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Polyethylene glycol mono(2-ethylhexyl) ether

Polyethylene glycol mono(2-ethylhexyl) ether Structure
CAS No.
26468-86-0
Chemical Name:
Polyethylene glycol mono(2-ethylhexyl) ether
Synonyms
EH 6;PEH 6;JFC-35;Berol 840;Newcol 1004;Newcol 1006;Newcol 1008;Newcol 1020;Blaunon EH 2;Ethylan EH 4
CBNumber:
CB3360602
Molecular Formula:
C24H50O9
Molecular Weight:
482.6484
MOL File:
26468-86-0.mol
MSDS File:
SDS
Modify Date:
2024/4/9 22:15:29

Polyethylene glycol mono(2-ethylhexyl) ether Properties

InChI InChI=1S/C24H50O9/c1-2-3-4-5-6-7-9-26-11-13-28-15-17-30-19-21-32-23-24-33-22-20-31-18-16-29-14-12-27-10-8-25/h25H,2-24H2,1H3
InChIKey YZEARKLIPBHQHG-UHFFFAOYSA-N
SMILES C(OCCCCCCCC)COCCOCCOCCOCCOCCOCCOCCO
EPA Substance Registry System Poly(oxy-1,2-ethanediyl), .alpha.-(2-ethylhexyl)-.omega.-hydroxy- (26468-86-0)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05
Signal word  Danger
Hazard statements  H318
Precautionary statements  P280-P305+P351+P338-P310

Polyethylene glycol mono(2-ethylhexyl) ether Chemical Properties,Uses,Production

Chemical Properties

Polyethylene glycol mono(2-ethylhexyl) ether is a low foaming nonionic surfactant with a high cloud point and used as a brightener in acid zinc baths.

Uses

Use as wetting agent, permeating agent. For example, used in textile, leather, chemical fiber.
Use as cleansing agent. For example, used in personal care products, household cleaning, industrial cleaning, textile, leather, chemical fiber.
Use as emulsifying agent, dispersing agent.
Use as solubilizing agent.

Side effects

The main adverse reactions to Polyethylene glycol mono(2-ethylhexyl) ether are: (1) neurotoxin - acute solvent syndrome; (2) occupational hepatotoxicity - secondary hepatotoxicity: cases in which the potential for toxic effects in an occupational setting depends on human ingestion or experimental poisoning in animals.

Synthesis

Preparation of Polyethylene glycol mono(2-ethylhexyl) ether:  In a first stage, a 1003g sample of 2-ethylhexanol (EH) was charged to a one-gallon alkoxylation reactor and dehydrated at 115-120°C under a slight nitrogen purge until the moisture content was less than 0.05%. After the dehydrated alcohol was cooled to about 90°C, 3g of boron trifluoride-etherate, included as a catalyst, was charged to the reactor. The alcohol- catalyst mixture was then mixed for 10 minutes, then purged with nitrogen 5 times to remove air and heated to 105°C. Next, 684g of ethylene oxide (EO) was added to the reactor. An exothermic reaction occurred immediately and cooling was applied throughout the EO addition to maintain the reaction temperature within the range of 105-115°C. Following the EO addition, the reaction mixture was digested at 115°C for one hour then purged with nitrogen five times and cooled to 90°C. In a second stage, 31 g of 45% potassium hydroxide, included as a second catalyst, was charged to the reactor. The mixture was then mixed for 10 minutes and then dehydrated at 110°C under nitrogen purge. When the moisture content of the mixture was less than 0.1% (after about 120 minutes of dehydration) 665g of EO was then added to the reactor. Here again, an exothermic reaction occurred and cooling was applied throughout the EO addition to maintain the reaction temperature within the range of 120-130°C. Following the EO addition, the ethoxylation reaction mixture was digested at 125°C-130°C for one hour, then purged with nitrogen five times and cooled to 65°C. Next, 16g of acetic acid was added and then the product mixture was mixed for 15 minutes then discharged. About 2270g of alcohol ethoxylate was collected.
synthesis of 26468-86-0

Polyethylene glycol mono(2-ethylhexyl) ether Preparation Products And Raw materials

Raw materials

Preparation Products

Polyethylene glycol mono(2-ethylhexyl) ether Suppliers

Global( 54)Suppliers
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Viswaat Chemicals Limited +91-7208827711 +91-8291300373 Mumbai, India 63 58 Inquiry
Wuhan Bright Chemical Co., Ltd +86-02785804899 +86-15071395570 China 93 58 Inquiry
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Polyethyleneglycolmono(2-ethylhexyl)ether ralufonen16-80 Polyethylenglykol, Mono(2-ethylhexyl)ether mit 4-35 Mol Ethylenoxid α-(2-Ethylhexyl)-ω-hydroxy-poly(oxy-1,2-ethanediyl) Polyethyleneglycol 2-ethylhexyl ether 2-ethylhexanol ethoxylate Ethylan EH 4 OCTAETHYLENEGLYCOL OCTYL ETHER RALUFON (R) EN 16-80 Berol 840 Blaunon EH 2 Blaunon EH 4 Blaunon EH 6 Ecosurf EH 6 EH 6 Ethoxylated 2-ethylhexanol Imbentin OA 100 Koremul OT 5 Newcol 1004 Newcol 1006 Newcol 1008 Newcol 1008GC Newcol 1020 Nissan Nonion EH 202 Nissan Nonion EH 203 Nonion EH 202 Nonion EH 203 PEH 6 2-ethanediyl),.alpha.-(2-ethylhexyl)-.omega.-hydroxy-Poly(oxy-1 alpha-(2-ethylhexyl)-omega-hydroxy-poly(oxy-2-ethanediyl) Poly(oxy-1,2-ethanediyl),.alpha.-(2-ethylhexyl)-.omega.-hydroxy- Poly(oxy-1,2-ethanediyl),a-(2-ethylhexyl)-w-hydroxy- JFC-35 Ethylhexanol?ethoxylate OCTAETHYLENEGLYCOL OCTYL ETHER ISO 9001:2015 REACH High temperature zinc plating carrier/Ralufon EN 16-80 Fatty alcohol ethoxylates (JFC series) penetrant EH-158 26468-86-0 xC2H4OC8H18O