ChemicalBook > Product Catalog >Organic Chemistry >Organometallic compounds >Organic palladium >Tris(dibenzylideneacetone)dipalladium-chloroform adduct

Tris(dibenzylideneacetone)dipalladium-chloroform adduct

Tris(dibenzylideneacetone)dipalladium-chloroform adduct Structure
CAS No.
52522-40-4
Chemical Name:
Tris(dibenzylideneacetone)dipalladium-chloroform adduct
Synonyms
Pd2dba3.CHCl3;TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM CHLOROFORM COMPLEX;TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM(0) CHLOROFORM ADDUCT;Pd2(bda)3 CHCl3;TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM-CHLOROFORM;Tris(dibenzylideneacetone)dipalladium(0)-chloroform;chloroform,(1E,4E)-1,5-diphenylpenta-1,4-dien-3-one,palladium;Tris DBA;adium-chL;oroform adduct
CBNumber:
CB2298434
Molecular Formula:
C52H31Cl3O3Pd2
Molecular Weight:
1023.01
MOL File:
52522-40-4.mol
Modify Date:
2023/4/23 16:37:41

Tris(dibenzylideneacetone)dipalladium-chloroform adduct Properties

Melting point 131-135 °C(lit.)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
form Crystalline Powder
color Purple to black
Water Solubility Soluble in organic solvents. Insoluble in water.
Sensitive Air & Moisture Sensitive
InChIKey NLYJPAJWGANOKG-CXKPDERJSA-N

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07,GHS08
Signal word  Warning
Hazard statements  H302-H315-H351
Precautionary statements  P201-P202-P264-P301+P312-P302+P352-P308+P313
Hazard Codes  Xn,Xi
Risk Statements  22-38-40-48/20/22-36/37/38
Safety Statements  36/37-37/39-26
WGK Germany  3
TSCA  No
HS Code  28439000
NFPA 704
1
2 0

Tris(dibenzylideneacetone)dipalladium-chloroform adduct price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 366315 Tris(dibenzylideneacetone)dipalladium(0)-chloroform adduct 52522-40-4 250MG ₹1309.8 2022-06-14 Buy
Sigma-Aldrich(India) 366315 Tris(dibenzylideneacetone)dipalladium(0)-chloroform adduct 52522-40-4 1G ₹6648.9 2022-06-14 Buy
Product number Packaging Price Buy
366315 250MG ₹1309.8 Buy
366315 1G ₹6648.9 Buy

Tris(dibenzylideneacetone)dipalladium-chloroform adduct Chemical Properties,Uses,Production

Chemical Properties

purple to black crystalline powder

Uses

suzuki reaction

Application

Tris(dibenzylideneacetone)dipalladium-chloroform adduct (Pd2dba3·CHCl3) was used in the following studies:
To compose the catalytic system for the preparation of homoallylpalladium complexes.These complexes underwent in situ Stille type cross coupling with various vinyltin reagents to afford the cyclized products bearing allyl appendages.
As palladium source in the asymmetric transformations of 3,4-epoxy-1-butene.
As catalyst for the Heck cross-coupling reaction of iodobenzene with styrene.
As cyclization catalyst.
As catalyst for [2+2+2] cycloaddtion of didehydrotriphenylenes to the corresponding extended triphenylenes.
As catalyst for the carbonylation of b,b-imidoyl iodides to the corresponding imidate esters used, in turn, to prepare cyclic, quaternary amino acids.

General Description

Tris(dibenzylideneacetone)dipalladium(0)-chloroform adduct (Pd2dba3·CHCl3) is reported to serve as effective precatalysts, or precursors to the active Pd(0) catalyst.

Biological Activity

N -myristoyltransferase-1 (NMT-1) inhibitor that prevents activation of MAPK, PI 3-K and STAT3 signaling pathways. Exhibits antiproliferative activity against melanoma cells in vitro and in vivo . Also used as a cyclization catalyst.

Tris(dibenzylideneacetone)dipalladium-chloroform adduct Preparation Products And Raw materials

Global( 289)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
Johnson Matthey Chemicals India Pvt Ltd +91-9820622275 +91-9711869003 Maharashtra, India 69 58 Inquiry
Vineeth Precious Catalysts Pvt Ltd +91-9049600004 +91-9049600004 Mumbai, India 29 58 Inquiry
Omkar Lab +91-9130062553 +91-9326135973 Maharashtra, India 47 58 Inquiry
ALS INDIA LIFE SCIENCES +91-8977036379 +91-8977036379 Hyderabad, India 1879 58 Inquiry
CHEMSWORTH +91-261-2397244 New Delhi, India 6707 30 Inquiry
CLEARSYNTH LABS LTD. +91-22-45045900 Hyderabad, India 6351 58 Inquiry
A.J Chemicals 91-9810153283 New Delhi, India 6124 58 Inquiry
Reax Chemicals 08048372701Ext 416 Hyderabad, India 4223 58 Inquiry
Avra Synthesis Pvt Ltd +914027175796 New Delhi, India 1606 30 Inquiry
LOBA CHEMIE PVT.LTD. 91-22-6663 6699 Mumbai, India 3077 58 Inquiry
TRIS(DIBENZYLIDENEACETONE)(CHLOROFORM)-DI-PALLADIUM(0) TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM-CHLOROFORM ADDUCT DIPALLADIUM(0)TRIS(DIBENZYLIDENEACETONE)-CHLOROFORM ADDUCT DI-PALLADIUM-TRIS(DIBENZYLIDENEACETONE)CHLOROFORM COMPLEX Dipalladiumtris(dibenzylideneacetone) chloroform adduct TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM(0) CHLOROFORM ADDUCT 98+% Tris(dibenylideneacetone)dipalladium-chloroform Tris (dibenzylidene acetone)di palladiuM(O)-chloroforM addict Tris DBA chloroform adduct Tris(dibenzylideneacetone)dipalladium(0), complex with chloroform, Pd 20.6% Tris(dibenzylideneacetone)dipalladium-chloroform adduct,97% Tris-(dibenzylideneacetone)-dipalladium(O)-chloroform adduct Tris(Dibenzylideneacetone)Dipalladium(0), Complex With Chloroform, Pd Tris DBA Tris(dibenzylideneacetone)dipalladium(0) chloroform adduct [Pd > 20.2%] Tris(dibenzylideneacetone)dipalladiuM-chloroforM adduct, 97% 1GR Tris(dibenzylideneacetone)dipalladiuM (0) chloroforM adduct, Pd2(dba)3·CHCl3 Tris(Dibenzylideneacetone)DipalladiuM- ChloroforM AdduCL 2,2'',3',6,6'',7'-hexaphenyldispiro[1-palladatricyclo[3.1.0.0^{1,3}]hexane-1,2'-[1,2]dipalladatricyclo[4.1.0.0^{2,4}]heptane-1',1''-[1]palladatricyclo[3.1.0.0^{1,3}]hexane]-2,2'',3',5,5'',6'-hexaene-4,4'',5'-trione adium-chL oroform adduct DIPALLADIUM(0)TRIS(DIBENZYLI tris(dibenzylideneacetone)(chloroform)-di-p Tris(dibenzylideneacetone)dipalladium-chloroform a Tris(dibenzylideneacetone)dipalladium chloroform adduct 98% (1E,4E)-1,5-diphenyl-3-penta-1,4-dienone Tris(dibenzylideneacetone)dipalladium-chloroform adduct ISO 9001:2015 REACH Tris(dibenzylideneacetone)dipalladium-chloroform adduct 52522-40-4 TRIS (DIBENZYLIDENEACETONE) DIPALLADIUM CHLOROFORM ADDUCT For Synthesis TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM(0) CHLOROFORM ADDUCT TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM CHLOROFORM COMPLEX TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM-CHLOROFORM chloroform,(1E,4E)-1,5-diphenylpenta-1,4-dien-3-one,palladium Tris(dibenzylideneacetone)dipalladium(0)-chloroform Pd2dba3.CHCl3 Pd2(bda)3 CHCl3 Palladium, tris[μ-[(1,2-η:4,5-η)-(1E,4E)-1,5-diphenyl-1,4-pentadien-3-one]]di-, compd. with trichloromethane (1:1) (9CI, ACI) Trismu-(1,2-eta:4,5-eta)-(1E,4E)-1,5-diphenyl-1,4-pentadien-3-onedi-palladium compd. with trichloromethane (1:1) 52522-40-4 52552-40-4 C52H43Cl3O3Pd2 C51H42O3Pd2CHCl3 Pd2C17H14O3CHCl3 C6H5CHCHCOCHCHC6H53Pd2CHCl3 C52Cl3H43O3Pd2 C35H29Cl3O2Pd C6H5CHCHCOCHCHC6H53Pd2稢HCl3 3C17H14OCHCl32Pd Catalysis and Inorganic Chemistry New Products for Chemical Synthesis May/June 2007 Homogeneous Pd Catalysts organometallic complexes Metal Compounds