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Methyl trioctyl ammonium chloride

Methyl trioctyl ammonium chloride Structure
CAS No.
5137-55-3
Chemical Name:
Methyl trioctyl ammonium chloride
Synonyms
ALIQUAT 336;aliquat;ADOGEN 464;METHYLTRIOCTYLAMMONIUM CHLORIDE;TRICAPRYLYLMETHYLAMMONIUM CHLORIDE;TOMAC;TRIOCTYLMETHYLAMMONIUM CHLORIDE;TRICAPRYLMETHYLAMMONIUM CHLORIDE;METHYLTRI-N-OCTYLAMMONIUM CHLORIDE;trioctylmethylammonium
CBNumber:
CB4412612
Molecular Formula:
C25H54ClN
Molecular Weight:
404.16
MOL File:
5137-55-3.mol
MSDS File:
SDS
Modify Date:
2024/5/30 16:33:02

Methyl trioctyl ammonium chloride Properties

Melting point -20°C
Boiling point 240°C
Density 0.884 g/mL at 25 °C(lit.)
vapor pressure 0Pa at 25℃
refractive index n20/D 1.4665(lit.)
Flash point >230 °F
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility soluble in Chloroform, Hexanes
form Viscous Liquid
color Colourless to pale orange
Odor Ammonical
Water Solubility Partially insoluble
Sensitive Hygroscopic
BRN 4039255
Stability Stable. Incompatible wth strong oxidizing agents. Hygroscopic.
InChIKey XKBGEWXEAPTVCK-UHFFFAOYSA-M
LogP 4.5 at 25℃
CAS DataBase Reference 5137-55-3(CAS DataBase Reference)
EPA Substance Registry System Methyltrioctylammonium chloride (5137-55-3)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05,GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H301-H314-H360FD-H373-H410
Precautionary statements  P202-P273-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  Xn,N,C
Risk Statements  22-38-41-50/53-36/37/38-20/21/22-34
Safety Statements  26-39-60-61-36-45-36/37/39
RIDADR  UN 2810 6.1/PG 3
WGK Germany  3
RTECS  UZ2997500
3-10
HazardClass  6.1
PackingGroup  III
HS Code  29239000
NFPA 704
1
2 0

Methyl trioctyl ammonium chloride price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 69485 Methyltrioctylammonium chloride ≥97.0% (AT) 5137-55-3 10G ₹7101.2 2022-06-14 Buy
Sigma-Aldrich(India) 69485 Methyltrioctylammonium chloride ≥97.0% (AT) 5137-55-3 50G ₹17504.03 2022-06-14 Buy
TCI Chemicals (India) T1365 Methyltri-n-octylammonium Chloride 5137-55-3 25G ₹6600 2022-05-26 Buy
TCI Chemicals (India) T1365 Methyltri-n-octylammonium Chloride 5137-55-3 500G ₹51400 2022-05-26 Buy
Product number Packaging Price Buy
69485 10G ₹7101.2 Buy
69485 50G ₹17504.03 Buy
T1365 25G ₹6600 Buy
T1365 500G ₹51400 Buy

Methyl trioctyl ammonium chloride Chemical Properties,Uses,Production

Chemical Properties

viscous colourless to pale orange liquid

Uses

Methyltrioctylammonium chloride can be used:

  • As a catalyst in the synthesis of acridine dione derivatives from aromatic aldehyde, dimedone and amines under ultrasonic irradiations.
  • As a catalyst in the synthesis of extended π-systems using aromatic aldehydes and methyldiazines.
  • As a component of a catalytic system used in the Suzuki-Miyaura cross-coupling reaction of a variety of aryl and heteroaryl chlorides in H2O.

Definition

ChEBI: An organic chloride salt having methyltrioctylammonium as the cation.

Safety Profile

Poison by ingestion and intraperitoneal routes. When heated to decomposition it emits very toxic fumes of NOx, NH3, and Cl-.

Purification Methods

A 30% (v/v) of Aliquat 336 solution in *benzene is washed twice with an equal volume of 1.5M HBr. [Petrow & Allen, Anal Chem 33 1303 1961.] It is purified by dissolving 50g in CHCl3 (100mL) and shaking with 20% NaOH solution (200mL) for 10minutes, and followed by 20% NaCl (200mL) for 10minutes. It is then washed with a small volume of H2O and filtered through a dry filter paper [Adam & Pribil Talanta 18 733 1971]. n-Alkylammonium chloride n=2,4,6. Recrystallise them from EtOH or an EtOH/Et2O mixture. [Hashimoto & Thomas J Am Chem Soc 107 4655 1985, Chu & Thomas J Am Chem Soc 108 6270 1986.] n-Alkyltrimethylammonium bromide n=10,12,16. Recrystallise them from an EtOH/Et2O mixture. [Hashimoto & Thomas J Am Chem Soc 107 4655 1985.]

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TRICAPRYLYL MONOMETHYLAMMONIUM CHLORIDE TRI-N-OCTYLMETHYLAMMONIUM CHLORIDE CAPRIQUAT METHYLTRIOCTYLAMINE HYDROCHLORIDE Aliquat(rg 336 METHYLTRICAPRYLAMMONIUM CHLORIDE Methyltri-n-octylammonium chloride~Tricaprylylmethylammonium chloride Trictylmethylammonium chloride METHYLTRI-N-OCTYLAMMONIUM N-Methyl-N,N,N-trioctylammonium chloride AliquatÖÖ(rg336 Trioctylmethylammonium Chloride (R=C6-C10) [Phase-transfer Catalyst] ALIQUAT(R) 336 ALIQUAT(TM) 336 Aliquat 336, average MW 442 AMMONIUM,METHYLTRIOCTYL-,CHLORIDE ALIQUAT 336 (TRIOCTYLMETHYLAMMONIUM CHLORIDE) Trioctylmonomethylammonium chloride Methyltrioctylammonium chloride ,90% Aliquat 336N Aliquat 336-PTC Methyltri(octyl)aminium Methyltrioctylaminium 1-Octanaminium,N-methyl-N,N-dioctyl-,chloride methyltricaprylylammoniumchloride methyltrioctyl-ammoniuchloride n-methyl-n,n-dioctyl-1-octanaminiuchloride n-methyl-n,n-dioctyl-1-octanaminiumchloride Methyltrioctylammonium N-Methyl-N,N,N-trioctylaminium Trioctylmethylaminium TRICAPRYLYL MONOMETHYLAMMONIUM CHLORIDE, 75% SOLN Methyltrioctylammoni Methyltrioctylammonium chloride purum, >=97.0% (AT) Nsc61369 Trioctylmethylammonium chloride ,98% TOMAC 75 DeMecolcine research grade 1-OctanaMiniuM,N-Methyl-N,N-dioctyl-, chloride (1:1) MethyltrioctylaMMoniuM chloride >=97.0% (AT) Three octyl diMethyl aMMoniuM chloride (5137-55-3) Methyl octyl three aMMoniuM chloride MethyltrioCLylaMMoniuM Chloride N8,8,8,1Cl Methyl trioctyl ammonium chloride Liquid TricapryL Methyl Trioctylammonum Chloride Aliquat 336Aliquat 336 ALIQUAT(R) 336 (METHYLTRIOCTYLAMMONIUM CHLORIDE) Methyltrioctylammonium chloride, 99%, for synthesis Tricaprylylmethylammonium Chloride,99% Methyl trioctyl ammonium chloride ISO 9001:2015 REACH Methyl trioctyl ammonium chloride ( Aliquat 336) SKL1475 TA811 TRICAPRYLMETHYLAMMONIUM CHLORIDE TRICAPRYLYLMETHYLAMMONIUM CHLORIDE TRIOCTYLMETHYLAMMONIUM CHLORIDE TOMAC