Allyl glycidyl ether
- CAS No.
- 106-92-3
- Chemical Name:
- Allyl glycidyl ether
- Synonyms
- AGE;allyl;Allylglycidaether;M 560;NCI-C56666;Ageflex AGE;Sipomer AGE;Allylglycide ether;ALLYLGLYCIDOLETHER;Ally glycidyl ether
- CBNumber:
- CB3852688
- Molecular Formula:
- C6H10O2
- Molecular Weight:
- 114.14
- MOL File:
- 106-92-3.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/7/4 14:04:14
| Melting point | -100 °C |
|---|---|
| Boiling point | 154 °C(lit.) |
| Density | 0.962 g/mL at 25 °C(lit.) |
| vapor density | 3.9 (vs air) |
| vapor pressure | 4.7 mm Hg ( 25 °C) |
| refractive index |
n |
| Flash point | 135 °F |
| storage temp. | Store at <= 20°C. |
| solubility | 50 g/L (20°C) |
| form | Liquid |
| color | Clear colorless |
| Specific Gravity | 0.962 |
| Water Solubility | 50 g/L (20 ºC) |
| FreezingPoint | -100 |
| BRN | 105871 |
| Henry's Law Constant | (x 10-6 atm?m3/mol): 3.83 at 20 °C (approximate - calculated from water solubility and vapor pressure) |
| Exposure limits | NIOSH REL: TWA 5 ppm (22 mg/m3), STEL 10 ppm (44 mg/m3), IDLH 50 ppm; OSHA PEL: ceiling 10 ppm; ACGIH TLV: TWA 5 ppm, STEL 10 ppm. |
| Stability | Stable. Combustible. Incompatible with strong oxidizing agents, acids, bases. May form peroxides in storage if in contact with air. |
| InChIKey | LSWYGACWGAICNM-UHFFFAOYSA-N |
| LogP | 0.45 at 25℃ |
| CAS DataBase Reference | 106-92-3(CAS DataBase Reference) |
| NIST Chemistry Reference | Oxirane, [(2-propenyloxy)methyl]-(106-92-3) |
| EPA Substance Registry System | Allyl glycidyl ether (106-92-3) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |     GHS02,GHS05,GHS06,GHS08 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H226-H302-H315-H317-H318-H331-H335-H341-H351-H361fd-H412 | |||||||||
| Precautionary statements | P210-P273-P280-P304+P340+P311-P305+P351+P338-P308+P313 | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 10-20/22-37/38-40-41-43-52/53-62-68 | |||||||||
| Safety Statements | 24/25-26-36/37/39-61 | |||||||||
| OEB | A | |||||||||
| OEL | TWA: 5 ppm (22 mg/m3), STEL: 10 ppm (44 mg/m3) [skin] | |||||||||
| RIDADR | UN 2219 3/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | RR0875000 | |||||||||
| Autoignition Temperature | 264 °C | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 3 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29109000 | |||||||||
| Toxicity | LD50 orally in Rabbit: 922 mg/kg LD50 dermal Rabbit 2550 mg/kg | |||||||||
| IDLA | 50 ppm | |||||||||
| NFPA 704 |
|
Allyl glycidyl ether price More Price(9)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | A32608 | Allyl glycidyl ether ≥99% | 106-92-3 | 100ML | ₹2132.53 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | A32608 | Allyl glycidyl ether ≥99% | 106-92-3 | 500ML | ₹6440.88 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 8.00259 | Allyl 2,3-epoxypropyl ether for synthesis | 106-92-3 | 250ML | ₹8620 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 8.00259 | Allyl 2,3-epoxypropyl ether for synthesis | 106-92-3 | 8002592500 | ₹65150.01 | 2022-06-14 | Buy |
| ALFA India | ALF-L11634-36 | Allyl glycidyl ether, 97% | 106-92-3 | 500g | ₹5148 | 2022-05-26 | Buy |
Allyl glycidyl ether Chemical Properties,Uses,Production
Chemical Properties
Allyl glycidyl ether is a stable, colorless, flammable liquid with a pleasant odor. It is incompatible with strong oxidizers agents, acids, and bases. It may form peroxides in storage if in contact with air.
Physical properties
Clear, colorless, watery, combustible liquid with a strong, pleasant odor. An odor threshold value of 47 mg/m3 was reported (quoted, Verschueren, 1983).
Uses
Allyl glycidyl ether is a monoglycidyl derivative, used as a reactive epoxy diluent for epoxy resins. As an impurity, it was considered as the sensitizing agent in a plastic industry worker allergic to 3-glycidyloxypropyltrimethoxysilane, an epoxy silane compound used as a fixing additive in silicone and polyurethane.
Production Methods
AGE is manufactured through the condensation of allyl alcohol and epichlorohydrin with subsequent dehydrochlorination with caustic to form the epoxy ring.
General Description
A colorless liquid with a pleasant odor. Flash point 135°F. Slightly less dense than water and insoluble in water. Hence floats on water. Poisonous by ingestion and mildly toxic by inhalation and skin contact. Very irritating to skin and eyes. Used to make other chemicals.
Air & Water Reactions
Flammable. Insoluble in water.
Reactivity Profile
Allyl glycidyl ether reacts violently with oxidizing agents. Can form peroxides. Polymerizes readily [Handling Chemicals Safely 1980. p.128].
Hazard
Skin, eye, and upper respiratory tract irri- tant, and dermatitis. Questionable carcinogen.
Health Hazard
Occupational workers exposed to allyl glycidyl ether develop severe symptoms of poisoning that include, but are not limited to, irritation of the eyes, redness, pain, blurred vision, deep skin burns, respiratory system; causes damage of the mucous membranes, dermatitis, burning sensation, shortness of breath, headache, drowsiness, dullness, nausea, vomiting, pulmonary edema, narcosis, possible hematopoietic and reproductive effects. Acute exposure may cause CNS depression. The major target organs include the eyes, skin, respiratory system, blood, and the reproductive system.
Fire Hazard
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
Contact allergens
Allyl glycidyl ether is a monoglycidyl derivative, used as a reactive epoxy diluent for epoxy resins. As an impurity, it was considered to be the sensitizing agent in a plastic industry worker allergic to 3-glycidyloxypropyl trimethoxysilane, an epoxy silane compound used as a fixing additive in silicone and polyurethane
Safety Profile
Confirmed animal carcinogen. Poison by ingestion. Moderately toxic by inhalation and skin contact. Mutation data reported. A severe skin and eye irritant. Can cause central nervous system depression and pulmonary edema. A flammable liquid when exposed to heat or flame; can react with oxidizing materials. To fight fire, use foam, CO2, dry chemical.When heated to decomposition it emits acrid smoke and irritating fumes. See also ALLYL COMPOUNDS
Allyl glycidyl ether has an LD50 of 390 mg/kg (mouse, oral) and an LD50 of 1600 mg/kg (rat, oral). In rabbits, the dermal LD50 is 2550 mg/kg. Inhalational toxicity has been estimated: LC50 = 270 ppm (mice, 4 h) and 670 ppm (rats, 8 h)
Potential Exposure
Used as a solvent and emulsifier; making epoxy resins, chlorinated compounds; and rubber.
Carcinogenicity
In a 2-year inhalation carcinogenicity study in Osborne Mendel rats and B6C3F1 mice (50 of each sex at each exposure level), animals were exposed to concentrations of 0, 5, or 10 ppm AGE, 6 h/day, 5 days/ week. Although occasional respiratory epithelial tumors were observed, the NTP concluded the data provided only equivocal evidence of carcinogenicity in male rats and female mice. No evidence was obtained to support a carcinogenic effect in female rats. Some evidence was provided for a carcinogenic response in male mice, which included three adenomas of the respiratory epithelium, dysplasia in four mice, and focal basal cell hyperplasia of the respiratory epithelium in the nasal passages of seven mice .
Environmental Fate
Biological. Bridié et al. (1979) reported BOD and COD values of 0.06 and 1.99 g/g using
filtered effluent from a biological sanitary waste treatment plant. These values were determined
using a standard dilution method at 20 °C for a period of 5 d. The ThOD for allyl glycidyl ether is
2.11 g/g.
Chemical/Physical. Hydrolysis of the epoxide ring is likely forming 1-allyloxy-2,3-
dihydroxypropane (Perez and Osterman-Golkar, 2000).
storage
Allyl glycidyl ether should be kept stored in a cool, dark, fi reproof area separated from strong oxidants, strong bases, and strong acids.
Shipping
UN2219 Allyl glycidal ether, Hazard Class: 3; Labels: 3-Flammable liquid
Incompatibilities
May form explosive mixture with air. Contact with acids or bases may cause explosive polymerization. Contact with oxidizers or amines may cause fire and explosions.
Waste Disposal
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.
Precautions
During use and/or handling of allyl glycidyl ether, occupational workers should not be near open flames, sparks, or smoking areas. For temperatures above 48°C, use a closedsystem ventilation and explosion-proof electrical equipment. Workers should use protective gloves, protective clothing, and avoid all contact.
Allyl glycidyl ether Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| Otto Chemie Pvt. Ltd. | +91 9820041841 | Mumbai, India | 5873 | 58 | Inquiry |
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
| Spectrochem Pvt., Ltd. | 91-22-22016968 | Maharashtra, India | 183 | 58 | Inquiry |
| Ishant Polychem | 08048372582Ext 338 | Mumbai, India | 21 | 58 | Inquiry |
| Advent Chembio Pvt., Ltd. | 91-22-27690836 | Maharashtra, India | 625 | 58 | Inquiry |
| RASCHIG PMC India Private Limited. | 91-22-42919965 | Maharashtra, India | 27 | 58 | Inquiry |
| Hebei Guanlang Biotechnology Co,.LTD | +86-19930503253; +8619930503252 | China | 5911 | 58 | Inquiry |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | China | 21675 | 55 | Inquiry |
| Shanghai Time Chemicals CO., Ltd. | +86-021-57951555 +8617317452075 | China | 1807 | 55 | Inquiry |