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Sodium bromate

Sodium bromate Structure
CAS No.
7789-38-0
Chemical Name:
Sodium bromate
Synonyms
BROMIDE;dyetone;SODIUM BROMATE;bromatedesodium;SodiuM broMated;neutralizerk-126;neutralizerk-140;neutralizerk-938;BROMIDE STANDARD;SODIUM BROMIDE 45
CBNumber:
CB6181002
Molecular Formula:
BrNaO3
Molecular Weight:
150.89
MOL File:
7789-38-0.mol
Modify Date:
2023/12/28 15:52:49

Sodium bromate Properties

Melting point 755 °C(lit.)
Boiling point 1390 °C
Density 3.339 g/mL at 25 °C (lit.)
vapor pressure 1 mm Hg ( 806 °C)
refractive index 1.594
storage temp. Store below +30°C.
solubility H2O: 1 M at 20 °C, clear, colorless
form Powder/Solid
Specific Gravity 3.34
color White
PH Range 5 - 9
PH 5.0-9.0 (25℃, 50mg/mL in H2O)
Water Solubility 364 g/L (20 ºC)
Merck 14,8593
Stability Stable. Oxidizer. Incompatible with finely powdered metals, alcohols, strong acids, strong reducing agents.
InChIKey XUXNAKZDHHEHPC-UHFFFAOYSA-M
CAS DataBase Reference 7789-38-0(CAS DataBase Reference)
EPA Substance Registry System Sodium bromate (7789-38-0)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS03,GHS06
Signal word  Danger
Hazard statements  H271-H301-H315-H319-H335
Precautionary statements  P210-P220-P261-P301+P310-P302+P352-P305+P351+P338
Hazard Codes  O,Xn,Xi
Risk Statements  8-22-36/37/38-9-36/37
Safety Statements  17-26-36-37/39
RIDADR  UN 1494 5.1/PG 2
WGK Germany  3
RTECS  VZ3150000
3
Hazard Note  Oxidising Agent/Harmful
TSCA  Yes
HS Code  2829 90 40
HazardClass  5.1
PackingGroup  II
Toxicity LD50 orally in Rabbit: 400 mg/kg
NFPA 704
1
1 2
OX

Sodium bromate price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 8.14368 Sodium bromate for synthesis 7789-38-0 1KG ₹6370 2022-06-14 Buy
Sigma-Aldrich(India) 8.14368 Sodium bromate for synthesis 7789-38-0 250G ₹7160 2022-06-14 Buy
Sigma-Aldrich(India) 8.14368 Sodium bromate for synthesis 7789-38-0 7.5KG ₹29560 2022-06-14 Buy
Sigma-Aldrich(India) 8.14368 Sodium bromate for synthesis 7789-38-0 25KG ₹77470 2022-06-14 Buy
Sigma-Aldrich(India) 71325 Sodium bromate puriss. p.a., ≥99.5% (RT) 7789-38-0 250G ₹6614.08 2022-06-14 Buy
Product number Packaging Price Buy
8.14368 1KG ₹6370 Buy
8.14368 250G ₹7160 Buy
8.14368 7.5KG ₹29560 Buy
8.14368 25KG ₹77470 Buy
71325 250G ₹6614.08 Buy

Sodium bromate Chemical Properties,Uses,Production

Chemical Properties

Sodium bromate is a colorless or white crystalline solid. Odorless.

Uses

The bromates of chief industrial interest are those of sodium and potassium. Sodium bromate is used in mixtures with sodium bromide to extract gold from ore. It is also used as an analytical reagent, as a cleaning agent for boilers, and as a component in hair-waving formulations. Potassium bromate is used primarily as a conditioner for flour and dough; some of its nonfood uses include use as an oxidizing agent for analytic chemistry and as a brominating agent. The bromates of calcium and barium have limited use as oxidizers, maturing agents in flour, and analytic reagents.

Definition

ChEBI: An inorganic sodium salt having bromate as the counterion.

General Description

A white crystalline solid. May explode under prolonged exposure to heat or fire. Used in chemical analysis.

Air & Water Reactions

Water soluble.

Reactivity Profile

Sodium bromate is an oxidizing agent. May react violently with combustibles and reducing agents. Reacts with textiles, oil, fat, grease, sugar, sawdust and ammonium salts, carbon, phosphorus, metal powders and sulfides with hazard of fire and explosion [Handling Chemicals Safely 1980 p. 831]. A mixture of finely divided aluminum with finely divided Sodium bromate explodes by heat, percussion, and friction [Mellor 2:310 1946-47].

Hazard

Oxidizing material, dangerous fire risk near organic materials. Toxic by ingestion.

Health Hazard

Toxic by ingestion. Inhalation of dust is toxic. Fire may produce irritating, corrosive and/or toxic gases. Contact with substance may cause severe burns to skin and eyes. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

These substances will accelerate burning when involved in a fire. May explode from heat or contamination. Some may burn rapidly. Some will react explosively with hydrocarbons (fuels). May ignite combustibles (wood, paper, oil, clothing, etc.). Containers may explode when heated. Runoff may create fire or explosion hazard.

Safety Profile

Poison by ingestion, intravenous, subcutaneous, and intraperitoneal routes. A powerful oxidizer. Violent reactions with Al, As, C, Cu, oil, F2, metal sulfides, organic matter, P, S. lxtures with grease are shock-sensitive explosives at 120’C. When heated to decomposition it emits toxic fumes of Na2O and Br-. See also BROMATES.

Potential Exposure

Used for research and development; as an analytical reagent; for separating gold from ores; making vat dyes; boiler cleaning.

Shipping

UN1494 Sodium bromate, Hazard Class: 5.1; Labels: 5.1-Oxidizer. UN1450 Bromates, inorganic, n.o.s., Hazard Class: 5.1; Labels: 5.1-Oxidizer, Technical Name Required.

Purification Methods

It is crystallised from hot water (1.1mL/g) to decrease contamination by NaBr, bromine and hypobromite. [Noszticzius et al. J Am Chem Soc 107 2314 1985.]

Incompatibilities

Dust may form explosive mixture with air. A strong oxidizer capable of increasing the intensity of an existing fire. Can react, possibly violently, with combustible, organic, or other oxidizable materials, alcohols, glycols, reducing agents, strong acids, finely divided metals, especially aluminum. Contamination with carbon, organic matter, and finely divided metal can cause sodium bromate become shock-sensitive. Decomposes at 381C. Sodium bromate may explode in heat of fire.

Waste Disposal

SRP: The most favorable course of action is to use an alternative chemical product with less inherent propensity for occupational exposure or environmental contamination. Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material’s impact on air quality; potential migration in soil or water; effects on animal, aquatic, and plant life; and conformance with environmental and public health regulations. See also Sigma-Aldridge data sheet (Sodium Bromate .99%).

Global( 303)Suppliers
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