Tris(triphenylphosphine)rhodiu
Tris(triphenylphosphine)rhodiu
- CAS:
- 14694-95-2
- MF:
- C54H45ClP3Rh
- MW:
- 925.21
Suppliers by country/region
Company Type
Properties
- Melting point:
- 245-250 °C (dec.)
- Boiling point:
- >170°C
- Density
- 1.363; d 1.379
- vapor pressure
- 0Pa at 25℃
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- solubility
- Soluble in most solvents (e.g. benzene, ethanol, chloroform, dichloromethane) but with phosphine dissociation. Reacts with O{2} in solution
- form
- Crystalline Powder
- color
- Red-brown to maroon
- Water Solubility
- insoluble
- Hydrolytic Sensitivity
- 4: no reaction with water under neutral conditions
- Sensitive
- air sensitive
- Merck
- 14,9758
- BRN
- 4581440
- Exposure limits
- ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
- InChIKey
- QEYYHUJFSQCTAE-UHFFFAOYSA-M
- LogP
- 5.69 at 20℃
Safety Information
- Symbol(GHS)
GHS07
- Signal word
- Warning
- Hazard statements
- H317-H413
- Precautionary statements
- P261-P272-P273-P280-P302+P352-P333+P313
- Hazard Codes
- C,Xi
- Risk Statements
- 34-36/38
- Safety Statements
- 22-24/25-37/39-28A-26-15-45-36/37/39
- RIDADR
- 1759
- WGK Germany
- 1
- F
- 8-10-23
- TSCA
- Yes
- HS Code
- 28439090
Use
Tris(triphenylphosphine)rhodiu is also known as Wilkinson's catalyst and is commonly used to catalyze the hydrogenation of alkenes. Tris(triphenylphosphine)rhodiu is also used in the catalytic hydroboration of alkenes with catecholborane and pinacolborane and the selective 1,4-reduction of α, β-unsaturated carbonyl compounds.
17 India supplier list of "Tris(triphenylphosphine)rhodiu"
- Product Name:TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I)CHLORIDE
- Products Intro:Purity: 99% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
- Company Type: Manufacturer
- Country/Region: Maharashtra,INDIA
- Product Name:Chlorotris-(triphenylphosphino)-rhodium
- Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg And 1MT
- Company Type: Manufacturer
- Country/Region: Maharashtra,INDIA
- Product Name:Chlorotris-(triphenylphosphino)-rhodium
- Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
- Company Type: Trader
- Country/Region: Hyderabad,INDIA
- Product Name:Rhodium(I) tris(triphenylphosphine)
- Products Intro:Purity: 99% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
- Company Type: Trader
- Country/Region: Gujarat,INDIA
- Product Name:Chlorotris-(triphenylphosphino)-rhodium
- Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
- Company Type: Reagent
- Country/Region: Maharashtra,INDIA
- Product Name:Chlorotris-(triphenylphosphino)-rhodium
- Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
- Company Type: Manufacturer
- Country/Region: Maharashtra,INDIA
- Product Name:Tris(triphenylphosphine)rhodium(I) chloride
- Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
- Company Type: Reagent
- Country/Region: Mumbai,INDIA
- Product Name:Tris(triphenylphosphine)rhodium(I)chloride
- Products Intro:Brand:sigma aldrich | Product Number:205036 | Purity:99.9%tracemetalsbasis
- Company Type: Trader
- Country/Region: Bangalore,INDIA