Iron
![Iron Structure](CAS/GIF/7439-89-6.gif)
- CAS No.
- 7439-89-6
- Chemical Name:
- Iron
- Synonyms
- Fe;iron powder;CARBONYL IRON;FERRUM;IRON METAL;Iron Filings;FERRONYL;IRON STANDARD SOLUTION;Iron rod;Iron granules
- CBNumber:
- CB8280013
- Molecular Formula:
- Fe
- Molecular Weight:
- 55.85
- MOL File:
- 7439-89-6.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/5/27 15:19:26
Melting point | 1535 °C(lit.) |
---|---|
Boiling point | 2750 °C(lit.) |
Density | 7.86 g/mL at 25 °C(lit.) |
Flash point | >230 °F |
storage temp. | 2-8°C |
solubility | H2O: soluble |
form | wire |
color | Silvery |
Specific Gravity | 7.86 |
Odor | Odorless |
Resistivity | 9.71 μΩ-cm |
Water Solubility | INSOLUBLE |
Sensitive | Moisture Sensitive |
Merck | 13,5109 |
Exposure limits |
ACGIH: TWA 2 mg/m3 OSHA: TWA 15 mg/m3; TWA 5 mg/m3 NIOSH: IDLH 1250 mg/m3; TWA 2.5 mg/m3 |
Stability | Stable. Reacts slowly with moist air and water. Dust may form an explosive or combustible mixture with air. Incompatible with organic acids, strong oxidizing agents, water, mineral acids. |
CAS DataBase Reference | 7439-89-6(CAS DataBase Reference) |
NIST Chemistry Reference | Iron(7439-89-6) |
EPA Substance Registry System | Iron (7439-89-6) |
Modulus of Elasticity | 200 GPa |
---|---|
Poissons Ratio | 0.291 |
Shear Modulus | 77.5 GPa, Calculated |
Hardness, Vickers | 150 |
Bulk Modulus | 166 GPa |
Hardness, Brinell | 146, Converted from Vickers for 3000 kg load/10 mm ball Brinell test |
Hardness, Rockwell A | 49, Converted from Vickers |
Hardness, Rockwell B | 79, Converted from Vickers |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS02 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H228 | |||||||||
Precautionary statements | P210 | |||||||||
Hazard Codes | F,Xi | |||||||||
Risk Statements | 36/38-11-17 | |||||||||
Safety Statements | 26-16-33-24/25 | |||||||||
RIDADR | UN 3264 8/PG 3 | |||||||||
WGK Germany | 1 | |||||||||
RTECS | NO4565500 | |||||||||
TSCA | Yes | |||||||||
HazardClass | 8 | |||||||||
PackingGroup | III | |||||||||
HS Code | 72052900 | |||||||||
Toxicity | LD50 oral in rat: 30gm/kg | |||||||||
NFPA 704 |
|
Iron price More Price(164)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | C3518 | Carbonyl iron ≥97% Fe basis | 7439-89-6 | 100G | ₹11488.95 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | SRP2006 | TFIIE, α+β subunits human recombinant, expressed in E. coli, ≥80% (SDS-PAGE) | 7439-89-6 | 10μG | ₹47567.8 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | SRP2005 | TFIIE β, p34 human recombinant, expressed in E. coli, ≥70% (SDS-PAGE) | 7439-89-6 | 10μG | ₹46970 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | C3518 | Carbonyl iron ≥97% Fe basis | 7439-89-6 | 500G | ₹23199.45 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | C3518 | Carbonyl iron ≥97% Fe basis | 7439-89-6 | 1KG | ₹36903.9 | 2022-06-14 | Buy |
Iron Chemical Properties,Uses,Production
Description
Carbonyl iron is elemental iron produced by the decomposition of iron pentacarbonyl as a dark gray powder. When viewed under a microscope having a magnifying power of 500 diameters or greater, it appears as spheres built up with concentric shells. It is stable in dry air.
Chemical Properties
Silver-white malleable metal. The only metal that can be tempered. Mechanical properties are altered by impurities, especially carbon.Iron is highly reactive chemically, a strong reducing agent, oxidizes readily in moist air, reacts with steam when hot, t
Physical properties
Pure iron is a silvery-white, hard, but malleable and ductile metal that can be worked andforged into many different shapes, such as rods, wires, sheets, ingots, pipes, framing, and soon. Pure iron is reactive and forms many compounds with other elements. It is an excellentreducing agent. It oxidizes (rusts) in water and moist air and is highly reactive with most acids,releasing hydrogen from the acid. One of its main properties is that it can be magnetized andretain a magnetic field.The iron with a valence of 2 is referred to as “ferrous” in compounds (e.g., ferrous chloride= FeCl2). When the valence is 3, it is called “ferric” (e.g., ferric chloride = FeCl3).Iron’s melting point is 1,535°C, its boiling point is 2,750°C, and its density is 7.873g/cm3.
Isotopes
There are 30 isotopes of iron ranging from Fe-45 to Fe-72. The following arethe four stable isotopes with the percentage of their contribution to the element’s naturalexistence on Earth: Fe-54 = 5.845%, Fe-56 = 91.72%, Fe-57 = 2.2%, and Fe-58 =0.28%. It might be noted that Fe-54 is radioactive but is considered stable because ithas such a long half-life (3.1×10+22 years). The other isotopes are radioactive and areproduced artificially. Their half-lives range from 150 nanoseconds to 1×105 years.
Origin of Name
The name “iron” or “iren” is Anglo-Saxon, and the symbol for iron (Fe) is from ferrum, the Latin word for iron.
Characteristics
Iron is the only metal that can be tempered (hardened by heating, then quenching in wateror oil). Iron can become too hard and develop stresses and fractures. This can be corrected byannealing, a process that heats the iron again and then holds it at that temperature until thestresses are eliminated. Iron is a good conductor of electricity and heat. It is easily magnetized,but its magnetic properties are lost at high temperatures. Iron has four allotropic states. Thealpha form exists at room temperatures, while the other three allotropic forms exist at varyinghigher temperatures.Iron is the most important construction metal. It can be alloyed with many other metals tomake a great variety of specialty products. Its most important alloy is steel.An interesting characteristic of iron is that it is the heaviest element that can be formed byfusion of hydrogen in the sun and similar stars. Hydrogen nuclei can be “squeezed” in the sunto form all the elements with atomic numbers below cobalt (27Co), which includes iron. Itrequires the excess fusion energy of supernovas (exploding stars) to form elements with protonnumbers greater than iron (26Fe).
Uses
Iron is a mineral used in food fortification that is necessary for the prevention of anemia, which reduces the hemoglobin concentra- tion and thus the amount of oxygen delivered to the tissues. sources include ferric ammonium sulfate, chloride, fructose, glycerophos- phate, nitrate, phosphate, pyrophosphate and ferrous ammonium sulfate, citrate, sulfate, and sodium iron edta. the ferric form (fe3+) is iron in the highest valence state and the ferrous form (fe2+) is iron in a lower valence state. the iron source should not discolor or add taste and should be stable. iron powders produce low discoloration and rancidity. it is used for fortification in flour, baked goods, pasta, and cereal products.
Production Methods
Iron ore reserves are found worldwide. Areas with more than 1 billion metric tons of reserves include Australia, China, Brazil, Canada, the United States, Venezuela, South Africa, India, the former Soviet Union, Gabon, France, Spain, Sweden, and Algeria. The ore exists in varying grades, ranging from 20 to 70% iron content. North America has been fortunate in its ore deposits. There are commercially usable quantities in 22 U.S. states and in six Canadian provinces. In the United States the most abundant supplies, discovered in the early 1890s, are located in the Lake Superior region around the Mesabi Range. Other large deposits are found in Alabama, Utah, Texas, California, Pennsylvania, and New York. These deposits, particularly the Mesabi Range reserves, seemed inexhaustible in the 1930s when an average of 30 million tons of ore was produced annually from that one range. The tremendous demand for iron ore duringWorldWar II virtually tripled the output of the Mesabi Range and severely depleted its deposits of high-grade ore. The major domestic (U.S.) production is nowfrom crude iron ore, mainly taconite, a low-grade ore composed chiefly of hematite [FeO(OH) ·H2O] and silica found in the Great Lakes region.
Definition
iron: Symbol Fe. A silvery malleableand ductile metallic transition element;a.n. 26; r.a.m. 55.847; r.d.7.87; m.p. 1535°C; b.p. 2750°C. Themain sources are the ores haematite(Fe2O3), magnetite (Fe3O4), limonite(FeO(OH)nH2O), ilmenite (FeTiO3),siderite (FeCO3), and pyrite (FeS2).The metal is smelted in a blast furnaceto give impure pig iron, whichis further processed to give castiron, wrought iron, and varioustypes of steel. The pure element hasthree crystal forms: alpha-iron, stablebelow 906°C with a body-centredcubicstructure; gamma-iron, stablebetween 906°C and 1403°C with anonmagnetic face-centred-cubicstructure; and delta-iron, which isthe body-centred-cubic form above1403°C. Alpha-iron is ferromagneticup to its Curie point (768°C). The elementhas nine isotopes (mass numbers52–60), and is the fourth mostabundant in the earth’s crust. It is requiredas a trace element (see essentialelement) by living organisms.Iron is quite reactive, being oxidizedby moist air, displacing hydrogenfrom dilute acids, and combiningwith nonmetallic elements. It formsionic salts and numerous complexeswith the metal in the +2 or +3 oxidationstates. Iron(VI) also exists in theferrate ion FeO42-, and the elementalso forms complexes in which its oxidationnumber is zero (e.g. Fe(CO)5).
General Description
A gray lustrous powder. Used in powder metallurgy and as a catalyst in chemical manufacture.
Air & Water Reactions
Highly flammable. May react with water to give off hydrogen, a flammable gas. The heat from this reaction may ignite the hydrogen.
Reactivity Profile
Iron is pyrophoric [Bretherick, 1979 p. 170-1]. A strong reducing agent and therefore incompatible with oxidizing agents. Burns in chlorine gas [Mellor 2, Supp. 1:380 1956]. Reacts with fluorine with incandescence [Mellor 13:314, 315, 1946-1947].
Hazard
Iron dust from most iron compounds is harmful if inhaled and toxic if ingested. Iron dustand powder (even filings) are flammable and can explode if exposed to an open flame. Asmentioned, excessive iron in the diet may cause liver damage.
Health Hazard
Fire may produce irritating and/or toxic gases. Contact may cause burns to skin and eyes. Contact with molten substance may cause severe burns to skin and eyes. Runoff from fire control may cause pollution.
Fire Hazard
Flammable/combustible material. May be ignited by friction, heat, sparks or flames. Some may burn rapidly with flare burning effect. Powders, dusts, shavings, borings, turnings or cuttings may explode or burn with explosive violence. Substance may be transported in a molten form at a temperature that may be above its flash point. May re-ignite after fire is extinguished.
Environmental Fate
Iron occurs rarely by itself in nature due to the ease with which it forms compounds, especially in oxidation reactions. Many iron compounds are water soluble, leading to potentially high concentrations in water, especially in seawater. Iron is a necessary component of all life and it is therefore taken up readily by organisms from all sources.
Purification Methods
Clean it in conc HCl, rinse in de-ionised water, then reagent grade acetone and dry it under vacuum.
Iron Preparation Products And Raw materials
Raw materials
Preparation Products
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chevron_rightSupplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
Vardhaman P Golechha | 9704422000 | Telangana, India | 294 | 58 | Inquiry |
Murli Krishna Exports Pvt Ltd | +91-2225631595 +91-2225631594 | New Delhi, India | 185 | 58 | Inquiry |
ADVENT CHEMBIO PRIVATE LIMITED | +91-9821524116 +91-9821524116 | Mumbai, India | 353 | 58 | Inquiry |
SYNOVA CHEMICALS | +91-9920741772 +91-9920741772 | Mumbai, India | 428 | 58 | Inquiry |
INDUSTRIAL METAL POWDERS (INDIA) PVT LTD | +91-9881672810 +91-9881672810 | Pune, India | 1 | 58 | Inquiry |
ANJI BIOSCIENCES | +91-9000100077 +91-9000100077 | Hyderabad, India | 430 | 58 | Inquiry |
JSK Chemicals | +919879767970 | Gujarat, India | 3756 | 58 | Inquiry |
SAANVI CORP | +91-7208939370 +91-7208939370 | Maharashtra, India | 46 | 58 | Inquiry |
SOLFYN INTERNATIONAL LLP | +91-9321772608 +91-9321772608 | Mumbai, India | 105 | 58 | Inquiry |
Kamman Group | +91-9619902204 +91-9619902204 | Mumbai, India | 33 | 58 | Inquiry |
Supplier | Advantage |
---|---|
Vardhaman P Golechha | 58 |
Murli Krishna Exports Pvt Ltd | 58 |
ADVENT CHEMBIO PRIVATE LIMITED | 58 |
SYNOVA CHEMICALS | 58 |
INDUSTRIAL METAL POWDERS (INDIA) PVT LTD | 58 |
ANJI BIOSCIENCES | 58 |
JSK Chemicals | 58 |
SAANVI CORP | 58 |
SOLFYN INTERNATIONAL LLP | 58 |
Kamman Group | 58 |
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