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BETA-ENDOSULFAN

BETA-ENDOSULFAN Structure
CAS No.
33213-65-9
Chemical Name:
BETA-ENDOSULFAN
Synonyms
β-Endosulfan;ENDOSULFAN II;B-ENDOSULFAN;-Endosulfan;ENDOSULFAN II (BETA ISOMER);endosulfan2;endosulfanb;beta-Thiodan;'LGC' (1120);alpha-thionex
CBNumber:
CB2400813
Molecular Formula:
C9H6Cl6O3S
Molecular Weight:
406.93
MOL File:
33213-65-9.mol
Modify Date:
2023/6/8 9:02:54

BETA-ENDOSULFAN Properties

Melting point 209°C
Boiling point 449.7±45.0 °C(Predicted)
Density 1.6568 (estimate)
vapor pressure 450 at 20 °C (shake flask-GLC, Bowman and Sans, 1983)
Flash point 11 °C
storage temp. APPROX 4°C
solubility Chloroform: Slightly Soluble; Methanol: Slightly Soluble
Water Solubility 0.28mg/L(25 ºC)
BRN 2950317
Henry's Law Constant 0.022 at 5 °C, 0.037 at 15 °C, 0.043 at 20 °C, 0.065 at 25 °C, 0.80 at 35 °C:in 3% NaCl solution: 0.20 at 5 °C, 0.37 at 15 °C, 0.46 at 25 °C, 0.56 at 35 °C (gas stripping-GC, Cetin et al., 2006)
Exposure limits ACGIH TLV: TWA 0.1 mg/m3.
Stability Light Sensitive
NIST Chemistry Reference Endosulfan ii(33213-65-9)
EPA Substance Registry System .beta.-Endosulfan (33213-65-9)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS06,GHS09
Signal word  Danger
Hazard statements  H301-H310+H330-H410
Precautionary statements  P262-P273-P280-P301+P310+P330-P302+P352+P310-P304+P340+P310
Hazard Codes  Xn,N,F,T
Risk Statements  22-67-65-62-51/53-48/20-38-11-50/53-25
Safety Statements  36/37-61-62-33-29-16-9-60-45
RIDADR  2761
WGK Germany  3
RTECS  RB9875200
HazardClass  6.1(b)
PackingGroup  III
Toxicity LC50 (96-hour) for golden orfe 2 mg/L (Hartley and Kidd, 1987), rainbow trout 0.3 mg/L and white sucker 3.0 mg/L (Verschueren, 1983).
NFPA 704
0
2 0

BETA-ENDOSULFAN Chemical Properties,Uses,Production

Chemical Properties

Endosulfan is a chlorinated cyclodiene insecticide. The pure product is a colorless crystalline solid. The technical product is a light to dark brown waxy solid. It has a rotten egg or sulfur odor.

Physical properties

Colorless to brown, nonflammable solid or crystals with a mild odor similar to terpene or sulfur dioxide.

Uses

Insecticide for vegetable crops.

General Description

Brown crystals. Melting point 208-210°C. Used as an insecticide.

Air & Water Reactions

Insoluble in water. Reacts slowly with water to generate sulfur dioxide.

Reactivity Profile

BETA-ENDOSULFAN is a sulfite ester of a chlorinated cyclic diol. Decomposed rapidly by alkali to generate sulfur dioxide. Decomposed by acid. Incompatible with strong oxidizing and reducing agents. may be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.

Health Hazard

ACUTE/CHRONIC HAZARDS: Highly toxic by ingestion, inhalation, and skin absorption.

Fire Hazard

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Containers may explode when heated. Runoff may pollute waterways.

Shipping

UN2761 Organochlorine pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.

Waste Disposal

A recommended method for disposal is burial 18 in deep in noncropland, away from water supplies, but bags can be burned. Large quantities should be incinerated at high temperature in a unit with effluent gas scrubbing. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/ mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

BETA-ENDOSULFAN Preparation Products And Raw materials

Raw materials

Preparation Products

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6,7,8,9,10,10-HEXACHLORO-1,5,5A,6,9,9A-HEXAHYDRO-6,9-METHANO-2,4,3-BENZODIOXATHIEPIN-3-OXIDE BETA ISOMER BETA-ENDOSULFAN BETA-1,4,5,6,7,7-HEXACHLOROBICYCLO[2.2.1]-5-HEPTENE-2,3-BIS-(METHYLENE)-SULFITE BETA-BENZOEPIN 'LGC' (1120) ENDOSULFAN (BETA ISOMER) 1,4,5,6,7,7-hexachloro-,cyclicsulfite,exo-5-norbornene-3-dimethanol 5-Norbornene-2,3-dimethanol, 1,4,5,6,7,7-hexachloro-, cyclic sulfite, exo- alpha-thionex b-endosulfan-beta beta-Thiodan (3alpha,5a beta,6beta,9beta,9a beta)-6,7,8,9,10,10-Hexachloro-1,5,5a,6,9,9a-hexahydro-6,9-methano-2,4,3-benzodioxathiepin-3-oxide 6,7,8,9,10,10-Hexachloro-1,5,5a,6,9,9a-Hexahydro-6,9-Methano-2,4,3-Benzodioxathiepin-3-Oxide Beta Isomer β-benzoepin standard (6S,9R)-6,7,8,9,10,10-Hexachloro-1,5,5aα,6,9,9aα-hexahydro-6β,9β-methano-2,4,3-benzodioxathiepin 3-oxide b-Endosulfan 100mg [33213-65-9] Endosulfan (beta isomer) 100mg [33213-65-9] Endosulfan II (β isomer) 99% β-Endosulfan Standard endosulfan2 endosulfanb Endosulfan-beta endosulfanii(beta) General Weed Killer generalweedkiller ENDOSULFAN ETHER PESTANAL, 100 MG ENDOSULFAN (BETA ISOMER), 100MG, NEAT ENDOSULFAN II (BETA), 25MG, NEAT -ENDOSULFAN PESTANAL 6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10-hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide, (3.alpha.,5a.alpha.,6.beta.,9.beta.,9a.alpha.)- endosulfan (beta isomer) (bsi,iso,ansi,esa) BETA-ENDOSULPHAN ENDOSULPHANBETA BETA-BENZOEPIN STANDARD Endosulfan II@1000 μg/mL in Acetone Endosulfan II @100 μg/mL in Methanol Endosulfan II @1000 μg/mL in MeOH beta-Endosulfan @1000 μg/mL in p-Dioxane EndosulfanIISolution,100mg/L,1ml Endosulfan Impurity 6 β-Endosulfan solution β-Endosulfan Solution in Hexane, 100μg/mL B-ENDOSULFAN ENDOSULFAN II ENDOSULFAN II (BETA ISOMER) β-Endosulfan -Endosulfan β-Endosulfan Standard 6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10-hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide, (3α,5aα,6β,9β,9aα)- 33213-65-9 33212-65-9 C9H6Cl6O3S European Community: ISO and DIN Insecticides Oeko-Tex Standard 100 Pesticides Pesticides&Metabolites PesticidesMethod Specific