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Ferric chloride

Ferric chloride Structure
CAS No.
7705-08-0
Chemical Name:
Ferric chloride
Synonyms
FeCl3;IRON(III) CHLORIDE;IRON CHLORIDE;Ferric chloride anhydrous;FERRIC CHLORIDE SOLUTION;DB03;FERRIC CHLORID;Iron perchloride;IRON TRICHLORIDE;Iron(Ⅲ) chloride
CBNumber:
CB5444364
Molecular Formula:
Cl3Fe
Molecular Weight:
162.2
MOL File:
7705-08-0.mol
MSDS File:
SDS
Modify Date:
2024/7/30 17:43:28

Ferric chloride Properties

Melting point 304 °C(lit.)
Boiling point 316 °C
Density 2,804 g/cm3
vapor density 5.61 (vs air)
vapor pressure 1 mm Hg ( 194 °C)
refractive index n20/D1.414
Flash point 316°C
storage temp. Store below +30°C.
solubility H2O: soluble
form powder
color Yellow
Specific Gravity 2.804
PH 1 (200g/l, H2O, 20℃)
Water Solubility 920 g/L (20 ºC)
Sensitive Hygroscopic
Merck 14,4019
Exposure limits ACGIH: TWA 1 mg/m3
NIOSH: TWA 1 mg/m3
Stability Stable. Very sensitive to moisture. Incompatible with strong oxidizing agents; forms explosive mixtures with sodium, potassium. Hygroscopic.
CAS DataBase Reference 7705-08-0(CAS DataBase Reference)
NIST Chemistry Reference Ferric chloride(7705-08-0)
EPA Substance Registry System Ferric chloride (7705-08-0)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS05,GHS07,GHS08
Signal word  Danger
Hazard statements  H225-H290-H302-H318-H335-H351
Precautionary statements  P201-P210-P233-P261-P280-P305+P351+P338+P310
Hazard Codes  C,Xn,Xi
Risk Statements  41-38-22-34-37/38-10-36
Safety Statements  26-39-45-36/37/39
RIDADR  UN 2582 8/PG 3
WGK Germany  1
RTECS  LJ9100000
TSCA  Yes
HS Code  2827 39 20
HazardClass  8
PackingGroup  III
Toxicity LD50 orally in Rabbit: 316 mg/kg
NFPA 704
0
2 1

Ferric chloride price More Price(29)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 8.03945 Iron(III) chloride anhydrous for synthesis 7705-08-0 1KG ₹8280 2022-06-14 Buy
Sigma-Aldrich(India) 908908 Iron(III) chloride free-flowing, Redi-Dri?, reagent grade, 97% 7705-08-0 100G ₹5206.83 2022-06-14 Buy
Sigma-Aldrich(India) 8.03945 Iron(III) chloride anhydrous for synthesis 7705-08-0 500G ₹10040 2022-06-14 Buy
Sigma-Aldrich(India) 809330 Fe/ppm Pd for nitro group reductions 7705-08-0 500MG ₹4384.13 2022-06-14 Buy
Sigma-Aldrich(India) 8.03945 Iron(III) chloride anhydrous for synthesis 7705-08-0 60KG ₹86010 2022-06-14 Buy
Product number Packaging Price Buy
8.03945 1KG ₹8280 Buy
908908 100G ₹5206.83 Buy
8.03945 500G ₹10040 Buy
809330 500MG ₹4384.13 Buy
8.03945 60KG ₹86010 Buy

Ferric chloride Chemical Properties,Uses,Production

Description

Ferric chloride (iron(IH)chloride, FeCl3, CAS No. 7705-08-0) may be prepared from iron and chlorine or from ferric oxide and hydrogen chloride. The pure material occurs as hydroscopic, hexagonal, dark crystals. Ferric chloride hexahydrate (iron(III)chloride hexahydrate, FeCl3*6H2O, CAS No. 10025-77-1) is readily formed when ferric chloride is exposed to moisture.

Chemical Properties

Ferric chloride,FeCl3, is a brown crystalline solid and is soluble in water,alcohol,and glycerol. It is also known as anhydrous ferric chloride,ferric trichloride, Flores martis,and iron chloride. Ferric chloride is used as a coagulant for sewage and industrial wastes, as an oxidizing and chlorinating agent,as a disinfectant, in copper etching, and as amordant. In addition, this compound is employed in the ferric chloride test,which is used to assess the relative corrosion resistance of stainless and nickel-base alloys. The ferric chloride test has been shown to be an appropriate measure of the suitability of such alloys for service in paper mill bleach plants and seawater.

Uses

Ferric Chloride is a nutrient and dietary supplement that serves as a source of iron.

General Description

Ferric chloride is an orange to brown-black solid. Ferric chloride is slightly soluble in water. Ferric chloride is noncombustible. When wet Ferric chloride is corrosive to aluminum and most metals. Pick up and remove spilled solid before adding water. Ferric chloride is used to treat sewage, industrial waste, to purify water, as an etching agent for engraving circuit boards, and in the manufacture of other chemicals.

Air & Water Reactions

Very hygroscopic. Slightly water soluble, where a 0.1M solution has a pH of 2.0.

Reactivity Profile

Alkali metal hydroxides, acids, anhydrous chlorides of iron, tin, and aluminum, pure oxides of iron and aluminum, and metallic potassium are some of the catalysts that may cause ethylene oxide to rearrange and polymerize, liberating heat, [J. Soc. Chem. Ind. 68:179(1949)]. Explosions occur , although infrequently, from the combination of ethylene oxide and alcohols or mercaptans, [Chem. Eng. News 20:1318(1942)]. Allyl chloride may polymerize violently under conditions involving an acid catalyst, such as sulfuric acid, Ferric chloride, aluminum chloride, Lewis acids, and Ziegler type catalysts (initiators), [Ventrone (1971)].

Hazard

Toxic by ingestion, strong irritant to skin and tissue.

Health Hazard

Inhalation of dust may irritate nose and throat. Ingestion causes irritation of mouth and stomach. Dust irritates eyes. Prolonged contact with skin causes irritation and burns.

Fire Hazard

Special Hazards of Combustion Products: Irritating hydrogen chloride fumes may form in fire.

Industrial uses

Ferric chloride (FeCl3) is obtained by an iron chlorination method at a temperature of 600–700 °C. Very limited data are available on the use of ferric chloride in the mineral processing industry. Ferric chloride has a depressing effect on barite and can be used in barite–celestite separation. It was also evaluated as a depressant during niobium– zirconium separation. In general, ferric and ferrous compounds are not selective depressants and in many cases are detrimental for flotation of oxidic and industrial minerals as in the case of anionic flotation, fatty acid, iron complexes or oleate iron complexes.

Safety Profile

Poison by ingestion and intravenous routes. Experimental reproductive effects. Corrosive. Probably an eye, skin, and mucous membrane irritant. Mutation data reported. Reacts with water to produce toxic and corrosive fumes. Catalyzes potentially explosive polymerization of ethylene oxide, chlorine + monomers (e.g., styrene). Forms shock sensitive explosive mixtures with some metals (e.g., potassium, sodium). Violent reaction with all$ chloride. When heated to decomposition it emits highly toxic fumes of HCl.

Potential Exposure

Iron chloride is used to treat sewage and industrial waste. It is also used as an etchant for photo engraving and rotogravure; in textiles; photography; as a disinfectant; as a feed additive.

Shipping

UN1773 Ferric chloride, anhydrous, Hazard class: 8; Labels: 8-Corrosive material. UN2582 Ferric chlo ride, solution, Hazard class: 8; Labels: 8-Corrosive material

Purification Methods

Sublime it at 200o in an atmosphere of chlorine. It is an “iron-black” coloured powder with green irridescence. Store it in a weighing bottle inside a desiccator as it absorbs moisture from air to form the yellow hexahydrate (see next entry). [Tarr Inorg Synth III 191 1950, Pray Inorg Synth V 153 1957, Epperson Inorg Synth VII 163 1963.]

Incompatibilities

Aqueous solutions are a strong acid. Violent reaction with bases, allyl chloride; sulfuric acid; water. Shock- and friction-sensitive explosive material forms with potassium, sodium and other active metals. Attacks metals when wet.

Waste Disposal

Neutralize with lime or soda ash and bury in an approved landfill.

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Ferric chloride Spectrum

IRON(III) CHLORIDE ANHYDROUS FOR SYNTHES IRON(III) CHLORIDE SOLUTION (15% FE) Z.A IRON(III) CHLORIDE SOLUTION (10% FE) FOR Ferric Chloride, 41 DEG Be Solution Ferricchloride,anhydrous Flores martis floresmartis Iron chloride (Fe2Cl3) Iron chloride (FeCl3) Iron sesquichloride ironchloride(fecl3) ironperchloride naturalmolysite Perchlorure de fer perchloruredefer IRON (III) CHLORIDE ON SILICA IRON ATOMIC SPECTROSCOPY STANDARD IRON(+3)CHLORIDE Iron (III) chloride anhydrous Iron(III) chloride, 5 wt.% Ironchlorideanhydrous Iron(Ⅲ) chloride anhydrous Iron(III) chloride, anhydrous, powder, 99.99+% IRON(III) CHLORIDE SOLUTION 0.25 G/L IN IRON(III) CHLORIDE SOLUTION 45 % FECL3, PURE IRON(III) CHLORIDE 5 WT. % ON SILICA G& IRON(III) CHLORIDE, 5 WT. % ON SILICA GE L IRON(III) CHLORIDE REAGENT GRADE 97% IRON ATOMIC SPECTROSCOPY STANDARD CONC. 1.00 G FE, AMPOULE FerricChlorideAnydrous Iron(Iii)ChlorideSolution FerricChlorideGrAnhydrous Ferricchloridesolution15%Fe Iron(III) chloride, anhydrous, pure, 98% Iron(III)chloride,anhydrous,98% iron atomic spectroscopy standard concentrate 1.00 g fe iron standard concentrate 10.00 g fe FERRICCHLORIDE,41BSOLUTION FERRICCHLORIDE,ANHYDROUS,POWDER,PURIFIED FERRICCHLORIDE,ANHYDROUS,SUBLIMED,POWDER,REAGENT FERRICCHLORIDE,ANHYDROUSTECH(BULK FERRICCHLORIDE,SOLUTION(BULK Eisen(III)-chlorid8 Iron(III) chloride anhydrous, powder, >=99.99% trace Metals basis PROTEIN MW MARKER WIDE RANGE BIOTECH GR SERAFREE CRYOPRESERVATION MEDIA TC GRADE Iron(Ⅲ) Chloride Solution Ferric chloride, anhydrous, Chemistry Ferric Chloride Solution, 40% w/v Ferric Chloride Solution, 0.025% (w/v) Iron(III) chloride subliMed grade, >=99.9% trace Metals basis Molysite Iron(III) chloride on silica gel powder, extent of labeling: 5 wt. % loading Iron(III) chloride reagent grade, 97% Iron(III) chloride solution 0.2 M in 2-methyltetrahydrofuran Iron(III) chloride solution purum, 45% FeCl3 basis Fe/ppm Pd for nitro group reductions Chlorure perrique