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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organic rhodium >Chloro(1,5-cyclooctadiene)rhodium(I) dimer

Chloro(1,5-cyclooctadiene)rhodium(I) dimer

Chloro(1,5-cyclooctadiene)rhodium(I) dimer Structure
  • ₹7400 - ₹81684.9
  • Product name: Chloro(1,5-cyclooctadiene)rhodium(I) dimer
  • CAS: 12092-47-6
  • MF: C16H24Cl2Rh2
  • MW: 493.08
  • EINECS:235-157-6
  • MDL Number:MFCD00012415
  • Synonyms:Bis(1,5-cyclohexadiene)-mu,mu'-dichlorodirhodium;Bis(cycloocta-1,5-diene)dichlorodirhodium;Chloro(1,5-cyclooctadiene)rhodium dimer;Dichloro-bis-1,5-cyclooctadiene dirhodium;Di-mu-chlorobis(1,5-cyclooctadiene)dirhodium;di-mu-chlorobis[(1,2,5,6-eta)-1,5-cyclooctadiene]di-rhodiu ;Rhodium 1,5-cyclooctadiene chloride dimer;Rhodium chloro(cycloocta-1,5-diene) dimer
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  • ALFA India
  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 100MG
  • 250mg
  • 500MG
  • 1g
  • 2G
  • 5G
  • ManufacturerALFA India
  • Product numberALF-010466-03
  • Product descriptionChloro(1,5-cyclooctadiene)rhodium(I) dimer
  • Packaging1g
  • Price₹21341
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-010466-MD
  • Product descriptionChloro(1,5-cyclooctadiene)rhodium(I) dimer
  • Packaging250mg
  • Price₹70710
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB1045
  • Product descriptionChloro(1,5-cyclooctadiene)rhodium(I) Dimer
  • Packaging100MG
  • Price₹7400
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB1045
  • Product descriptionChloro(1,5-cyclooctadiene)rhodium(I) Dimer
  • Packaging1G
  • Price₹23000
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number683132
  • Product descriptionChiralyst P493 Umicore, 98%
  • Packaging500MG
  • Price₹22444.2
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number227951
  • Product descriptionChloro(1,5-cyclooctadiene)rhodium(I) dimer 98%
  • Packaging500MG
  • Price₹33133.5
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number227951
  • Product descriptionChloro(1,5-cyclooctadiene)rhodium(I) dimer 98%
  • Packaging5G
  • Price₹64979.4
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number683132
  • Product descriptionChiralyst P493 Umicore, 98%
  • Packaging2G
  • Price₹81684.9
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
ALFA India ALF-010466-03 Chloro(1,5-cyclooctadiene)rhodium(I) dimer 1g ₹21341 2022-05-26 Buy
ALFA India ALF-010466-MD Chloro(1,5-cyclooctadiene)rhodium(I) dimer 250mg ₹70710 2022-05-26 Buy
TCI Chemicals (India) B1045 Chloro(1,5-cyclooctadiene)rhodium(I) Dimer 100MG ₹7400 2022-05-26 Buy
TCI Chemicals (India) B1045 Chloro(1,5-cyclooctadiene)rhodium(I) Dimer 1G ₹23000 2022-05-26 Buy
Sigma-Aldrich(India) 683132 Chiralyst P493 Umicore, 98% 500MG ₹22444.2 2022-06-14 Buy
Sigma-Aldrich(India) 227951 Chloro(1,5-cyclooctadiene)rhodium(I) dimer 98% 500MG ₹33133.5 2022-06-14 Buy
Sigma-Aldrich(India) 227951 Chloro(1,5-cyclooctadiene)rhodium(I) dimer 98% 5G ₹64979.4 2022-06-14 Buy
Sigma-Aldrich(India) 683132 Chiralyst P493 Umicore, 98% 2G ₹81684.9 2022-06-14 Buy

Properties

Melting point :243 °C (dec.) (lit.)
Density :1.94[at 20℃]
vapor pressure :0Pa at 25℃
storage temp. :Inert atmosphere,Room Temperature
solubility :Soluble in chloroform, dichloromethane, and methanol. Sparingly soluble in most common solvents.
form :Crystals or Crystalline Powder
color :Orange to orange-brown
Water Solubility :1.56g/L at 20℃
Sensitive :Air Sensitive & Hygroscopic
Exposure limits :ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3
NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3 Stability :hygroscopic
LogP :3.16 at 20℃
NIST Chemistry Reference :Bis(1,5-cyclooctadienerhodium chloride)(12092-47-6)
EPA Substance Registry System :Rhodium, di-.mu.-chlorobis[(1,2,5,6-.eta.)-1,5-cyclooctadiene]di- (12092-47-6)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
Precautionary statements:
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P337+P313 IF eye irritation persists: Get medical advice/attention.

Description

It is a widely used precursor to homogeneous catalysts. This is a chiral catalyst capable of asymmetrically hydrogenating certain prochiral alkenes. Chloro(1,5-cyclooctadiene)rhodium(I) dimer is also used in the synthesis of other metal ligands for use in catalysis.

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