Lily aldehyde
- CAS No.
- 80-54-6
- Chemical Name:
- Lily aldehyde
- Synonyms
- LILIAL;BUTYLPHENYL METHYLPROPIONAL;2-(4-TERT-BUTYLBENZYL)PROPIONALDEHYDE;LYSMERAL;Lillial;synthetic convallaria aldehyde;4-(1,1-Dimethylethyl)-methylbenzenepropanal;Propanal, alpha-methyl-beta-(p-tert.-butylphenyl)-;Lilyal;lilyall
- CBNumber:
- CB2492379
- Molecular Formula:
- C14H20O
- Molecular Weight:
- 204.31
- MOL File:
- 80-54-6.mol
- Modify Date:
- 2024/7/29 15:17:36
| Melting point | 106-109 °C |
|---|---|
| Boiling point | 150°C 10mm |
| Density | 0.946 g/mL at 20 °C(lit.) |
| vapor pressure | 0.25Pa at 20℃ |
| refractive index |
n |
| Flash point | 100°C |
| storage temp. | 2-8°C |
| solubility | Chloroform (Sparingly), Ethyl Acetate (Slightly) |
| form | Liquid |
| color | Colorless to Light yellow |
| Odor | at 100.00 %. floral muguet watery green powdery cumin |
| Odor Type | floral |
| Water Solubility | 33mg/L at 20℃ |
| BRN | 880140 |
| InChIKey | SDQFDHOLCGWZPU-UHFFFAOYSA-N |
| LogP | 4.2 at 24℃ |
| CAS DataBase Reference | 80-54-6(CAS DataBase Reference) |
| NIST Chemistry Reference | Lilial(80-54-6) |
| EPA Substance Registry System | Benzenepropanal, 4-(1,1-dimethylethyl)-.alpha.-methyl- (80-54-6) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS07,GHS08 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302-H315-H317-H361-H412 | |||||||||
| Precautionary statements | P202-P273-P280-P301+P312-P302+P352-P308+P313 | |||||||||
| Hazard Codes | Xn,N | |||||||||
| Risk Statements | 22-38-51/53-62-43 | |||||||||
| Safety Statements | 60-61-36/37 | |||||||||
| RIDADR | UN 3082 9/PG 3 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | MW4895000 | |||||||||
| F | 10 | |||||||||
| HS Code | 29121900 | |||||||||
| NFPA 704 |
|
Lily aldehyde price More Price(4)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 43884 | 2-(4-tert-Butylbenzyl)propionaldehyde analytical standard | 80-54-6 | 10MG | ₹5618.18 | 2022-06-14 | Buy |
| TCI Chemicals (India) | B1145 | 3-(4-tert-Butylphenyl)isobutyraldehyde min. 96.0 % | 80-54-6 | 25ML | ₹2900 | 2022-05-26 | Buy |
| TCI Chemicals (India) | B1145 | 3-(4-tert-Butylphenyl)isobutyraldehyde min. 96.0 % | 80-54-6 | 100ML | ₹5300 | 2022-05-26 | Buy |
| TCI Chemicals (India) | B1145 | 3-(4-tert-Butylphenyl)isobutyraldehyde min. 96.0 % | 80-54-6 | 500ML | ₹10800 | 2022-05-26 | Buy |
Lily aldehyde Chemical Properties,Uses,Production
Chemical Properties
Lily aldehyde is a homolog of
cyclamenaldehyde. The racemic compound is a colorless to slightly yellow liquid
with a mild-floral odor, reminiscent of cyclamen and lily of the valley.
The aldehyde is prepared by the same routes as cyclamenaldehyde.
Other routes start from ??-methylcinnamaldehyde. ??-Methylcinnamaldehyde
(from benzaldehyde and propionaldehyde) is hydrogenated to ??-methyldihydrocinnamic
alcohol.The alcohol is alkylated with tert-butyl chloride or isobutene to
4-tert-butyl-??-methyldihydrocinnamic alcohol, which is subsequently dehydrogenated to the desired aldehyde.
4-tert-Butyl-??-methyldihydrocinnamaldehyde is more stable than cyclamenaldehyde
and is a popular component of flower compositions, particularly lily of the
valley and linden types, because of its mild, pleasant, blossomfragrance. It is used
in a wide range of perfume types, but especially in soap and detergent perfumes.
Uses
In addition to its applications in the perfume and aroma industry, lilial is used mainly for the synthesis of substituted 3-(4-tert-butylphenyl)-2-methylpropylamines, a new class of substances with fungicidal properties. These compounds are effective against mildew in barley and wheat.
Production Methods
Lily aldehyde is produced industrially almost solely by aldol condensation of 4-tert-butylbenzaldehyde and propionaldehyde to give 4-tert-butyl-α-methylcinnamaldehyde, which can be hydrogenated selectively on noble metal catalysts such as Pd, Rh, Pd – Pr2O3 on Al2O3, or on modified cobalt catalysts. The aldol condensation and the hydrogenation can be carried out in one step in the presence of a hydrogenation catalyst.
The Friedel – Crafts reaction of 4-tertbutylbenzene with methacrolein or methacrolein diacetate proceeds in an analogous manner to the preparation of cyclamenaldehyde.
Further possibilities are the Rh-catalyzed hydroformylation of 1-(4-tert-butylphenyl)-1- methoxypropene and subsequent partial hydrogenation, the palladium salt catalyzed reaction of 4-tert-butylphenylhalide with methallylalcohol, and the dehydrogenation of 3-(4-tert-butylphenyl)-2-methylpropanol on silver catalysts.
General Description
2-(4-tert-Butylbenzyl)propionaldehyde is categorized under the synthetic fragrance class of compounds widely utilized in consumer products such as perfumes, after shave lotions, cosmetics, etc.
Trade name
Lilestralis Pure (Innospec), Lysmeral® Extra (BASF).
Contact allergens
Lilial? is a synthetic compound listed as a fragrance allergen. Its presence is indicated on cosmetics within the EU.
Lily aldehyde Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| Privi Speciality Chemicals Ltd. | +91-2233043500 +91-2233043500 | Mumbai, India | 63 | 58 | Inquiry |
| Vee Kay International | 91-5832-221548 | Uttar Pradesh, India | 57 | 58 | Inquiry |
| Associate Allied Chemicals (India) Pvt., Ltd. | 91-22-24198800 | Maharashtra, India | 36 | 58 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| Parth Antibiotics Pvt Ltd. | +91 (22) 2562-8329 | New Delhi, India | 173 | 50 | Inquiry |
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
| CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6351 | 58 | Inquiry |
| P.P. Sheth Aromas Pvt., Ltd. | 91-22-27780900 | Maharashtra, India | 35 | 58 | Inquiry |
| Aroma Sales Corporation | 08068442234Ext 905 | Delhi, India | 131 | 58 | Inquiry |
| Druja Chem Private Limited | 91-22-40435757 | Maharashtra, India | 17 | 58 | Inquiry |
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