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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organic ruthenium >Carbonylchlorohydrotris(triphenylphosphine)ruthenium

Carbonylchlorohydrotris(triphenylphosphine)ruthenium

Carbonylchlorohydrotris(triphenylphosphine)ruthenium Structure
  • ₹14696.4
  • Product name: Carbonylchlorohydrotris(triphenylphosphine)ruthenium
  • CAS: 16971-33-8
  • MF: C55H45ClOP3Ru
  • MW: 951.39
  • EINECS:241-051-0
  • MDL Number:MFCD31942895
  • Synonyms:CARBONYLCHLOROHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II);carbonylchlorohydridotris(triphenyl-phosphine)rut;carbonylchlorohydrotris(triphenylphosphine)ruthenium;Hydridochlorocarbonyltris-(triphenylphosphino)-ruthenium;Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II),99%;Carbonylchlorohydrido tris (triphenylphosphine) ru;Carbonylchlorohydridotris(triphenylphosphine)rutheniuM(II),98% (PPh3)3(CO)HRuCl;Ru(CO)ClH(PPh3)3
Price2 Properties Safety Information Description
2 prices
Selected condition：

Brand

  • Sigma-Aldrich
  • Sigma-Aldrich(India)

Package

  • 1G
  • ManufacturerSigma-Aldrich
  • Product number334995
  • Product descriptionCarbonylchlorohydridotris(triphenylphosphine)ruthenium(II)
  • Packaging1G
  • Price₹14696.4
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number334995
  • Product descriptionCarbonylchlorohydridotris(triphenylphosphine)ruthenium(II)
  • Packaging1G
  • Price₹14696.4
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich 334995 Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) 1G ₹14696.4 2022-06-14 Buy
Sigma-Aldrich(India) 334995 Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) 1G ₹14696.4 2022-06-14 Buy

Properties

Melting point :204-206 °C (dec.)(lit.)
Boiling point :approximate 360℃
storage temp. :Keep in dark place,Inert atmosphere,Room temperature
form :Powder
color :Cream to tan
Water Solubility :insoluble
Sensitive :Air stable, light sensitive

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) is used as a raw material to synthesize other ru-hydride catalysts. It is involved in the hydrogenation of ring-opening metathesis polymers such as norbornene and other cyclic olefin ROMP polymers used as plastics, resins and optical materials. It can act as an alternative catalyst to rhodium hydrogenation catalyst. It also serves as a catalyst in the hydrogenation of conjugated diene copolymers like acrylonitrile-butadiene rubber (NBR).

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Suppliers and manufacturers

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