ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Phosphine ligand >Methyltriphenylphosphonium bromide

Methyltriphenylphosphonium bromide

Methyltriphenylphosphonium bromide Structure
CAS No.
1779-49-3
Chemical Name:
Methyltriphenylphosphonium bromide
Synonyms
TRIPHENYLMETHYLPHOSPHONIUM BROMIDE;MTPPB;Methyltriphenylphosphanium bromide;Methyltriphenylphosphine bromide;Bromo(methyl)triphenylphosphorane;Methyl Triphenyl Phosphonium Bromide (MTPBB);Methyl triphenyl pho;Methy triphenylphosphonium;Triphenyl phosphate bromide;Methyltriphenyl bromide PHOSPH
CBNumber:
CB1137882
Molecular Formula:
C19H18BrP
Molecular Weight:
357.22
MOL File:
1779-49-3.mol
MSDS File:
SDS
Modify Date:
2024/8/21 22:41:43

Methyltriphenylphosphonium bromide Properties

Melting point 230-234 °C (lit.)
vapor pressure 0.0000002 hPa
Flash point >240°C
storage temp. Inert atmosphere,Room Temperature
solubility H2O: 0.1 g/mL, clear
form Powder
color White
PH 6.0-6.5 (400g/l, H2O, 20℃)
Water Solubility 400 g/L (25 ºC)
Sensitive Hygroscopic
BRN 3599467
InChIKey LSEFCHWGJNHZNT-UHFFFAOYSA-M
LogP -1.18
CAS DataBase Reference 1779-49-3(CAS DataBase Reference)
NIST Chemistry Reference Methyltriphenylphosphonium bromide(1779-49-3)
EPA Substance Registry System Phosphonium, methyltriphenyl-, bromide (1779-49-3)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS06,GHS09
Signal word  Danger
Hazard statements  H301-H411
Precautionary statements  P273-P301+P310+P330
Hazard Codes  Xn,Xi
Risk Statements  20/21/22-36/37/38
Safety Statements  36/37-36-26
RIDADR  UN 1390 4.3/PG 2
WGK Germany  3
Autoignition Temperature 410 °C
TSCA  T
HazardClass  6.1
PackingGroup  III
HS Code  29310095
Toxicity LD50 orally in Rabbit: 118 mg/kg
NFPA 704
1
2 1

Methyltriphenylphosphonium bromide price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 130079 Methyltriphenylphosphonium bromide 98% 1779-49-3 25G ₹1920 2022-06-14 Buy
Sigma-Aldrich(India) 130079 Methyltriphenylphosphonium bromide 98% 1779-49-3 100G ₹4580 2022-06-14 Buy
Sigma-Aldrich(India) 94993 Mettler-Toledo Calibration substance ME 30130598, Methyltriphenylphosphoniumbromide tracable to primary standards (LGC) 1779-49-3 5G ₹5726.43 2022-06-14 Buy
Sigma-Aldrich(India) 130079 Methyltriphenylphosphonium bromide 98% 1779-49-3 500G ₹10695.1 2022-06-14 Buy
TCI Chemicals (India) M0779 Methyltriphenylphosphonium Bromide 1779-49-3 25G ₹1900 2022-05-26 Buy
Product number Packaging Price Buy
130079 25G ₹1920 Buy
130079 100G ₹4580 Buy
94993 5G ₹5726.43 Buy
130079 500G ₹10695.1 Buy
M0779 25G ₹1900 Buy

Methyltriphenylphosphonium bromide Chemical Properties,Uses,Production

Chemical Properties

white powder

Uses

Methyltriphenylphosphonium Bromide is a lipophilic molecule with a cation allowing for it to be used to deliver molecules to specific cell components. Also considered an antineoplastic agent.

General Description

Methyltriphenylphosphoniumbromide is an organophosphorus compound, with potential use as a precursor and a solvent in organic synthesis.

Mettler-Toledo calibration substance ME 30130598, methyltriphenylphosphoniumbromide is ideal for use in the regular calibration of Mettler-Toledo melting point instrument. Its value is a mean of 6 to 12 iterations with a Mettler-Toledo MP70 Excellence instrument that is calibrated against primary standards. The melting point is validated by Capillary method according to European Pharmacopeia (2.2.14.)

Purification Methods

If the solid is sticky, wash it with *C6H6 and dry it in a vacuum over P2O5. [Marvel & Gall J Org Chem 24 1494 1959, Chem Ber 87 1318 1954, Milas & Priesing J Am Chem Soc 79 6295 1957, Wittig & Sch.llkopf Org Synth 40 66 1960.] The iodide, on recrystallisation from H2O, has m 187.5-188.5o [Mann et al. J Chem Soc 1130 1953, Wittig & Geissler Justus Liebigs Ann Chem 580 44 1953]. [Beilstein 16 IV 981.]

Global( 708)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
GLR Innovations +91 9891111994 New Delhi, India 4542 58 Inquiry
MAISURIYA PHARMA SOLUTIONS +91 9870085570 Gujarat, India 65 58 Inquiry
DAVY CHEM LABS +91-9603460845 +91-9493444489 Hyderabad, India 109 58 Inquiry
AD Pharmachem Pvt Ltd +91 9326149185 Maharashtra, India 15 58 Inquiry
Element Chemilink Pvt. Ltd. +91-6358814008 +91-6358814008 Gujarat, India 31 58 Inquiry
Vardhaman P Golechha 9704422000 Telangana, India 294 58 Inquiry
JUVENUS DRUGS +91-9655606404 +91-9655606404 Tamil Nadu, India 94 58 Inquiry
ACME SUJAN CHEMICALS +91 7588647937 Maharashtra, India 90 58 Inquiry
JSK Chemicals +919879767970 Gujarat, India 3756 58 Inquiry
AMINO ORGANICS +919866989891 Hyderabad, India 275 58 Inquiry
METHYLTRIPHENYLPHOSPHONIUM BROMIDE Methyltriphenylphosphonium bromideDISC. when stock is sold 11/2/00 Methyl triphenyl pho Methyltriphenyl phosphorniuM broMide MethyltriphenylphosphoniuM broMide, 98% 100GR METHYLTRIPHENYLPHOSPHONIUM BROMIDE FOR S PhosphoniuM,Methyltriphenyl-, broMide (1:1) MethyltriphenylphosphoniuM broMide 98% Three phenyl Methyl broMide phosphine Triphenyl phosphate bromide Mettler-Toledo Calibration substance ME 30130598, Methyltriphenylphosphoniumbromide METHYL TRIPHENYL PHOSPHONIUM BROMIDE LOW WATER Methy triphenylphosphonium MethyltriphenylphosphoniumBromide>98% methyltriphenyl-phosphoniubromide Phosphonium, methyltriphenyl-, bromide Phosphonium,methyltriphenyl-,bromide VLOOKUP(C5,[1]Export!$D:$H,5,0) METHYL TRIPHENYL PHOSPHONIUM BROMIDE MTPPB (2S,4R)-N-[(1S,2R)-2-chloro-1-[(2R,3R,4S,5R,6R)-3,4,5-trihydroxy-6-(methylthio)-2-oxanyl]propyl]-1-methyl-4-propyl-2-pyrrolidinecarboxamide hydrochloride MethyltriphenylphosphoniumBromide> Methyltriphenylphosphonium bromide, 98%, for synthesis Methyl Triphenyl Phosphonium Bromide,99% Methyltriphenyl bromide PHOSPH Methyl triphenyl phosphonium Bromide Solid Methyltriphenylphosphonium Bromide pure, 98% TRIPHENYLMETHYLPHOSPHONIUM BROMIDE Bromo(methyl)triphenylphosphorane Methyltriphenylphosphine bromide Methyltriphenylphosphanium bromide MTPPB Methyl Triphenyl Phosphonium Bromide (MTPBB) Methyltriphenylphosphonium bromide (6CI, 7CI) MTPPBR (METHYL TRI PHENYL PHOSPHONIUM BROMIDE) Methyltriphenylphosponiumbromide(MTPB) 1779-49-3 C19H18Br C19H18BrP C19H18PBr C19H18BPr CH3C6H53PBr C-C Bond Formation Phosphonium Compounds Wittig Reaction Wittig & Horner-Emmons Reaction Olefination Synthetic Reagents Wittig Reagents Phosphonium Compounds Synthetic Organic Chemistry Wittig & Horner-Emmons Reaction Wittig Reaction C-C Bond Formation Olefination Wittig Reagents organophosphorus compound