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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organic manganese >(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE

(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE

(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Structure
  • ₹4200.1 - ₹28891.93
  • Product name: (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE
  • CAS: 135620-04-1
  • MF: C36H52ClMnN2O2
  • MW: 635.2
  • EINECS:
  • MDL Number:MFCD02101663
  • Synonyms:(+)-BIS(3,5-DI-T-BU-SALICYL.)-1,2-CYCLO- HEXANEDIAMINO-MN CL;(S,S)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYL- IDENE)-1,2-CYCLOHEXANEDIAMINO-MN-CL;(1S,2S)-(+)-(1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene))manganese(III)chloride;(S,S)-Jacobsencat.;(1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III)chloride,98%(S,S)-JacobsenCat.;(S,S)(+)N,N'-Bis(3,5-di-tbutylsalicylidene)1,2-chexanediaminomanganese(iii)chlorideco;(S,S)-(+)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chlo;(1S,2S)-(+)-[1,2-CyclohexanediaMino-N,N'-bis(3,5-di-t-butylsalicylidene)]Manganese(III) chloride (S,S)-Jacobsen Cat.
Price3 Properties Safety Information Description
3 prices
Selected condition：

Brand

  • Sigma-Aldrich(India)

Package

  • 1G
  • 5G
  • 25G
  • ManufacturerSigma-Aldrich(India)
  • Product number404454
  • Product description(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
  • Packaging1G
  • Price₹4200.1
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number404454
  • Product description(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
  • Packaging5G
  • Price₹12546.18
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number404454
  • Product description(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
  • Packaging25G
  • Price₹28891.93
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 404454 (S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 1G ₹4200.1 2022-06-14 Buy
Sigma-Aldrich(India) 404454 (S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 5G ₹12546.18 2022-06-14 Buy
Sigma-Aldrich(India) 404454 (S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 25G ₹28891.93 2022-06-14 Buy

Properties

Melting point :330-332 °C(lit.)
storage temp. :Inert atmosphere,Room Temperature
form :Powder
color :brown
InChIKey :VGAJDQCIDNCJQC-JINVCYSXSA-K
CAS DataBase Reference :135620-04-1

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Salen (Mn)-catalyzed asymmetric epoxidation of unfunctionalized olefins.High enantioselectivities and yields are obtained for a variety of substrates,especiallycis-alkenes. A few applications include the synthesis of the taxol side chainandcis-1-amino-2-indanol.Jacobsen′s catalyst has also been used in the asymmetricα-hydroxylation of silyl enol ethers.Catalyst for the enantioselective epoxidation of a variety of olefins.

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Suppliers and manufacturers

career henan chemical co
(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE
₹1.00 /1KG
(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE CAS:135620-04-1
Evans Fine Chem SOLFYN INTERNATIONAL LLP A.J Chemicals
Chongqing Chemdad Co., Ltd
CONIER CHEM AND PHARMA LIMITED
Neostar United (Changzhou) Industrial Co., Ltd.
Zhengzhou Alfa Chemical Co.,Ltd
Shanghai UCHEM Inc.
Shaanxi Dideu Medichem Co. Ltd