GLYCINE ANHYDRIDE
- CAS No.
- 106-57-0
- Chemical Name:
- GLYCINE ANHYDRIDE
- Synonyms
- Oxiracetam-1;Cyclodiglycine;Glycinanhydrid;CYCLO(-GLY-GLY);GLYCINANHYDRIDE;ycine anhydride;Glycerinanhydrid;Diketopiperazine;Diglycolydiamide;Dioxo Piperazine
- CBNumber:
- CB3356030
- Molecular Formula:
- C4H6N2O2
- Molecular Weight:
- 114.1
- MOL File:
- 106-57-0.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/5/4 15:15:41
Melting point | >300 °C (lit.) |
---|---|
Boiling point | 213.59°C (rough estimate) |
Density | 1.3565 (rough estimate) |
refractive index | 1.4487 (estimate) |
storage temp. | Store below +30°C. |
solubility | 142g/l |
pka | 12.88±0.20(Predicted) |
form | Crystalline Powder |
color | White to slightly yellow |
Water Solubility | Soluble in water (142mg/L). |
Merck | 14,7466 |
BRN | 112112 |
InChIKey | BXRNXXXXHLBUKK-UHFFFAOYSA-N |
CAS DataBase Reference | 106-57-0(CAS DataBase Reference) |
EPA Substance Registry System | 2,5-Piperazinedione (106-57-0) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
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Signal word | Warning | |||||||||
Hazard statements | H315-H319-H335 | |||||||||
Precautionary statements | P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P | |||||||||
Safety Statements | 24/25 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | TL6325250 | |||||||||
TSCA | Yes | |||||||||
HS Code | 29335990 | |||||||||
NFPA 704 |
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GLYCINE ANHYDRIDE price More Price(8)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | G7251 | Glycine anhydride cyclic dipeptide | 106-57-0 | 25G | ₹4570 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | G7251 | Glycine anhydride cyclic dipeptide | 106-57-0 | 100G | ₹15923.58 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | G7251 | Glycine anhydride cyclic dipeptide | 106-57-0 | 1KG | ₹56138.45 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 8.14160 | 2,5-Piperazinedione for synthesis | 106-57-0 | 25G | ₹11040 | 2022-06-14 | Buy |
TCI Chemicals (India) | G0100 | Glycine Anhydride | 106-57-0 | 25G | ₹4000 | 2022-05-26 | Buy |
GLYCINE ANHYDRIDE Chemical Properties,Uses,Production
Chemical Properties
white to slightly yellow crystalline powder
Uses
2,5-Piperazinedione, can be used as an intermediate in the preparation of various pharmaceutical and biologically active compounds. It can be used in the synthesis of dipeptide isosteres by cross-metathesis.
Definition
ChEBI: A cyclic peptide that is piperazine in which the hydrogens at positions 2 and 5 are replaced by oxo groups.
Purification Methods
Recrystallise glycine anhydride from H2O (plates) and it can be sublimed (slowly) at 260o or at 140-170o/0.5mm. The dihydrochloride has m 129-130o and is prepared by dissolving it in conc HCl and adding EtOH to crystallisation point; dry it in a vacuum. The bis-1-naphthylurethane has m 232o(dec), and the diperchlorate has m 117o (hygroscopic). [MS: Johnstone J Chem Soc, Perkin Trans 1 1297 1975, NMR: Blaha & Samek Collect Czech Chem Commun 32 3780 1967, Sauborn J Phys Chem 36 179 1932, Corey J Am Chem Soc 60 1599 1938, Beilstein 24 IV 1070.]
GLYCINE ANHYDRIDE Preparation Products And Raw materials
Supplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
GLR Innovations | +91 9891111994 | New Delhi, India | 4542 | 58 | Inquiry |
HiMedia Laboratories | 91-22-61471919 | Maharashtra, India | 1843 | 58 | Inquiry |
Maas Pharma Chemicals | +91-9958666224 | Delhi, India | 1607 | 58 | Inquiry |
CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6351 | 58 | Inquiry |
A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
Otto Chemie Pvt. Ltd. | +91 9820041841 | Mumbai, India | 5873 | 58 | Inquiry |
Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
Central Drug House(P) Ltd. | 91-11-49404040 | New Delhi, India | 6160 | 58 | Inquiry |
Pharmaffiliates Analytics and Synthetics P. Ltd | +91-172-5066494 | Haryana, India | 6773 | 58 | Inquiry |
Supplier | Advantage |
---|---|
GLR Innovations | 58 |
HiMedia Laboratories | 58 |
Maas Pharma Chemicals | 58 |
CLEARSYNTH LABS LTD. | 58 |
A.J Chemicals | 58 |
TCI Chemicals (India) Pvt. Ltd. | 58 |
Otto Chemie Pvt. Ltd. | 58 |
Alfa Aesar | 58 |
Central Drug House(P) Ltd. | 58 |
Pharmaffiliates Analytics and Synthetics P. Ltd | 58 |