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(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE

(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE Structure
  • ₹5228.48 - ₹20015.43
  • Product name: (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE
  • CAS: 135616-36-3
  • MF: C36H54N2O2
  • MW: 546.83
  • EINECS:
  • MDL Number:MFCD00191801
  • Synonyms:(S,S)-(+)-N,N'-BIS(3,5-DI-T-BU-SALICYL.);(1S,2S)-(+)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene);(S,S)-(+)-N,N'-BIS(3,5-DI-T-BUTYLSALICYL-IDENE)-1,2-CYCLOHEXANEDIAMINE;(S,S)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE;(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE;(S,S)-JACOBSEN'S LIGAND;(S,S)-JACOBSEN LIGAND;(1S,2S)-(+)-1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)
Price2 Properties Safety Information Description
2 prices
Selected condition：

Brand

  • Sigma-Aldrich(India)

Package

  • 1G
  • 5G
  • ManufacturerSigma-Aldrich(India)
  • Product number404438
  • Product description(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine 98%
  • Packaging1G
  • Price₹5228.48
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number404438
  • Product description(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine 98%
  • Packaging5G
  • Price₹20015.43
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 404438 (S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine 98% 1G ₹5228.48 2022-06-14 Buy
Sigma-Aldrich(India) 404438 (S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine 98% 5G ₹20015.43 2022-06-14 Buy

Properties

Melting point :203-206 °C(lit.)
alpha :+305° (c 1, CH2Cl2)
Boiling point :619.74°C (rough estimate)
Density :1.0110 (rough estimate)
refractive index :1.5300 (estimate)
storage temp. :Inert atmosphere,Room Temperature
pka :13.06±0.40(Predicted)
form :Powder
color :yellow
optical activity :[α]20/D +315 to 15°, c = 1 in methylene chloride
BRN :5464823
InChIKey :FYNXDGNCEBQLGC-GTHUDTLPSA-N

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

A ligand used in the preparation of Jacobsen's catalyst which is suitable for enantioselective epoxidation of olefins lacking functional groups.

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Suppliers and manufacturers

Shanghai UCHEM Inc.
(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
₹47.00 /25g
(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine CAS:135616-36-3
Henan Fengda Chemical Co., Ltd
(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE
₹2.00 /1000kg
(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE CAS:135616-36-3
career henan chemical co
(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE
₹1.00 /1KG
(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE CAS:135616-36-3
Evans Fine Chem SOLFYN INTERNATIONAL LLP TCI Chemicals (India) Pvt. Ltd. CLEARSYNTH LABS LTD. A.J Chemicals
Chongqing Chemdad Co., Ltd
CONIER CHEM AND PHARMA LIMITED