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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organic palladium >Tris(dibenzylideneacetone)dipalladium

Tris(dibenzylideneacetone)dipalladium

Tris(dibenzylideneacetone)dipalladium Structure
  • ₹4680 - ₹810677.4
  • Product name: Tris(dibenzylideneacetone)dipalladium
  • CAS: 51364-51-3
  • MF: C51H42O3Pd2
  • MW: 915.71738
  • EINECS:610-654-4
  • MDL Number:MFCD00013310
  • Synonyms:Bis(dibenzylideneacetone)palladium(0)~Pd_2(dba)_3;Tris(dibezylideneacetone)dipalladium;Palladium, tris.mu.-(1,2-.eta.:4,5-.eta.)-(1E,4E)-1,5-diphenyl-1,4-pentadien-3-onedi-;Tris(dibenzylidenaceton)dipalladium;TRIS(BIBENZYLIDENEACETONE) DIPALLADIUM;Tris(dibenzylideneacetone)dipalladium(0), Pd 21.5% min;Tris(dibenzylideneacetone)dipalladium(0), Pd content 22-24%;TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM,20.3%
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  • Sigma-Aldrich(India)
  • ALFA India
  • TCI Chemicals (India)
  • ottokemi
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  • ManufacturerSigma-Aldrich(India)
  • Product number328774
  • Product descriptionTris(dibenzylideneacetone)dipalladium(0) 97%
  • Packaging500G
  • Price₹810677.4
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number328774
  • Product descriptionTris(dibenzylideneacetone)dipalladium(0) 97%
  • Packaging100G
  • Price₹349594.5
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number328774
  • Product descriptionTris(dibenzylideneacetone)dipalladium(0) 97%
  • Packaging50G
  • Price₹181362.9
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number683345
  • Product description[Pd2(dba)3] x dba Umicore
  • Packaging50G
  • Price₹133299.9
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number328774
  • Product descriptionTris(dibenzylideneacetone)dipalladium(0) 97%
  • Packaging25G
  • Price₹93273.3
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number328774
  • Product descriptionTris(dibenzylideneacetone)dipalladium(0) 97%
  • Packaging5G
  • Price₹29825.7
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number683345
  • Product description[Pd2(dba)3] x dba Umicore
  • Packaging5G
  • Price₹29725.8
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number919772
  • Product descriptionTris(dibenzylideneacetone)dipalladium(0) ChemBeads
  • Packaging1G
  • Price₹26174.85
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number919772
  • Product descriptionTris(dibenzylideneacetone)dipalladium(0) ChemBeads
  • Packaging250MG
  • Price₹10467.78
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number328774
  • Product descriptionTris(dibenzylideneacetone)dipalladium(0) 97%
  • Packaging1G
  • Price₹9679.2
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number328774
  • Product descriptionTris(dibenzylideneacetone)dipalladium(0) 97%
  • Packaging500MG
  • Price₹5572.2
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number683345
  • Product description[Pd2(dba)3] x dba Umicore
  • Packaging500MG
  • Price₹5505.6
  • Updated2022-06-14
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  • ManufacturerALFA India
  • Product numberALF-012760-14
  • Product descriptionTris(dibenzylideneacetone)dipalladium(0), Pd 21.5% min.
  • Packaging25g
  • Price₹107010
  • Updated2022-05-26
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  • ManufacturerALFA India
  • Product numberALF-012760-09
  • Product descriptionTris(dibenzylideneacetone)dipalladium(0), Pd 21.5% min.
  • Packaging10g
  • Price₹45900
  • Updated2022-05-26
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  • ManufacturerTCI Chemicals (India)
  • Product numberT2184
  • Product descriptionTris(dibenzylideneacetone)dipalladium(0)
  • Packaging1G
  • Price₹10700
  • Updated2022-05-26
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  • ManufacturerTCI Chemicals (India)
  • Product numberT2184
  • Product descriptionTris(dibenzylideneacetone)dipalladium(0)
  • Packaging5G
  • Price₹47600
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 328774 Tris(dibenzylideneacetone)dipalladium(0) 97% 500G ₹810677.4 2022-06-14 Buy
Sigma-Aldrich(India) 328774 Tris(dibenzylideneacetone)dipalladium(0) 97% 100G ₹349594.5 2022-06-14 Buy
Sigma-Aldrich(India) 328774 Tris(dibenzylideneacetone)dipalladium(0) 97% 50G ₹181362.9 2022-06-14 Buy
Sigma-Aldrich(India) 683345 [Pd2(dba)3] x dba Umicore 50G ₹133299.9 2022-06-14 Buy
Sigma-Aldrich(India) 328774 Tris(dibenzylideneacetone)dipalladium(0) 97% 25G ₹93273.3 2022-06-14 Buy
Sigma-Aldrich(India) 328774 Tris(dibenzylideneacetone)dipalladium(0) 97% 5G ₹29825.7 2022-06-14 Buy
Sigma-Aldrich(India) 683345 [Pd2(dba)3] x dba Umicore 5G ₹29725.8 2022-06-14 Buy
Sigma-Aldrich(India) 919772 Tris(dibenzylideneacetone)dipalladium(0) ChemBeads 1G ₹26174.85 2022-06-14 Buy
Sigma-Aldrich(India) 919772 Tris(dibenzylideneacetone)dipalladium(0) ChemBeads 250MG ₹10467.78 2022-06-14 Buy
Sigma-Aldrich(India) 328774 Tris(dibenzylideneacetone)dipalladium(0) 97% 1G ₹9679.2 2022-06-14 Buy
Sigma-Aldrich(India) 328774 Tris(dibenzylideneacetone)dipalladium(0) 97% 500MG ₹5572.2 2022-06-14 Buy
Sigma-Aldrich(India) 683345 [Pd2(dba)3] x dba Umicore 500MG ₹5505.6 2022-06-14 Buy
ALFA India ALF-012760-14 Tris(dibenzylideneacetone)dipalladium(0), Pd 21.5% min. 25g ₹107010 2022-05-26 Buy
ALFA India ALF-012760-09 Tris(dibenzylideneacetone)dipalladium(0), Pd 21.5% min. 10g ₹45900 2022-05-26 Buy
TCI Chemicals (India) T2184 Tris(dibenzylideneacetone)dipalladium(0) 1G ₹10700 2022-05-26 Buy
TCI Chemicals (India) T2184 Tris(dibenzylideneacetone)dipalladium(0) 5G ₹47600 2022-05-26 Buy

Properties

Melting point :152-155°C
storage temp. :2-8°C
solubility :Soluble in chlorinated solvents, benzene and THF.
form :Fine Crystalline Powder
color :Purple to black
Water Solubility :insoluble
Sensitive :Air & Moisture Sensitive
InChIKey :IBXMKLPFLZYRQZ-VCHVFRDLSA-N
CAS DataBase Reference :51364-51-3(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 2
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P333+P313 IF SKIN irritation or rash occurs: Get medical advice/attention.

Description

Tris(dibenzylideneacetone)dipalladium(0) is the most widely used Pd0 precursor complex in synthesis and catalysis, in particular as a catalyst for various coupling reactions. It is used as a catalyst precursor for palladium-catalyzed carbon-nitrogen bond formation, conversion of aryl chlorides, triflates and nonaflates to nitroaromatics. It is used as catalyst for the synthesis of epoxides, alpha-arylation of ketones, in combination with BINAP for the asymmetric heck arylation of olefins, site-selective benzylic sp3 palladium-catalyzed direct arylation and homoallylic diamination of terminal olefins. It also used for palladium-catalyzed one-pot synthesis of tricyclic indolines, in the Suzuki-Miyaura coupling of 2-pyridyl nucleophiles and cross-coupling of aryl halides with aryl boronic acids.

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