ChemicalBook > Product Catalog >Organic Chemistry >Organometallic compounds >Organic manganese >(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE

CAS No.: 138124-32-0

Chemical Name:: (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE

Synonyms: Jacobsen;96+%(chn);(R,R)-form;(R,R)Jacobesn;(R,R)-JACOBSEN;JACOBSEN'S CATALYST;(R,R)-Jacobsen Cat.;(R,R)-JACOBSEN CATALYST;Jacobsen'scatalyst(R,R);(R,R)-JACOBSEN'S CATALYST

CBNumber:: CB2778574

Molecular Formula:: C36H52ClMnN2O2

Molecular Weight:: 635.2

MOL File:: 138124-32-0.mol

Modify Date:: 2023/10/13 18:16:27

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(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Properties

Melting point	330-332 °C(lit.)
alpha	D23 +580° (c = 0.01 in ethanol)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
form	Liquid May Develop Some Turbidity or Precipitate
color	Light yellow to gold to brown
λmax	509nm(CH2Cl2)(lit.)
Merck	14,5252
InChIKey	LJVAWOSDJSQANR-OHRASPNLSA-K

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P264-P271-P280-P302+P352-P305+P351+P338

Hazard Codes

Risk Statements

36/37/38-20/21/22

Safety Statements

26-36-36/37/39

WGK Germany

HS Code

29349990

NFPA 704

	0
2		0

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE price More Price(5)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich(India)	404446	(R,R)-(−)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride	138124-32-0	1G	₹4232.58	2022-06-14	Buy
Sigma-Aldrich(India)	404446	(R,R)-(−)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride	138124-32-0	5G	₹16399.88	2022-06-14	Buy
Sigma-Aldrich(India)	404446	(R,R)-(−)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride	138124-32-0	25G	₹38666.9	2022-06-14	Buy
TCI Chemicals (India)	B5613	(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) Chloride	138124-32-0	1G	₹4800	2022-05-26	Buy
TCI Chemicals (India)	B5613	(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) Chloride	138124-32-0	5G	₹17600	2022-05-26	Buy

Product number	Packaging	Price	Buy
404446	1G	₹4232.58	Buy
404446	5G	₹16399.88	Buy
404446	25G	₹38666.9	Buy
B5613	1G	₹4800	Buy
B5613	5G	₹17600	Buy

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Chemical Properties,Uses,Production

Chemical Properties

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE is Dark brown powder or chunks

Uses

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE is a coordinated compound of manganese and a salen-type ligand. It is also used as an asymmetric catalyst used to enantioselectively transform prochiral alkenes into epoxides.

Reactions

Catalyst for the conversion of olefins to chiral epoxides in high enantiomeric excess.
Pharmaceutically important, single enantiomer amino alcohols are efficiently produced from the corresponding chiral epoxide by acid or base-catalyzed epoxide ring-opening reactions.
symmetric Kinetic resolution of secondary alcohols in water.
Enantioselective Reformatsky reaction with ketones.

General Description

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(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Suppliers

Global( 108)Suppliers

Supplier	Tel	Country	ProdList	Advantage	Inquiry
Evans Fine Chem	+91-9821340302 +91-9821340302	Maharashtra, India	286	58	Inquiry
SOLFYN INTERNATIONAL LLP	+91-9321772608 +91-9321772608	Mumbai, India	105	58	Inquiry
A.J Chemicals	91-9810153283	New Delhi, India	6124	58	Inquiry
CLEARSYNTH LABS LTD.	+91-22-45045900	Hyderabad, India	6351	58	Inquiry
EMMELLEN BIOTECH PHARMACEUTICALS LTD	+91-22-66797200	New Delhi, India	52	61	Inquiry
TCI Chemicals (India) Pvt. Ltd.	1800 425 7889	New Delhi, India	6778	58	Inquiry
Shanghai UCHEM Inc.	+862156762820 +86-13564624040	China	6938	58	Inquiry
Chongqing Chemdad Co., Ltd	+86-023-6139-8061 +86-86-13650506873	China	39916	58	Inquiry
CONIER CHEM AND PHARMA LIMITED	+8618523575427	China	49391	58	Inquiry
career henan chemical co	+86-0371-86658258 +8613203830695	China	29826	58	Inquiry

Supplier	Advantage
Evans Fine Chem	58
SOLFYN INTERNATIONAL LLP	58
A.J Chemicals	58
CLEARSYNTH LABS LTD.	58
EMMELLEN BIOTECH PHARMACEUTICALS LTD	61
TCI Chemicals (India) Pvt. Ltd.	58
Shanghai UCHEM Inc.	58
Chongqing Chemdad Co., Ltd	58
CONIER CHEM AND PHARMA LIMITED	58
career henan chemical co	58

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Spectrum

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE(138124-32-0)IR (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE(138124-32-0)FT-IR

138124-32-0((R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE)Related Search:

(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE N,N'-BIS(SALICYLIDENE)-1,6-HEXANEDIAMINE

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Manganese Manganese chloride tetrahydrate (R,R)-(-)-1,2-DIAMINOCYCLOHEXANE HYDROCHLORIDE CIS/TRANS-DISALYCYLIDENE-1,2-CYCLOHEXYLIDENEDIAMINE

N,N'-BIS(SALICYLIDENE)-1,2-PROPANEDIAMINE N-benzylidenecyclohexylamine N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINE

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(R,R)-(-)-N,N'-BIS(3.5-DI-T-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE-MANGANESE (III) CHLORIDE (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE (R,R)-JACOBSEN CATALYST (R,R)-JACOBSEN'S CATALYST (R,R)-JACOBSEN'S CATALYST MANGANESE(III) CHLORIDE COMPLEX (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]MANGANESE(III)CHLORIDE JACOBSEN'S CATALYST (-)-BIS(3,5-DI-T-BU-SALICYL.)-1,2-CYCLO- (R,R)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYL- IDENE)-1,2-CYCLOHEXANEDIAMINO-MN-CL98% (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminemanganese(III)chloride 96+%(chn) (R,R)(-)N,N'Bis(3,5-di-tbutylsalicylidene)1,2-chexanediaminomanganese(iii)chlorideco (1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III)chloride,98%(R,R)-JacobsenCat. (R,R)-(-)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chlo (R,R)-Jacobsen’s catalyst, Jacobsen’s catalyst Jacobsen'scatalyst(R,R) (R,R)-(-)-[N,N(1)-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaMinoat(2-)]Manganese(III) chloride (1R,2R)-(-)-[1,2-CyclohexanediaMino-N,N'-bis(3,5-di-t-butylsalicylidene)]Manganese (III) chloride (R,R)-Jacobsen Cat. (R,R)-N,N -BIS(3,5-DI-TERT-BUTYLSALICYL- IDENE)-1,2-CYCLOHEXANEDIAMINO-MN-CL (R,R)Jacobesn Jacobsen Manganese,chloro[[2,2'-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-kN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-kO]](2-)]-, (SP-5-13)- -1,2- cyclohexanediaminomanganese(III) -N,N'-Bis(3,5-di-tertbutylsalicylidene) (R,R)-JACOBSEN (R,R)-form (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylid ene)-1,2-cyclohexanediamino-manganese(I)chloride (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE ISO 9001：2015 REACH (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) (R,R)-Jacobsen Cat. (1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-Bis(3,5-di-tert-butylsalicylidene)]manganese(III) Chloride (R,R)-(-)-Jacobsen manganese (III) catalyst (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE (1R,2R)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butyl-salicylidene)]manganese(III) chloride 138124-32-0 138124-32-1 C36H52ClMnN2O2 Epoxidation Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents Jacobsen Metal Other Metal Chiral Reagents