Julolidine
- CAS No.
- 479-59-4
- Chemical Name:
- Julolidine
- Synonyms
- JULOLIDINE;Julolidine>Julolidine,98%;Julolidine, 98% 25GR;Julolidine USP/EP/BP;Julolidine>97.0%(GC&T);5h-benzo[ij]quinolizine,2,3,6,7-tetrahydro-1;2,3,6,7-TETRAHYDRO-1H,5H-BENZO[IJ]QUINOLIZINE;1,2,3,5,6,7-Hexahydropyrido[3,2,1-ij]quinoline;2,3,6,7-Tetrahydro-1H,5H-benzop[ij]quinolizine
- CBNumber:
- CB3167092
- Molecular Formula:
- C12H15N
- Molecular Weight:
- 173.25
- MOL File:
- 479-59-4.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/5/15 10:43:23
| Melting point | 34-36 °C(lit.) |
|---|---|
| Boiling point | 170-173°C 31mm |
| Density | 1.0030 |
| refractive index | 1.5680 |
| Flash point | >230 °F |
| storage temp. | 2-8°C |
| solubility | Chloroform (Slightly), Ethyl Acetate (Slightly) |
| form | Liquid After Melting |
| pka | 6.54±0.20(Predicted) |
| color | Clear yellow to orange-brown |
| Water Solubility | Soluble in toluene. Insoluble in water. |
| Sensitive | Air Sensitive |
| BRN | 139925 |
| InChIKey | DZFWNZJKBJOGFQ-UHFFFAOYSA-N |
| CAS DataBase Reference | 479-59-4(CAS DataBase Reference) |
| NIST Chemistry Reference | Julolidine(479-59-4) |
| EPA Substance Registry System | 1H,5H-Benzo[ij]quinolizine, 2,3,6,7-tetrahydro- (479-59-4) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P305+P351+P338 | |||||||||
| Risk Statements | 52/53 | |||||||||
| Safety Statements | 24/25-61 | |||||||||
| WGK Germany | 3 | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 29339900 | |||||||||
| NFPA 704 |
|
Julolidine price More Price(4)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | J1001 | Julolidine 97% | 479-59-4 | 5G | ₹3900 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | J1001 | Julolidine 97% | 479-59-4 | 25G | ₹13680 | 2022-06-14 | Buy |
| TCI Chemicals (India) | J0007 | Julolidine min. 97.0 % | 479-59-4 | 5G | ₹8400 | 2022-05-26 | Buy |
| TCI Chemicals (India) | J0007 | Julolidine min. 97.0 % | 479-59-4 | 25G | ₹34300 | 2022-05-26 | Buy |
Julolidine Chemical Properties,Uses,Production
Chemical Properties
CLEAR YELLOW TO ORANGE-BROWN LIQUID AFTER MELTING
Uses
Julolidine used as amine building block and in chemoluminescent dye. Also used in photoconductive materials, chemiluminescence substances, chromogenic substrates in analytical redox reactions, dye intermediates, potential antidepressants and tranquilizers, nonlinear optical materials, high sensitivity photopolymerizable materials, and for improving color stability in photography.
Purification Methods
Purify julolidine by dissolving it in dilute HCl, steam is bubbled through the solution and the residual acidic solution is basified with 10N NaOH, extracted with Et2O, washed with H2O, dried (NaOH pellets), filtered, evaporated and distilled in vacuo. The distillate crystallises on cooling (m 39-40o). It develops a red colour on standing in contact with air for several days. The colour can be removed by distilling or dissolving in 2-3 parts of hexane, adding charcoal, filtering and cooling in an Me2CO/Dry-ice bath when julolidine crystallises out (85-90% yield m 39-40o). The hydrobromide [83646-41-7] has m 218o (239-242o), the picrate has m 174o(165o) and the methiodide crystallises from MeOH, with m 186o [Glass & Weisberger Org Synth Coll Vol III 504 1955, Smith & Yu J Org Chem 17 1285 1952, Beilstein 20 H 332, 20 I 133, 20 II 214, 20 III/IV 3281.] Highly TOXIC.
Julolidine Preparation Products And Raw materials
Raw materials
1of2
chevron_rightPreparation Products
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| GLR Innovations | +91 9891111994 | New Delhi, India | 4542 | 58 | Inquiry |
| Dr. Silviu Pharmachem Pvt., Ltd. | +91-8390608382 +91-8390608382 | Mumbai, India | 248 | 58 | Inquiry |
| Eburon Organics (I) Pvt, Ltd | +91 260 240 0894 | Gujarat, India | 114 | 58 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| CHEMSWORTH | +91-261-2397244 | New Delhi, India | 6707 | 30 | Inquiry |
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
| Dr. Silviu Pharmachem Pvt., Ltd. (DRSPL) | 91-9665522151 | Maharashtra, India | 143 | 58 | Inquiry |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | China | 9338 | 55 | Inquiry |
| career henan chemical co | +86-0371-86658258 +8613203830695 | China | 29826 | 58 | Inquiry |
| Shanghai Rlavie Technology Co ltd | +86-021-67759270 +8617717059219 | China | 1030 | 58 | Inquiry |