Tris(dibenzylideneacetone)dipalladium
![Tris(dibenzylideneacetone)dipalladium Structure](CAS/20180906/GIF/51364-51-3.gif)
- CAS No.
- 51364-51-3
- Chemical Name:
- Tris(dibenzylideneacetone)dipalladium
- Synonyms
- (DBA)3PD2;Tris(dibenzylideneacetone)palladium;tris(1,5-diphenylpenta-1,4-dien-3-one) dipalladium;Pd2(dbba)3;Pd2(dibenzylideneacetone)3;Tris(dibenzylideneacetonyl)bis-palladium;Tris(dibenzylidenaceTone) dipalladium (O);Tris(dibenzylideneac;Tris(dibenzyL;ideneacetone)dipaL
- CBNumber:
- CB9855353
- Molecular Formula:
- C51H42O3Pd2
- Molecular Weight:
- 915.71738
- MOL File:
- 51364-51-3.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/5/9 14:46:00
Melting point | 152-155°C |
---|---|
storage temp. | 2-8°C |
solubility | Soluble in chlorinated solvents, benzene and THF. |
form | Fine Crystalline Powder |
color | Purple to black |
Water Solubility | insoluble |
Sensitive | Air & Moisture Sensitive |
InChIKey | IBXMKLPFLZYRQZ-VCHVFRDLSA-N |
CAS DataBase Reference | 51364-51-3(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() ![]() GHS07,GHS09 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Warning | |||||||||
Hazard statements | H317-H411 | |||||||||
Precautionary statements | P261-P272-P273-P280-P302+P352-P333+P313 | |||||||||
Hazard Codes | Xn | |||||||||
Risk Statements | 20/22-36-40 | |||||||||
Safety Statements | 24/25-36/37 | |||||||||
WGK Germany | 3 | |||||||||
TSCA | No | |||||||||
HS Code | 28439000 | |||||||||
NFPA 704 |
|
Tris(dibenzylideneacetone)dipalladium price More Price(20)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 328774 | Tris(dibenzylideneacetone)dipalladium(0) 97% | 51364-51-3 | 500MG | ₹5572.2 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 919772 | Tris(dibenzylideneacetone)dipalladium(0) ChemBeads | 51364-51-3 | 250MG | ₹10467.78 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 919772 | Tris(dibenzylideneacetone)dipalladium(0) ChemBeads | 51364-51-3 | 1G | ₹26174.85 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 683345 | [Pd2(dba)3] x dba Umicore | 51364-51-3 | 500MG | ₹5505.6 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 328774 | Tris(dibenzylideneacetone)dipalladium(0) 97% | 51364-51-3 | 1G | ₹9679.2 | 2022-06-14 | Buy |
Tris(dibenzylideneacetone)dipalladium Chemical Properties,Uses,Production
Chemical Properties
dark purple solid
Uses
Tris(dibenzylideneacetone)dipalladium is used in the preparation of semiconducting polymers processed from nonchlorinated solvents into high performance thin film transistors. It is also used as a semiconductor in the synthesis of polymer bulk-heterojunction solar cells.
Preparation
First reported in 1970,Tris(dibenzylideneacetone)dipalladium(0) is prepared from dibenzylideneacetone and sodium tetrachloropalladate. Because it is commonly recrystallized from chloroform, the complex is often supplied as the adduct [Pd2(dba)3·CHCl3].The purity of samples can be variable.
General Description
Tris(dibenzylideneacetone)dipalladium(0) (Pd2(dba)3) participates in the synthesis of azepane. Crystal structure of Pd2(dba)3 has been determined by three-dimensional X-ray data. Crystals of Pd2(dba)3 are reported to crystalize in triclinic system. It is widely used Pd(0) source in Pd-mediated transformations.
Structure and conformation
In [Pd2(dba)3], the pair of Pd atoms are separated by 320 pm but are tied together by dba units.The Pd(0) centres are bound to the alkene parts of the dba ligands.
Tris(dibenzylideneacetone)dipalladium Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
DAVY CHEM LABS | +91-9603460845 +91-9493444489 | Hyderabad, India | 109 | 58 | Inquiry |
JIVICHEM SYNTHESIS PVT LTD | +91-7028392790 +91-7028392790 | Maharashtra, India | 337 | 58 | Inquiry |
Evans Fine Chem | +91-9821340302 +91-9821340302 | Maharashtra, India | 286 | 58 | Inquiry |
JSK Chemicals | +919879767970 | Gujarat, India | 3756 | 58 | Inquiry |
Vineeth Precious Catalysts Pvt Ltd | +91-9049600004 +91-9049600004 | Mumbai, India | 29 | 58 | Inquiry |
Omkar Lab | +91-9130062553 +91-9326135973 | Maharashtra, India | 47 | 58 | Inquiry |
Johnson Matthey Chemicals India Pvt Ltd | +91-9820622275 +91-9711869003 | Maharashtra, India | 69 | 58 | Inquiry |
VASIN BIO LIFE SCIENCES PVT LTD | 9491644688 | Hyderabad, India | 2096 | 58 | Inquiry |
Dhara Industries (Formerly known as Karolinska Industries) | 91-9322395199 | Maharashtra, India | 97 | 58 | Inquiry |
Evans Chem India Pvt., Ltd. | 91-22-26162085 | Maharashtra, India | 27 | 58 | Inquiry |
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