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Tetradecafluorohexane

Tetradecafluorohexane Structure
CAS No.
355-42-0
Chemical Name:
Tetradecafluorohexane
Synonyms
FC-72;FLUORINERT;TETRADECAFLUOROHEXANE;PFC-51-14;FLUORINERT FC-72;PERFLUOROHEXANES;n-Perfluorohexane;PF5060;Hexane, tetradecafluoro-;PerfL
CBNumber:
CB2743404
Molecular Formula:
C6F14
Molecular Weight:
338.04
MOL File:
355-42-0.mol
MSDS File:
SDS
Modify Date:
2024/8/21 22:41:43

Tetradecafluorohexane Properties

Melting point −4 °C(lit.)
Boiling point 58-60 °C(lit.)
Density 1.669 g/mL at 25 °C(lit.)
vapor pressure 26.5kPa at 25℃
refractive index n20/D 1.252(lit.)
Flash point 56-60°C
form Liquid
Specific Gravity 1.699
color Clear colorless
Water Solubility Immiscible with water.
Merck 14,7157
BRN 1802113
Dielectric constant 1.5700000000000001
Stability Stable. Incompatible with strong oxidizing agents.
InChIKey ZJIJAJXFLBMLCK-UHFFFAOYSA-N
LogP 4.5 at 20℃ and pH7
CAS DataBase Reference 355-42-0(CAS DataBase Reference)
EPA Substance Registry System Perfluorohexane (355-42-0)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H412
Precautionary statements  P273-P501
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
RIDADR  2810
WGK Germany  3
RTECS  MO4310000
Hazard Note  Irritant
TSCA  T
HazardClass  6.1(b)
PackingGroup  III
HS Code  29033990
NFPA 704
0
0 0

Tetradecafluorohexane Chemical Properties,Uses,Production

Chemical Properties

colourless liquid

Uses

Perfluorohexanes is used as a coolant, photosensitizer in fluorous biphasic singlet oxygenation and an inert reaction medium. It is used in the electronic cooling liquid and insulator. It plays a vital role as a reaction medium, especially for photooxidation reactions. Further, it finds application as an ultrasound contrast agent.

Application

Perfluorohexane uses and applications include: dispersant for lubricants, mold release agents, protective coatings; reaction media for polymerizations, purification, separation processes; solvent for removal of halogenated lubricants, oils, greases; carrier for halogenated material; for quick-cooling or freezing foods; heat-transfer fluid.
Because it is biologically inert and chemically stable, perfluorohexane has attracted attention in medicine. Like other fluorocarbons, perfluorohexane dissolves gases, including oxygen from the air, to a higher concentration than ordinary organic solvents. This effect is attributed to the weak intermolecular forces between perfluorohexane molecules, which allows "space" for gas molecules to partition into the liquid. Animals can be submerged in a bath of perfluorohexane without drowning, as there is sufficient oxygen available in the solvent to allow respiration to continue. This effect has led to the experimental use of perfluorohexane in treating burn victims, as their lungs can be filled with either perfluorohexane vapor or in extreme cases liquid perfluorohexane, allowing breathing to continue without the problems normally seen with pulmonary edema that sometimes occur when the inside of the lungs have been burnt e.g. by inhalation of hot smoke.

General Description

Tetradecafluorohexane in the gas phase reacts spontaneously with lithium amalgam, to give a solid and intimate mixture of lithium fluoride and elemental polymeric carbon with a small amount of superstoichiometric lithium.

Purification Methods

Purify the fluorohexane by fractional freezing. The methods described for perfluoroheptane should be applicable here. [Beilstein 1 IV 348.]

Tetradecafluorohexane Preparation Products And Raw materials

Global( 241)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
CHEMSWORTH +91-261-2397244 New Delhi, India 6707 30 Inquiry
Otto Chemie Pvt. Ltd. +91 9820041841 Mumbai, India 5873 58 Inquiry
Alfa Aesar 1 800 209 7001 Maharashtra, India 6913 58 Inquiry
Wuhan Silworld Chemical Co.,Ltd +86-027-85613400 +86-15827173649 China 178 58 Inquiry
Shanghai Daken Advanced Materials Co.,Ltd +86-371-66670886 China 18652 58 Inquiry
Henan Fengda Chemical Co., Ltd +86-371-86557731 +86-13613820652 China 20294 58 Inquiry
Shaanxi Dideu Medichem Co. Ltd +86-029-81138252 +86-18789408387 China 3957 58 Inquiry
Hebei Chuanghai Biotechnology Co,.LTD +86-13131129325 China 5867 58 Inquiry
Hebei Mojin Biotechnology Co.,Ltd +86-15028179902 China 1003 58 Inquiry

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