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loline

loline Structure
CAS No.
25161-91-5
Chemical Name:
loline
Synonyms
loline;Festucine;(2R,3aβ,6aβ)-Hexahydro-N-methyl-2α,4α-methano-4H-furo[3,2-b]pyrrol-3α-amine;2,4-Methano-4H-furo[3,2-b]pyrrol-3-amine, hexahydro-N-methyl-, (2R,3R,3aS,4S,6aS)-
CBNumber:
CB31364382
Molecular Formula:
C8H14N2O
Molecular Weight:
154.212
MOL File:
25161-91-5.mol
Modify Date:
2023/5/4 17:34:36
Request For Quotation

loline Properties

Boiling point 103 °C(Press: 5 Torr)
Density 1.20±0.1 g/cm3(Predicted)
pka 9.36±0.20(Predicted)

loline Chemical Properties,Uses,Production

Description

This oily alkaloid has been obtained from a species of grass, Lotium cuneatum Nevski. It has a density of D 20 1.1343 and a refractive index of n20D 1.5505. It behaves as a diacidic base yielding a series of well crystalline salts and derivatives, e.g. the dihydrochloride, m.p. 256-7°C; [α]15D + 6.2° (H20); dihydrobromide, m.p. 254-5°C (dec.); [α]20D + 3.5° (c 4.29, H20); dihydriodide, m.p. 233-5°C (dec.); [α]34D + 5.0° (c 13.2 H20); perchlorate, m.p. 282°C with almost explosive decomposition; sulphate, yellow needles, m.p. 250-2°C (dec.); mononitrate,m.p. 208-2l0°C; dinitrate, m.p. l48-9°C; [α]38D + 6.18° (c 6.94, H20); dipicrate, m.p. 258-260°C (dec.); methiodide, m.p. 2l0-loC and the N-nitroso derivative, m.p. 64°C. The N-acetyl derivative yields a crystalline hydrochloride, m.p. 197-8°C; [α]20D + 36.9° (H20) and the N-methyl compound is obtained as a colourless oil, b.p. 90-l oC/2 mm; [α]31D+ 9.31° (c 9.5, MeOH). The alkaloid possesses an ether oxygen bridging the pyrrolizidine moiety.

Hazard

A poison.

References

Yunusov, Akramov., J. Gen. Chern., USSR, 25, 1765 (1955)
Yunusov, Akramov., ibid, 30,699,705,3105 (1960)

loline Preparation Products And Raw materials

Raw materials

Preparation Products

loline Suppliers

Global( 6)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
TargetMol Chemicals Inc. +1-781-999-5354 United States 19973 58 Inquiry
Chengdu Push Bio-Technology Co., Ltd. 18080489829 China 9209 58 Inquiry
Sichuan BioCrick Biotech Co., Ltd 28-85433893 CHINA 4988 58 Inquiry
Wuhan ChemFaces Biochemical Co., Ltd. 18607101326 15172504745 China 7059 55 Inquiry
Supplier Advantage
TargetMol Chemicals Inc. 58
Chengdu Push Bio-Technology Co., Ltd. 58
Sichuan BioCrick Biotech Co., Ltd 58
Wuhan ChemFaces Biochemical Co., Ltd. 55

25161-91-5(loline)Related Search:

loline Morpholin-2-yl-methylamine (S)-2-Methyl-morpholine 3-Pyrrolidinamine,1-propyl-,(3S)- 2-ETHYLMORPHOLINE
3-Hydroxyazetidine hydrochloride METHYL-MORPHOLIN-2-YLMETHYL-AMINE (S)-3-METHOXYPYRROLIDINE ETHOXYPYRROLIDINE(S-3-)
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loline (2R,3aβ,6aβ)-Hexahydro-N-methyl-2α,4α-methano-4H-furo[3,2-b]pyrrol-3α-amine Festucine 2,4-Methano-4H-furo[3,2-b]pyrrol-3-amine, hexahydro-N-methyl-, (2R,3R,3aS,4S,6aS)- 25161-91-5