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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organic manganese >(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Structure
  • ₹4232.58 - ₹38666.9
  • Product name: (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE
  • CAS: 138124-32-0
  • MF: C36H52ClMnN2O2
  • MW: 635.2
  • EINECS:
  • MDL Number:MFCD02101664
  • Synonyms:(R,R)-(-)-N,N'-BIS(3.5-DI-T-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE-MANGANESE (III) CHLORIDE;(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE;(R,R)-JACOBSEN CATALYST;(R,R)-JACOBSEN'S CATALYST;(R,R)-JACOBSEN'S CATALYST MANGANESE(III) CHLORIDE COMPLEX;(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]MANGANESE(III)CHLORIDE;JACOBSEN'S CATALYST;(-)-BIS(3,5-DI-T-BU-SALICYL.)-1,2-CYCLO-
Price5 Properties Safety Information Description
5 prices
Selected condition：

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 1G
  • 5G
  • 25G
  • ManufacturerTCI Chemicals (India)
  • Product numberB5613
  • Product description(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) Chloride
  • Packaging1G
  • Price₹4800
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB5613
  • Product description(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) Chloride
  • Packaging5G
  • Price₹17600
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number404446
  • Product description(R,R)-(−)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
  • Packaging1G
  • Price₹4232.58
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number404446
  • Product description(R,R)-(−)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
  • Packaging5G
  • Price₹16399.88
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number404446
  • Product description(R,R)-(−)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
  • Packaging25G
  • Price₹38666.9
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) B5613 (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) Chloride 1G ₹4800 2022-05-26 Buy
TCI Chemicals (India) B5613 (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) Chloride 5G ₹17600 2022-05-26 Buy
Sigma-Aldrich(India) 404446 (R,R)-(−)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 1G ₹4232.58 2022-06-14 Buy
Sigma-Aldrich(India) 404446 (R,R)-(−)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 5G ₹16399.88 2022-06-14 Buy
Sigma-Aldrich(India) 404446 (R,R)-(−)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 25G ₹38666.9 2022-06-14 Buy

Properties

Melting point :330-332 °C(lit.)
alpha :D23 +580° (c = 0.01 in ethanol)
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
form :Liquid May Develop Some Turbidity or Precipitate
color :Light yellow to gold to brown
λmax :509nm(CH2Cl2)(lit.)
Merck :14,5252
InChIKey :LJVAWOSDJSQANR-OHRASPNLSA-K

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Salen (Mn)-catalyzed asymmetric epoxidation of unfunctionalized olefins.High enantioselectivities and yields are obtained for a variety of substrates, especiallycis-alkenes. A few applications include the synthesis of the taxol side chainandcis-1-amino-2-indanol.Jacobsen′s catalyst has also been used in the asymmetricα-hydroxylation of silyl enol ethers.Catalyst for the enantioselective epoxidation of a variety of olefins.

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Suppliers and manufacturers

Shanghai UCHEM Inc.
(R,R)-Jacobsen Catalyst
₹70.00 /25g
(R,R)-Jacobsen Catalyst CAS:138124-32-0
career henan chemical co
(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE
₹0.01 /1KG
(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE CAS:138124-32-0
Evans Fine Chem SOLFYN INTERNATIONAL LLP A.J Chemicals CLEARSYNTH LABS LTD. EMMELLEN BIOTECH PHARMACEUTICALS LTD TCI Chemicals (India) Pvt. Ltd.
Chongqing Chemdad Co., Ltd
CONIER CHEM AND PHARMA LIMITED