ChemicalBook > Product Catalog >Organic Chemistry >Organometallic compounds >Organic rhodium >Tris(triphenylphosphine)rhodiu
Tris(triphenylphosphine)rhodiu
- CAS No.
- 14694-95-2
- Chemical Name:
- Tris(triphenylphosphine)rhodiu
- Synonyms
- Wilkinson;WILKINSON CATALYST;WILKINSON'S CATALYST;TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CHLORIDE;Tris(triphenylphosphine)rhodium chloride;Tetrakis(triphenlphosphine)palladium;TRIS(TRIPHENYLPHOSPHINE)CHLORORHODIUM;DECARBON;NSC 124140;Tris(triphenyL
- CBNumber:
- CB1494341
- Molecular Formula:
- C54H45ClP3Rh
- Molecular Weight:
- 925.21
- MOL File:
- 14694-95-2.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/12/14 20:49:34
| Melting point | 245-250 °C (dec.) |
|---|---|
| Boiling point | >170°C |
| Density | 1.363; d 1.379 |
| vapor pressure | 0Pa at 25℃ |
| storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
| solubility | Soluble in most solvents (e.g. benzene, ethanol, chloroform, dichloromethane) but with phosphine dissociation. Reacts with O{2} in solution |
| form | Crystalline Powder |
| color | Red-brown to maroon |
| Water Solubility | insoluble |
| Sensitive | air sensitive |
| Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions |
| Merck | 14,9758 |
| BRN | 4581440 |
| Exposure limits |
ACGIH: TWA 1 mg/m3 NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3 |
| InChIKey | QEYYHUJFSQCTAE-UHFFFAOYSA-M |
| LogP | 5.69 at 20℃ |
| CAS DataBase Reference | 14694-95-2(CAS DataBase Reference) |
| NIST Chemistry Reference | chlorotris(triphenylphosphine)rhodium(14694-95-2) |
| EPA Substance Registry System | Rhodium, chlorotris(triphenylphosphine)-, (SP-4-2)- (14694-95-2) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H317-H413 | |||||||||
| Precautionary statements | P261-P272-P273-P280-P302+P352-P333+P313 | |||||||||
| Hazard Codes | C,Xi | |||||||||
| Risk Statements | 34-36/38 | |||||||||
| Safety Statements | 22-24/25-37/39-28A-26-15-45-36/37/39 | |||||||||
| RIDADR | 1759 | |||||||||
| WGK Germany | 1 | |||||||||
| F | 8-10-23 | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 28439090 | |||||||||
| NFPA 704 |
|
Tris(triphenylphosphine)rhodiu price More Price(6)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 205036 | Tris(triphenylphosphine)rhodium(I) chloride 99.9% trace metals basis | 14694-95-2 | 250MG | ₹2930.4 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 205036 | Tris(triphenylphosphine)rhodium(I) chloride 99.9% trace metals basis | 14694-95-2 | 1G | ₹7303.8 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 205036 | Tris(triphenylphosphine)rhodium(I) chloride 99.9% trace metals basis | 14694-95-2 | 5G | ₹24819.6 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 199982 | Tris(triphenylphosphine)rhodium(I) chloride | 14694-95-2 | 1G | ₹7647.9 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 199982 | Tris(triphenylphosphine)rhodium(I) chloride | 14694-95-2 | 5G | ₹45898.5 | 2022-06-14 | Buy |
Tris(triphenylphosphine)rhodiu Chemical Properties,Uses,Production
Chemical Properties
magenta crystals
Uses
Tris(triphenylphosphine)rhodiu is also known as Wilkinson's catalyst and is commonly used to catalyze the hydrogenation of alkenes. Tris(triphenylphosphine)rhodiu is also used in the catalytic hydroboration of alkenes with catecholborane and pinacolborane and the selective 1,4-reduction of α, β-unsaturated carbonyl compounds.
Purification Methods
It forms dark burgundy crystals from hot EtOH after refluxing for 30minutes. When the solution is heated for only 5minutes, orange crystals are formed. Heating the orange crystals in EtOH yields red crystals. Crystallisation from Me2CO gives the orange crystals. The two forms have similar IR spectra, but the X-ray diffraction patterns are slighly different. [Osborne et al. J Chem Soc (A) 1711 1966, Osborne & Wilkinson Inorg Synth X 67 1967, Bennett & Donaldson Inorg Chem 16 655 1977.] The solubilities are as follows: in CH2Cl2 ~2% (25o), in toluene 0.2% (25o), and less soluble in Me2CO, MeOH, BuOH and AcOH, but insoluble in pet ethers and cyclohexane. It reacts with donor solvents such as pyridine, DMSO and MeCN.
Tris(triphenylphosphine)rhodiu Preparation Products And Raw materials
Global( 418)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| Evans Fine Chem | +91-9821340302 +91-9821340302 | Maharashtra, India | 286 | 58 | Inquiry |
| SOLFYN INTERNATIONAL LLP | +91-9321772608 +91-9321772608 | Mumbai, India | 105 | 58 | Inquiry |
| Omkar Lab | +91-9130062553 +91-9326135973 | Maharashtra, India | 47 | 58 | Inquiry |
| JSK Chemicals | +919879767970 | Gujarat, India | 3756 | 58 | Inquiry |
| ALS INDIA LIFE SCIENCES | +91-8977036379 +91-8977036379 | Hyderabad, India | 1879 | 58 | Inquiry |
| Metal Chem India | +91-8999856889 +91-9011882000 | Maharashtra, India | 46 | 58 | Inquiry |
| Johnson Matthey Chemicals India Pvt Ltd | +91-9820622275 +91-9711869003 | Maharashtra, India | 69 | 58 | Inquiry |
| Hindustan Platinum Pvt., Ltd. | 91-22-61904199 | Maharashtra, India | 53 | 58 | Inquiry |
| LOBA CHEMIE PVT.LTD. | 91-22-6663 6699 | Mumbai, India | 3077 | 58 | Inquiry |
| Mehta Enterprise | 08068442230Ext 607 | Mumbai, India | 155 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| Evans Fine Chem | 58 |
| SOLFYN INTERNATIONAL LLP | 58 |
| Omkar Lab | 58 |
| JSK Chemicals | 58 |
| ALS INDIA LIFE SCIENCES | 58 |
| Metal Chem India | 58 |
| Johnson Matthey Chemicals India Pvt Ltd | 58 |
| Hindustan Platinum Pvt., Ltd. | 58 |
| LOBA CHEMIE PVT.LTD. | 58 |
| Mehta Enterprise | 58 |
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DECARBON
CHLOROTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I)
CHLOROTRIS(TRIPHENYLPHOSPHINE)RHODATE (I)
CHLORO TRIS ( TRIPHENYL PHOSPHANE ) RHODIUM (1)
Chlorotris-(triphenylphosphino)-rhodium
TRIS(TRIPHENYLPHOSPHINE)RHODIUM(1) CHLORIDE
TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CHLORIDE POLYMER BOUND
(sp-4-2)-rhodiu
Rhodium, chlorotris(triphenylphosphine)-
Rhodium, chlorotris(triphenylphosphine)-, (SP-4-2)-
Tris(triphenylphosphine)chlororhodium(I)
Tris(triphenylphosphine)rhodium monochloride
CHLOROTRI(TRIPHENYLPHOSPHINE)RHODIUMDATE
Tris(triphenylphosphin)rhodium(I)chlorid
Chlorotris(triphenylphosphine)rhodium(I) Wilkinson's catalyst Store under inert gas Reacts with oxygen in solution
Chlorotis(trisphenylphosphine)Rhodium(I)
Rhodium(I) tris(triphenylphosphine) chloride, Wilkinsons catalyst
Tris(triphenylphosphine)rhodium(I) chloride,98%
Tris(triphenylphosphine)chlororhodium,10.8to11.2%(Rh)
Tris(triphenylphosphine)rhodium(I) chloride ,99%
Chlorotri (triphenyl
Tris(triphenylphosphine)rhodium(I) chloride, (trace metal basis), 99.99%
Tris(triphenylphosphine)-rhodiuM(I) chloride (11% RH)
Tris(triphenylphosphine)rhodiuM(I) chloride ,99% [C : 69.3%-69.4%]
Tris(triphenylphosphine)rhodiuM(I) chloride, 98% 1GR
Tris(triphenylphosphine)rhodiuM(I) chloride, 99.99% 1GR
Tris(triphenylphosphine)rhodiumchloride
Tris(triphenylphosphino)chlororhodium
RHODIUM(I) TRIS(TRIPHENYLPHOSPHINE) CHLORIDE
RHODIUM TRIS(TRIPHENYL-PHOSPHINE)CHLORIDE
Chlorotri (triphenylphosphine) rhodium
Chlorotris(triphenylphosphine)rhodium(I)~Wilkinsons Catalyst
Tris(tripehnylphosphine)rhodium(I)chloride
Chlorotris(triphenylphosphine)rhodium(I), 99.99% metals basis
Chlorotris(triphenylphosphine) rhodium
Tris(triphenylphosphine)rhodium(I) chloride, 99.99%
Chlorotris(triphenylphosphine)rhodium(I),99%WILKINSON'SCATALYST
Polymer-boundchlorotris(triphenylphosphine)rhodium(I)onstyrene-divinylbenzenecopolymer(20%cross-linked)
Chlorotris(triphenylphosphine)rhodiuM(I),98% WILKINSON'S CATALYST
NSC 124140
Tris(triphenylphosphine)chlororhodiu
Chlorotris(triphenylphosphine)rhodium(I)
Wilkinson Catalyst
Chlorotris(triphenylphosphine) RhodiuM(I) [ilkinson Catalyst
Tris(triphenylphosphine)rhodiuM(I) chloride, 99.99%, (trace Metal basis)
TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CHLOR
Tris(triphenylphosphine)chloro
Tris(triphenylphosphine)rodiuM(I) Chloride
Tetra(triphenylphosphine)-RhodiuM(I) chloride
Tris(triphenylphosphine)rhodium(Ⅰ) chlorideTris(triphenylphosphine)rhodium(Ⅰ) chloride
Tris(triphenylphosphine)rhodiuM(I) chloride, 99.99% Metals basis
Tris(triphenylphosphine)rhodium(I) chloride 99.9% trace metals basis
Tris(triphenylphosphine)rhodium(I) chloride (11% Rh) for synthesis
chloridotris(triphenylphosphine)rhodium(I)
Rh11.1%Tris(triphenylphosphine)chlororhodium(I I)
Tris(triphenylphosphine)rhodiu
TRIS(TRIPHENYLPHOSPHINE)RH
Chlorotris(triphenylphosphine)rhodium(Ⅰ)
phosphine)rhodium(I) chL