trans-1,4-Dichloro-2-butene
- CAS No.
- 110-57-6
- Chemical Name:
- trans-1,4-Dichloro-2-butene
- Synonyms
- tri-1,4-Dichloro-2-b;1,4-Dichlorobutene-2;1,4-DICHLORO-2-BUTENE;2-BUTYLENE DICHLORIDE;4-dichloro-(e)-2-buten;1,4-DICHLORO-2-BUTYLENE;4-dichloro-trans-2-buten;trans-1,4-dichlorobutene;trans-1,4-Dichlor-2-buten;(E)-1,4-dichlorobut-2-ene
- CBNumber:
- CB9705137
- Molecular Formula:
- C4H6Cl2
- Molecular Weight:
- 125
- MOL File:
- 110-57-6.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/1/23 14:06:52
| Melting point | 1-3 °C(lit.) |
|---|---|
| Boiling point | 74-76 °C40 mm Hg(lit.) |
| Density | 1.183 g/mL at 25 °C(lit.) |
| vapor pressure | 10 mm Hg ( 20 °C) |
| refractive index |
n |
| Flash point | 129 °F |
| storage temp. | 2-8°C |
| solubility | Chloroform, Ethyl Acetate |
| form | Oil |
| color | Clear Colourless to Light Yellow |
| BRN | 1719693 |
| InChIKey | FQDIANVAWVHZIR-OWOJBTEDSA-N |
| CAS DataBase Reference | 110-57-6(CAS DataBase Reference) |
| IARC | 3 (Vol. 15, Sup 7, 71) 1999 |
| NIST Chemistry Reference | 2-Butene, 1,4-dichloro-, (E)-(110-57-6) |
| EPA Substance Registry System | trans-1,4-Dichloro-2-butene (110-57-6) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS02,GHS05,GHS06 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H226-H301-H312-H314-H330 | |||||||||
| Precautionary statements | P210-P233-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338 | |||||||||
| Hazard Codes | T+,T,F,N | |||||||||
| Risk Statements | 10-21-25-26-34-39/23/24/25-23/24/25-11-50/53-45-24/25 | |||||||||
| Safety Statements | 53-23-26-36/37/39-45-36/37-99-61-60-16 | |||||||||
| RIDADR | UN 3390 6.1/PG 1 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | EM4903000 | |||||||||
| F | 8-21 | |||||||||
| HazardClass | 6.1(a) | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29032990 | |||||||||
| NFPA 704 |
|
trans-1,4-Dichloro-2-butene Chemical Properties,Uses,Production
Chemical Properties
clear colorless to light yellow liquid
Uses
1,4-Dichloro-2-butene is used in the synthesis of anthraquinones used in the asymmetric dihydroxylation of olefins. Also used to prepare arylcarboxamides used as novel dopamine receptor antagonists.
General Description
Colorless liquid with a distinct odor. An intermediate for hexamethylenediamine and chloroprene.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
trans-1,4-Dichloro-2-butene will burn, though trans-1,4-Dichloro-2-butene may require some effort to ignite. Fire produces irritating and poisonous gases. When heated to decomposition, trans-1,4-Dichloro-2-butene emits toxic fumes of chlorine-containing compounds. [EPA, 1998].
Health Hazard
(Non-Specific -- Dichlorobutene) Liquid and vapors from the material are highly corrosive and may damage skin, eyes, lungs, and internal organs.
Fire Hazard
The material will burn, though trans-1,4-Dichloro-2-butene may require some effort to ignite. Fire produces irritating and poisonous gases. When heated to decomposition, trans-1,4-Dichloro-2-butene emits toxic fumes of chlorine-containing compounds.
Potential Exposure
DC occurs as a by-product in chloroprene manufacture and may be used as a chemical intermediate
Shipping
UN3384 Toxic by inhalation liquid, flammable, n. o.s. with an LC50 ≦ 1000 ml/m3 and saturated vapor concentration ≧to 10 LC50, Hazard class: 6.1; Labels: 6.1-Poisonous materials, 3-Flammable liquid, Technical Name Required, Inhalation Hazard Zone B. UN2920 Corrosive liquids, flammable, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, 3-Flammable liquid. The code “D” identifies proper shipping names which are appropriate for describing materials for domestic transportation but may be inappropriate for international transportation under the provisions of international regulations, e.g., IMO, ICAO). An alternate proper shipping name may be selected when either domestic or international transportation is involved
Incompatibilities
Vapors may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. (cis-isomer): Reacts slowly with water forming hydrogen chloride. Attacks metals and may form other, more dangerous materials; attacks some plastics.
Waste Disposal
High-temperature incineration with hydrochloric acid scrubbing. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.
trans-1,4-Dichloro-2-butene Preparation Products And Raw materials
Raw materials
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| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| ARCHERCHEM | 91-22-28786843/ 91-22-28786842 /91-22-28786842 | New Delhi, India | 86 | 54 | Inquiry |
| CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6351 | 58 | Inquiry |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | China | 20294 | 58 | Inquiry |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | China | 29798 | 60 | Inquiry |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | China | 18648 | 58 | Inquiry |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | China | 21667 | 55 | Inquiry |
| career henan chemical co | +86-0371-86658258 +8613203830695 | China | 29888 | 58 | Inquiry |
| SHANDONG ZHI SHANG CHEMICAL CO.LTD | +86 18953170293 | China | 2931 | 58 | Inquiry |
| Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | China | 39916 | 58 | Inquiry |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | China | 49392 | 58 | Inquiry |
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