Allyltriphenylphosphonium bromide

- CAS No.
- 1560-54-9
- Chemical Name:
- Allyltriphenylphosphonium bromide
- Synonyms
- TAL;triphenyl(prop-2-en-1-yl)phosphaniuM broMide;NSC 59815;NSC 110609;allyltriphenylphosphonium;allyltriphenyl-phosphoniubromide;Allytriphenylphosphonium bromide;allyl triphenylphosphine bromide;Triphenylallylphosphonium bromide;ALLYLTRIPHENYLPHOSPHONIUM BROMIDE
- CBNumber:
- CB4381501
- Molecular Formula:
- C21H20BrP
- Molecular Weight:
- 383.26
- MOL File:
- 1560-54-9.mol
- MSDS File:
- SDS
- Modify Date:
- 2025/1/27 9:38:02
Melting point | 222-225 °C (lit.) |
---|---|
storage temp. | Sealed in dry,Room Temperature |
form | Powder |
color | White |
Water Solubility | decomposes |
Sensitive | Hygroscopic |
BRN | 3579053 |
InChI | InChI=1S/C21H20P.BrH/c1-2-18-22(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21;/h2-17H,1,18H2;1H/q+1;/p-1 |
InChIKey | FWYKRJUVEOBFGH-UHFFFAOYSA-M |
SMILES | [P+](CC=C)(C1C=CC=CC=1)(C1=CC=CC=C1)C1C=CC=CC=1.[Br-] |
CAS DataBase Reference | 1560-54-9(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS07 |
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Signal word | Warning | |||||||||
Hazard statements | H315-H319-H335 | |||||||||
Precautionary statements | P261-P280a-P304+P340-P305+P351+P338-P405-P501a-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313 | |||||||||
Hazard Codes | Xi | |||||||||
Risk Statements | 36/37/38 | |||||||||
Safety Statements | 26-37/39 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | TA1843000 | |||||||||
HS Code | 29310095 | |||||||||
Toxicity | mouse,LD50,intravenous,22mg/kg (22mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#01708, | |||||||||
NFPA 704 |
|
Allyltriphenylphosphonium bromide price More Price(4)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | A36603 | Allyltriphenylphosphonium bromide 99% | 1560-54-9 | 100G | ₹6590 | 2022-06-14 | Buy |
ALFA India | ALF-A14490-30 | Allyltriphenylphosphonium bromide, 99% | 1560-54-9 | 250g | ₹14414 | 2022-05-26 | Buy |
ALFA India | ALF-A14490-18 | Allyltriphenylphosphonium bromide, 99% | 1560-54-9 | 50g | ₹2749 | 2022-05-26 | Buy |
TCI Chemicals (India) | A1007 | Allyltriphenylphosphonium Bromide | 1560-54-9 | 25G | ₹5500 | 2022-05-26 | Buy |
Allyltriphenylphosphonium bromide Chemical Properties,Uses,Production
Chemical Properties
white crystalline powder
Uses
Allyltriphenylphosphonium bromide is used for the first time in the preparation of DES. It has been shown to be part of Phosphonium salts, having antiviral activity against influenza virus A. It can be used in witting olefination of aldehydes for preparation of conjugated dienes.
Preparation
Allyltriphenylphosphonium bromide was synthesized from the reaction of triphenylphosphine and allyl bromide in dry toluene.
Application
Reactant for:
Preparation of a diol and carbamate chemistry library for common functional groups
Regioselective synthesis of alkenes via semihydrogenation and semihydrogenation-oxidation of dienes
Alkene addition of frustrated Lewis pairs
Olefination of N-sulfonyl imines for stereoselective synthesis of vinyl arenes
Wittig olefination of aldehydes for preparation of conjugated dienes
Tandem Michael addition / ylide olefination reactions for the synthesis of highly functionalized cyclohexadienes
Reaction of allyltriphenylphosphonium bromide and Garner's aldehyde in basic media provided β- hydroxy-1,3-dienes.
Methyl 3-(buta-1,3-dienyl)benzoate
1-(Buta-1,3-dienyl)-4-(trifluoromethyl)benzene
1-(Buta-1,3-dienyl)-2-chlorobenzene
1-Bromo-4-(buta-1,3-dienyl)benzene
Buta-1,3-dienylbenzene
Allyltriphenylphosphonium bromide Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6905 | 58 | Inquiry |
VASIN BIO LIFE SCIENCES PVT LTD | 9491644688 | Hyderabad, India | 2092 | 58 | Inquiry |
CHEMSWORTH | +91-261-2397244 | New Delhi, India | 6700 | 30 | Inquiry |
TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6768 | 58 | Inquiry |
TCI Europe | 320-37350700 | Europe | 23671 | 75 | Inquiry |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | China | 33024 | 60 | Inquiry |
career henan chemical co | +86-0371-86658258 +8613203830695 | China | 29859 | 58 | Inquiry |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 | China | 49732 | 58 | Inquiry |
Shaanxi Dideu Medichem Co. Ltd | +86-29-81139210 +86-18192627656 | China | 3003 | 58 | Inquiry |
Fuxin Pharmaceutical | +86-021-021-50872116 +8613122107989 | China | 10035 | 58 | Inquiry |
Supplier | Advantage |
---|---|
Alfa Aesar | 58 |
VASIN BIO LIFE SCIENCES PVT LTD | 58 |
CHEMSWORTH | 30 |
TCI Chemicals (India) Pvt. Ltd. | 58 |
TCI Europe | 75 |
ATK CHEMICAL COMPANY LIMITED | 60 |
career henan chemical co | 58 |
CONIER CHEM AND PHARMA LIMITED | 58 |
Shaanxi Dideu Medichem Co. Ltd | 58 |
Fuxin Pharmaceutical | 58 |
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