Malonamide

- CAS No.
- 108-13-4
- Chemical Name:
- Malonamide
- Synonyms
- PROPANEDIAMIDE;MALONDIAMIDE;NSC 2134;MALONAMIDE;MALONODIAMIDE;Malonamide>AURORA KA-4099;malonicdiamide;Malonyldiamide;Malonamide 98%
- CBNumber:
- CB2418973
- Molecular Formula:
- C3H6N2O2
- Molecular Weight:
- 102.09
- MOL File:
- 108-13-4.mol
- MSDS File:
- SDS
- Modify Date:
- 2025/1/27 9:38:02
Melting point | 172-175 °C (lit.) |
---|---|
Boiling point | 191.38°C (rough estimate) |
Density | 1.3516 (rough estimate) |
refractive index | 1.5110 (estimate) |
storage temp. | Sealed in dry,Room Temperature |
solubility | Soluble in HCl. |
pka | 7.00±0.70(Predicted) |
form | powder to crystal |
color | White to Almost white |
Water Solubility | 180 g/L (20 ºC) |
BRN | 1751401 |
InChI | InChI=1S/C3H6N2O2/c4-2(6)1-3(5)7/h1H2,(H2,4,6)(H2,5,7) |
InChIKey | WRIRWRKPLXCTFD-UHFFFAOYSA-N |
SMILES | C(N)(=O)CC(N)=O |
CAS DataBase Reference | 108-13-4(CAS DataBase Reference) |
NIST Chemistry Reference | Propanediamide(108-13-4) |
EPA Substance Registry System | Propanediamide (108-13-4) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS07 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Warning | |||||||||
Hazard statements | H302-H315-H319-H332-H335 | |||||||||
Precautionary statements | P261-P280-P305+P351+P338 | |||||||||
Safety Statements | 22-24/25 | |||||||||
WGK Germany | 2 | |||||||||
RTECS | ON9125000 | |||||||||
TSCA | Yes | |||||||||
HS Code | 29241900 | |||||||||
NFPA 704 |
|
Malonamide price More Price(10)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 129593 | Malonamide 97% | 108-13-4 | 100G | ₹3593.9 | 2022-06-14 | Buy |
TCI Chemicals (India) | M0027 | Malonamide | 108-13-4 | 25G | ₹2200 | 2022-05-26 | Buy |
ALFA India | ALF-A17939-36 | Malonamide, 98% | 108-13-4 | 500g | ₹14356 | 2022-05-26 | Buy |
ALFA India | ALF-A17939-22 | Malonamide, 98% | 108-13-4 | 100g | ₹3477 | 2022-05-26 | Buy |
TCI Chemicals (India) | M0027 | Malonamide | 108-13-4 | 500G | ₹11800 | 2022-05-26 | Buy |
Malonamide Chemical Properties,Uses,Production
Description
Malonamide is a dicarboxylic acid diamide that is malonic acid in which both carboxy groups have been replaced by carbamoyl groups. It is functionally related to a malonic acid.
Chemical Properties
White crystalline powder
Uses
The malonamide-based ionic liquid extractant was used in the extraction of europium(iii) and other trivalent rare-earth ions from nitric acid medium.
Uses
Malonamide is used in the synthesis of malonamic acid, malonamate and malonamide derivative of some heterocyclic compounds with antiinflammatory activity.
General Description
The malonamide derivatives are obtained by the one-pot, five-component condensation reaction of isocyanide, Meldrum′s acid, arylidene malononitrile, and two amine molecules in CH2Cl2.
Hazard
Mildly toxic by ingestion.
Synthesis
The synthesis of Malonamide is as follows:
A typical reaction was carried out in a 10 mL flask. Benzonitrile (2 mmol), CuII-4 ? (0.2 g), acetaldoxime (6 mmol) and MeOH (4 mL) were stirred at 65 °C for 4 h. The solid was filtered, washed with MeOH and the filtrate evaporated. The residue was subjected to GC-MS analysis and NMR spectroscopy. The filtered catalyst can be recycled after drying at about 150 °C for 1 h.
Purification Methods
Crystallise the amide from water. [Beilstein 2 IV 1887.]
Malonamide Preparation Products And Raw materials
Raw materials
Preparation Products
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Central Drug House(P) Ltd. | 91-11-49404040 | New Delhi, India | 6157 | 58 | Inquiry |
TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6768 | 58 | Inquiry |
Otto Chemie Pvt. Ltd. | +91 9820041841 | Mumbai, India | 5870 | 58 | Inquiry |
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Vardhaman P Golechha | 040 2476 1719 | Bangalore, India | 152 | 58 | Inquiry |
Supplier | Advantage |
---|---|
ORGANO FINE CHEMICALS | 58 |
JSK Chemicals | 58 |
Organo Fine Chemicals | 60 |
CHEMSWORTH | 30 |
Triveni chemicals | 58 |
Central Drug House(P) Ltd. | 58 |
TCI Chemicals (India) Pvt. Ltd. | 58 |
Otto Chemie Pvt. Ltd. | 58 |
Alfa Aesar | 58 |
Vardhaman P Golechha | 58 |
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