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Allyltributyltin

Allyltributyltin Structure
CAS No.
24850-33-7
Chemical Name:
Allyltributyltin
Synonyms
ALLYLTRIBUTYLSTANNANE;ALLYLTRI-N-BUTYLTIN;Tributylallylstannane;allyltri-n-butylstannane;2-Propenyltributylstannane;TRIBUTYL-2-PROPENYLSTANNANE;SKL1093;ALLYLTRIBUTYLTIN;Allytri-N-Butyltin;allyitri-n-butyltin
CBNumber:
CB3257937
Molecular Formula:
C15H32Sn
Molecular Weight:
331.12
MOL File:
24850-33-7.mol
Modify Date:
2023/5/15 10:43:51

Allyltributyltin Properties

Melting point 134-135 °C
Boiling point 88-92 °C0.2 mm Hg(lit.)
Density 1.068 g/mL at 25 °C(lit.)
refractive index n20/D 1.486(lit.)
Flash point >230 °F
storage temp. 2-8°C
solubility Chloroform (Slightly), Methanol (Slightly)
form Liquid
color Clear colorless
Specific Gravity 1.068
Water Solubility Immiscible with water.
Sensitive Air Sensitive
Hydrolytic Sensitivity 1: no significant reaction with aqueous systems
BRN 3588340
Exposure limits ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3
Stability Air Sensitive
InChIKey YLGRTLMDMVAFNI-UHFFFAOYSA-N
CAS DataBase Reference 24850-33-7(CAS DataBase Reference)
NIST Chemistry Reference Allyltributyltin(24850-33-7)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H301-H312-H315-H319-H360FD-H372-H410
Precautionary statements  P201-P273-P280-P301+P310-P302+P352+P312-P305+P351+P338
Hazard Codes  T,N
Risk Statements  21-25-36/38-48/23/25-50/53-23/24/25
Safety Statements  35-36/37/39-45-60-61-28-27-26
RIDADR  UN 2788 6.1/PG 2
WGK Germany  3
13
TSCA  No
HazardClass  6.1
PackingGroup  II
HS Code  29319019
NFPA 704
0
3 0

Allyltributyltin price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 271411 Allyltributylstannane 97% 24850-33-7 5G ₹2608.83 2022-06-14 Buy
Sigma-Aldrich(India) 271411 Allyltributylstannane 97% 24850-33-7 25G ₹4351.65 2022-06-14 Buy
Sigma-Aldrich(India) 271411 Allyltributylstannane 97% 24850-33-7 100G ₹19322.63 2022-06-14 Buy
ALFA India ALF-L14087-14 Allyltri-n-butyltin, 97% 24850-33-7 25g ₹7796 2022-05-26 Buy
ALFA India ALF-L14087-06 Allyltri-n-butyltin, 97% 24850-33-7 5g ₹2575 2022-05-26 Buy
Product number Packaging Price Buy
271411 5G ₹2608.83 Buy
271411 25G ₹4351.65 Buy
271411 100G ₹19322.63 Buy
ALF-L14087-14 25g ₹7796 Buy
ALF-L14087-06 5g ₹2575 Buy

Allyltributyltin Chemical Properties,Uses,Production

Chemical Properties

CLEAR COLOURLESS LIQUID

Uses

Allylation reagent for aldehydes catalyzed by chiral Lewis acids1,2 and ytterbium(III) trifluoromethanesulfonate (cat. no. 430595).3 Undergoes tetrakis(triphenylphosphine)palladium(0) (cat. no. 216666) catalyzed coupling with iodoquinones4 and allyl acetates.5,6Efficient allylation of aldehydes leading to homoallylic alcohols with trichloro-1,3,5-triazene.7

Purification Methods

A possible impurity is tributylchlorostannane — test for Cl as Cl ion after hydrolysing. Dissolve it in *C6H6 (or toluene), shake this with dilute aqueous NaOH, dry (CaCl2), filter, evaporate and distil the residue in a vacuum [Jones et al. J Chem Soc 1446 1947, Bristow Aldrichimica Acta 17 75 1984, Yamamoto Aldrichimica Acta 20 45 1987]. [Beilstein 4 IV 4317.]

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Stannane, tributyl-2-propenyl- ALLYLTRIBUTYLTIN ALLYLTRIBUTYLTIN(IV) Allytri-N-Butyltin Allyltri-n-butyltin,97% (2-Propenyl)tributylstannane Allyltributyltin,97% Allyltributyltin(Ⅳ) allyitri-n-butyltin tri-n-butyl-2-propenylstannane Allyltributylstannane 97% The threebutyltinpropenyl Allyltributyltin, 97% 1GR (Prop-2-en-1-yl)tributyl stannane, 3-(Tributylstannyl)prop-1-ene 3-(Tributylstannyl)prop-1-ene Stannane, tributyl-2-propen-1-yl- Allyltributyltin ISO 9001:2015 REACH SKL1093 tributyl(prop-2-enyl)stannane ALLYLTRIBUTYLSTANNANE ALLYLTRI-N-BUTYLTIN TRIBUTYL-2-PROPENYLSTANNANE 2-Propenyltributylstannane Tributylallylstannane allyltri-n-butylstannane ributyl(prop-2-enyl)stannane Allyl Tri n-butyl tin /stannane 24850-33-7 CH2CHCH2SnCH2CH2CH2CH33 Classes of Metal Compounds Alkyl Metals Sn (Tin) Compounds Typical Metal Compounds Grignard Reagents & Alkyl Metals Organotin Organotins Organometallic Reagents Organotins Stannanes Chemical Synthesis Organometallic Reagents Alkyl Metals Sn (Tin) Compounds Classes of Metal Compounds Grignard Reagents & Alkyl Metals Synthetic Organic Chemistry Typical Metal Compounds Organometallic Reagents Organotin