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Allyltriphenylphosphonium bromide

CAS No.: 1560-54-9

Chemical Name:: Allyltriphenylphosphonium bromide

Synonyms: TAL;triphenyl(prop-2-en-1-yl)phosphaniuM broMide;NSC 59815;NSC 110609;allyltriphenylphosphonium;allyltriphenyl-phosphoniubromide;Allytriphenylphosphonium bromide;allyl triphenylphosphine bromide;Triphenylallylphosphonium bromide;ALLYLTRIPHENYLPHOSPHONIUM BROMIDE

CBNumber:: CB4381501

Molecular Formula:: C21H20BrP

Molecular Weight:: 383.26

MOL File:: 1560-54-9.mol

MSDS File:: SDS

Modify Date:: 2023/4/23 13:52:06

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Allyltriphenylphosphonium bromide Properties

Melting point	222-225 °C (lit.)
storage temp.	Sealed in dry,Room Temperature
form	Powder
color	White
Water Solubility	decomposes
Sensitive	Hygroscopic
BRN	3579053
InChI	InChI=1S/C21H20P.BrH/c1-2-18-22(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21;/h2-17H,1,18H2;1H/q+1;/p-1
InChIKey	FWYKRJUVEOBFGH-UHFFFAOYSA-M
SMILES	[P+](CC=C)(C1C=CC=CC=1)(C1=CC=CC=C1)C1C=CC=CC=1.[Br-]
CAS DataBase Reference	1560-54-9(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P280a-P304+P340-P305+P351+P338-P405-P501a-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313

Hazard Codes

Risk Statements

36/37/38

Safety Statements

26-37/39

WGK Germany

RTECS

TA1843000

HS Code

29310095

Toxicity

mouse,LD50,intravenous,22mg/kg (22mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#01708,

NFPA 704

	0
2		0

Allyltriphenylphosphonium bromide price More Price(4)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich(India)	A36603	Allyltriphenylphosphonium bromide 99%	1560-54-9	100G	₹6590	2022-06-14	Buy
ALFA India	ALF-A14490-30	Allyltriphenylphosphonium bromide, 99%	1560-54-9	250g	₹14414	2022-05-26	Buy
ALFA India	ALF-A14490-18	Allyltriphenylphosphonium bromide, 99%	1560-54-9	50g	₹2749	2022-05-26	Buy
TCI Chemicals (India)	A1007	Allyltriphenylphosphonium Bromide	1560-54-9	25G	₹5500	2022-05-26	Buy

Product number	Packaging	Price	Buy
A36603	100G	₹6590	Buy
ALF-A14490-30	250g	₹14414	Buy
ALF-A14490-18	50g	₹2749	Buy
A1007	25G	₹5500	Buy

Allyltriphenylphosphonium bromide Chemical Properties,Uses,Production

Chemical Properties

white crystalline powder

Uses

Allyltriphenylphosphonium bromide is used for the first time in the preparation of DES. It has been shown to be part of Phosphonium salts, having antiviral activity against influenza virus A. It can be used in witting olefination of aldehydes for preparation of conjugated dienes.

Preparation

Allyltriphenylphosphonium bromide was synthesized from the reaction of triphenylphosphine and allyl bromide in dry toluene.

Application

Reactant for:
Preparation of a diol and carbamate chemistry library for common functional groups
Regioselective synthesis of alkenes via semihydrogenation and semihydrogenation-oxidation of dienes
Alkene addition of frustrated Lewis pairs
Olefination of N-sulfonyl imines for stereoselective synthesis of vinyl arenes
Wittig olefination of aldehydes for preparation of conjugated dienes
Tandem Michael addition / ylide olefination reactions for the synthesis of highly functionalized cyclohexadienes
Reaction of allyltriphenylphosphonium bromide and Garner's aldehyde in basic media provided β- hydroxy-1,3-dienes.
Methyl 3-(buta-1,3-dienyl)benzoate
1-(Buta-1,3-dienyl)-4-(trifluoromethyl)benzene
1-(Buta-1,3-dienyl)-2-chlorobenzene
1-Bromo-4-(buta-1,3-dienyl)benzene
Buta-1,3-dienylbenzene

Allyltriphenylphosphonium bromide Preparation Products And Raw materials

Raw materials

Triphenylphosphine Allyl bromide Toluene

Preparation Products

1,3-Hexadien-5-yne. (7Z,9E)-dodeca-7,9-dienyl acetate

Allyltriphenylphosphonium bromide Suppliers

Global( 215)Suppliers

Supplier	Tel	Country	ProdList	Advantage	Inquiry
Alfa Aesar	1 800 209 7001	Maharashtra, India	6913	58	Inquiry
VASIN BIO LIFE SCIENCES PVT LTD	9491644688	Hyderabad, India	2096	58	Inquiry
CHEMSWORTH	+91-261-2397244	New Delhi, India	6707	30	Inquiry
TCI Chemicals (India) Pvt. Ltd.	1800 425 7889	New Delhi, India	6778	58	Inquiry
TCI Europe	320-37350700	Europe	23680	75	Inquiry
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	China	32760	60	Inquiry
career henan chemical co	+86-0371-86658258 +8613203830695	China	29896	58	Inquiry
Chongqing Chemdad Co., Ltd	+86-023-6139-8061 +86-86-13650506873	China	39916	58	Inquiry
CONIER CHEM AND PHARMA LIMITED	+8618523575427	China	49391	58	Inquiry
Shaanxi Dideu Medichem Co. Ltd	18192627656	China	2907	58	Inquiry

Supplier	Advantage
Alfa Aesar	58
VASIN BIO LIFE SCIENCES PVT LTD	58
CHEMSWORTH	30
TCI Chemicals (India) Pvt. Ltd.	58
TCI Europe	75
ATK CHEMICAL COMPANY LIMITED	60
career henan chemical co	58
Chongqing Chemdad Co., Ltd	58
CONIER CHEM AND PHARMA LIMITED	58
Shaanxi Dideu Medichem Co. Ltd	58

Allyltriphenylphosphonium bromide Spectrum

Allyltriphenylphosphonium bromide(1560-54-9)MS Allyltriphenylphosphonium bromide(1560-54-9)¹HNMR Allyltriphenylphosphonium bromide(1560-54-9)IR1 Allyltriphenylphosphonium bromide(1560-54-9)IR2 Allyltriphenylphosphonium bromide(1560-54-9)Raman

1560-54-9(Allyltriphenylphosphonium bromide)Related Search:

Triphenylphosphine hydrobromide Dimidium bromide TETRAPHENYLPHOSPHINE IMIDE Triphenylphosphine Rocuronium bromide

Tetraphenylphosphonium bromide Triphenylphosphine oxide Tris(triphenylphosphine)rhodiu Tetrakis(triphenylphosphine)palladium Sodium bromate

Vecuronium bromide Tetrapropylammonium bromide Allyl bromide Methyltriphenylphosphonium bromide Ethidium bromide

Allyl triphenylphosphonium chloride ALLYLTRIPHENYLTIN Allyltrimethylsilane

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NSC 59815 Allyltriphenylphosphonium bromide 99% ALLYLTRIPHENYLPHOSPHONIUM BROMIDE allyltriphenyl-phosphoniubromide allyltriphenylphosphonium Allyltriphenylphosphoniumbromide,99% Phosphonium, triphenyl-2-propenyl-, bromide 2-Propenyltriphenylphosphonium bromide Triphenyl(2-propenyl)phosphonium bromide Triphenylallylphosphonium bromide Triphenyl-prop-2-enylphosphanium bromide ALLYLTRIPHENYLPHOSPHONIUM BROMIDE (TAL) Allytriphenylphosphonium bromide ALLYLTRIPHENYLPHOSPHONIUM BROMIDE FOR SY NSC 110609 AllyltriphenylphosphoniumBromide> allyl triphenylphosphine bromide Phosphonium, triphenyl-2-propen-1-yl-, bromide (1:1) triphenyl(prop-2-enyl)phosphanium Phosphonium,triphenyl-2-propen-1-yl-, bromide triphenyl(prop-2-enyl)phosphonium bromide triphenyl(prop-2-en-1-yl)phosphaniuM broMide TAL 1560-54-9 C21H20BrP CH2CHCH2C6H53PBr H2CCHCH2PC6H53Br C21H20P Wittig Reaction Wittig & Horner-Emmons Reaction Phosphonium Compounds C-C Bond Formation Synthetic Reagents Wittig Reagents Olefination organophosphorus compound Pharmaceutical Intermediates Phosphonium Compounds Synthetic Organic Chemistry Wittig & Horner-Emmons Reaction Wittig Reaction C-C Bond Formation Olefination Wittig Reagents