Allyltributyltin
- CAS No.
- 24850-33-7
- Chemical Name:
- Allyltributyltin
- Synonyms
- ALLYLTRIBUTYLSTANNANE;ALLYLTRI-N-BUTYLTIN;Tributylallylstannane;allyltri-n-butylstannane;2-Propenyltributylstannane;TRIBUTYL-2-PROPENYLSTANNANE;SKL1093;ALLYLTRIBUTYLTIN;Allytri-N-Butyltin;allyitri-n-butyltin
- CBNumber:
- CB3257937
- Molecular Formula:
- C15H32Sn
- Molecular Weight:
- 331.12
- MOL File:
- 24850-33-7.mol
- Modify Date:
- 2023/5/15 10:43:51
Melting point | 134-135 °C |
---|---|
Boiling point | 88-92 °C0.2 mm Hg(lit.) |
Density | 1.068 g/mL at 25 °C(lit.) |
refractive index |
n |
Flash point | >230 °F |
storage temp. | 2-8°C |
solubility | Chloroform (Slightly), Methanol (Slightly) |
form | Liquid |
color | Clear colorless |
Specific Gravity | 1.068 |
Water Solubility | Immiscible with water. |
Sensitive | Air Sensitive |
Hydrolytic Sensitivity | 1: no significant reaction with aqueous systems |
BRN | 3588340 |
Exposure limits |
ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin) NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3 |
Stability | Air Sensitive |
InChIKey | YLGRTLMDMVAFNI-UHFFFAOYSA-N |
CAS DataBase Reference | 24850-33-7(CAS DataBase Reference) |
NIST Chemistry Reference | Allyltributyltin(24850-33-7) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS06,GHS08,GHS09 |
|||||||||
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Signal word | Danger | |||||||||
Hazard statements | H301-H312-H315-H319-H360FD-H372-H410 | |||||||||
Precautionary statements | P201-P273-P280-P301+P310-P302+P352+P312-P305+P351+P338 | |||||||||
Hazard Codes | T,N | |||||||||
Risk Statements | 21-25-36/38-48/23/25-50/53-23/24/25 | |||||||||
Safety Statements | 35-36/37/39-45-60-61-28-27-26 | |||||||||
RIDADR | UN 2788 6.1/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
F | 13 | |||||||||
TSCA | No | |||||||||
HazardClass | 6.1 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29319019 | |||||||||
NFPA 704 |
|
Allyltributyltin price More Price(5)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 271411 | Allyltributylstannane 97% | 24850-33-7 | 5G | ₹2608.83 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 271411 | Allyltributylstannane 97% | 24850-33-7 | 25G | ₹4351.65 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 271411 | Allyltributylstannane 97% | 24850-33-7 | 100G | ₹19322.63 | 2022-06-14 | Buy |
ALFA India | ALF-L14087-14 | Allyltri-n-butyltin, 97% | 24850-33-7 | 25g | ₹7796 | 2022-05-26 | Buy |
ALFA India | ALF-L14087-06 | Allyltri-n-butyltin, 97% | 24850-33-7 | 5g | ₹2575 | 2022-05-26 | Buy |
Allyltributyltin Chemical Properties,Uses,Production
Chemical Properties
CLEAR COLOURLESS LIQUID
Uses
Allylation reagent for aldehydes catalyzed by chiral Lewis acids1,2 and ytterbium(III) trifluoromethanesulfonate (cat. no. 430595).3 Undergoes tetrakis(triphenylphosphine)palladium(0) (cat. no. 216666) catalyzed coupling with iodoquinones4 and allyl acetates.5,6Efficient allylation of aldehydes leading to homoallylic alcohols with trichloro-1,3,5-triazene.7
Purification Methods
A possible impurity is tributylchlorostannane — test for Cl as Cl ion after hydrolysing. Dissolve it in *C6H6 (or toluene), shake this with dilute aqueous NaOH, dry (CaCl2), filter, evaporate and distil the residue in a vacuum [Jones et al. J Chem Soc 1446 1947, Bristow Aldrichimica Acta 17 75 1984, Yamamoto Aldrichimica Acta 20 45 1987]. [Beilstein 4 IV 4317.]
Allyltributyltin Preparation Products And Raw materials
Raw materials
Preparation Products
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GLR Innovations | +91 9891111994 | New Delhi, India | 4542 | 58 | Inquiry |
VASISTA LIFE SCIENCES PRIVATE LIMITED | +91-04029554774 +91-9010855544 | Hyderabad, India | 153 | 58 | Inquiry |
Sri Neelima Laboratories | +91-7981733602 +91-9849736989 | Telangana, India | 205 | 58 | Inquiry |
Ms Life Sciences | 08048372386Ext 826 | Hyderabad, India | 341 | 58 | Inquiry |
CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6351 | 58 | Inquiry |
A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
OCEAN TRADING CORPORATION | +91(22) 24921669 | New Delhi, India | 6211 | 58 | Inquiry |
Nanjing Kaitian Chemical Co., LTD | +undefined13337835376 | China | 40 | 58 | Inquiry |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | China | 21669 | 55 | Inquiry |
Supplier | Advantage |
---|---|
GLR Innovations | 58 |
VASISTA LIFE SCIENCES PRIVATE LIMITED | 58 |
Sri Neelima Laboratories | 58 |
Ms Life Sciences | 58 |
CLEARSYNTH LABS LTD. | 58 |
A.J Chemicals | 58 |
Alfa Aesar | 58 |
OCEAN TRADING CORPORATION | 58 |
Nanjing Kaitian Chemical Co., LTD | 58 |
Henan Tianfu Chemical Co.,Ltd. | 55 |
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