-IODOBENZALDEHYDE;4-Iodobenzaldehyde>Benzaldehyde, 4-iodo-;4-Iodobenzaldehyde 96%;Benzaldehyde of iodine;4-IODOBENZALDEHYDE 98+%;4-IODOBENZALDEHYDE, 97+%;TIANFUCHEM-- 15164-44-0--High purity 4-IODOBENZALDEHYDE in stock
CBNumber:
CB2265151
Molecular Formula:
C7H5IO
Molecular Weight:
232.02
MOL File:
15164-44-0.mol
MSDS File:
SDS
Modify Date:
2024/5/11 10:50:42

4-Iodobenzaldehyde Properties

Melting point 78-82 °C (lit.)
Boiling point 265°C(lit.)
Density 1.8576 (estimate)
storage temp. 2-8°C
form Crystals
color Yellow
Water Solubility Insoluble in water.
Sensitive Air & Light Sensitive
BRN 636101
InChI InChI=1S/C7H5IO/c8-7-3-1-6(5-9)2-4-7/h1-5H
InChIKey NIEBHDXUIJSHSL-UHFFFAOYSA-N
SMILES C(=O)C1=CC=C(I)C=C1
CAS DataBase Reference 15164-44-0(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
HazardClass  IRRITANT, AIR SENSITIVE, KEEP COLD
HS Code  29130000
NFPA 704
1
2 1

4-Iodobenzaldehyde price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 263826 4-Iodobenzaldehyde 96% 15164-44-0 1G ₹9266.2 2022-06-14 Buy
ALFA India ALF-L17448-MD 4-Iodobenzaldehyde, 98+% 15164-44-0 250mg ₹1703 2022-05-26 Buy
ALFA India ALF-L17448-06 4-Iodobenzaldehyde, 98+% 15164-44-0 5g ₹18597 2022-05-26 Buy
TCI Chemicals (India) I0612 4-Iodobenzaldehyde min. 96.0 % 15164-44-0 1G ₹5300 2022-05-26 Buy
ALFA India ALF-L17448-03 4-Iodobenzaldehyde, 98+% 15164-44-0 1g ₹9111 2022-05-26 Buy
Product number Packaging Price Buy
263826 1G ₹9266.2 Buy
ALF-L17448-MD 250mg ₹1703 Buy
ALF-L17448-06 5g ₹18597 Buy
I0612 1G ₹5300 Buy
ALF-L17448-03 1g ₹9111 Buy

4-Iodobenzaldehyde Chemical Properties,Uses,Production

Chemical Properties

Yellow crystals

Uses

4-Iodobenzaldehyde is used in synthesis of 4-[2-(trimethylsilyl)ethynyl]benzaldehyde, 5,15-dimesityl-10-(3-[2-(trimethylsilyl)ethynyi]phenyl}-20-(4-iodophenyl)porphyrin, and 5,15-dimesityl-10-[3,5-bis{2-[4-(N,N?-difluoroboryl-1,9-dimethyidipyrrin-5-yl)-phenyl]ethynyl}phenyl]-20-(4-iodophenyl)porphyrin.

Synthesis

A mixture of 10.0g p-bromobenzaldehyde (54mmol), 81.1gKI (488mmol, 9.0eq), 31.7gCuI (166mmol, 3.1eq) and 150ml freshly distilled DMI was placed in a 500ml three-neck flask. The mixture was purged with nitrogen and heated at 200°C with vigorous stirring for 6 hours. After cooling to room temperature, add salt water and ice. The reaction vessel was placed in an ice bath for several hours and precipitated inorganic salts were removed by filtration. After the filtrate was extracted with diethyl ether, the extracts were combined and washed with brine. Removal of the solvent under reduced pressure gave the product 4-Iodobenzaldehyde.

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4-Iodobenzaldehyde Spectrum

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