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Lanthanum(III) chloride

Lanthanum(III) chloride Structure
CAS No.
10099-58-8
Chemical Name:
Lanthanum(III) chloride
Synonyms
LaCl3;LANTHANUM CHLORIDE;LANTHANUM (III) CHLORIDE;Lanthanum chloride anhydrous;ultradry;anthanum(III) chL;LANTHANIUMCHLORIDE;Lanthanumtrichloride;LANTHANUM(+3)CHLORIDE;LANTHANUM, AA STANDARD
CBNumber:
CB3402975
Molecular Formula:
Cl3La
Molecular Weight:
245.26
MOL File:
10099-58-8.mol
MSDS File:
SDS
Modify Date:
2024/7/10 14:30:11

Lanthanum(III) chloride Properties

Melting point 860 °C(lit.)
Boiling point 1812 °C(lit.)
Density 3.84 g/mL at 25 °C(lit.)
Flash point 1000°C
storage temp. Inert atmosphere,Room Temperature
form beads
color White to almost white
Specific Gravity 3.842
Water Solubility Soluble in water.
Sensitive Hygroscopic
Merck 14,5363
Stability Stability
CAS DataBase Reference 10099-58-8(CAS DataBase Reference)
EPA Substance Registry System Lanthanum chloride (LaCl3) (10099-58-8)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05,GHS07,GHS09
Signal word  Danger
Hazard statements  H290-H317-H318-H411
Precautionary statements  P234-P261-P273-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi,N
Risk Statements  36/37/38-11-51/53-43-41
Safety Statements  26-36-61-36/37/39
RIDADR  UN3264
WGK Germany  2
RTECS  OE4375000
TSCA  Yes
HazardClass  8
PackingGroup  III
HS Code  28469023
NFPA 704
0
2 1

Lanthanum(III) chloride price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 449830 Lanthanum(III) chloride AnhydroBeads?, ?10?mesh, ≥99.99% trace metals basis 10099-58-8 5G ₹11571.93 2022-06-14 Buy
Sigma-Aldrich(India) 449830 Lanthanum(III) chloride AnhydroBeads?, ?10?mesh, ≥99.99% trace metals basis 10099-58-8 25G ₹31598.18 2022-06-14 Buy
Sigma-Aldrich(India) 298182 Lanthanum(III) chloride AnhydroBeads?, ?10?mesh, 99.9% trace metals basis 10099-58-8 10G ₹11030.68 2022-06-14 Buy
Sigma-Aldrich(India) 298182 Lanthanum(III) chloride AnhydroBeads?, ?10?mesh, 99.9% trace metals basis 10099-58-8 50G ₹26975.9 2022-06-14 Buy
ALFA India ALF-039036-AP Lanthanum chloride, Releasing Agent Solution, Specpure™ 10099-58-8 500mL ₹23554 2022-05-26 Buy
Product number Packaging Price Buy
449830 5G ₹11571.93 Buy
449830 25G ₹31598.18 Buy
298182 10G ₹11030.68 Buy
298182 50G ₹26975.9 Buy
ALF-039036-AP 500mL ₹23554 Buy

Lanthanum(III) chloride Chemical Properties,Uses,Production

Description

Lanthanum(III) chloride is a relatively stable non-homogeneous catalyst widely used in a variety of organic reactions or transformations. These include the solvent-free preparation of substituted olefins via the Knoevenagel condensation method; the one-pot synthesis of 3,4-dihydropyrimidin-2(1H)-ones; and as a precursor for the synthesis of La/V co-doped TiO2 nanoparticles via the sol-gel method.

Chemical Properties

Lanthanum(III) chloride is white powder or colourless crystals

Uses

Lanthanum chloride is used to prepare other lanthanum salts. The anhydrous chloride is employed to produce lanthanum metal.

Preparation

The heptahydrate is formed by dissolving the oxide, hydroxide or carbonate in hydrochloric acid, followed by crystallization. The anhydrous chloride is obtained by heating oxide, hydroxide, or carbonate in an atmosphere of dry hydrogen chloride.
La2(CO3)3 + 6HCl → 2LnCl3 + 3CO2 + 3H2O
Another method involves heating lanthanum oxide with excess ammonium chloride at 300°C.

General Description

Lanthanum(III) chloride is white crystalline solid. Gives an amber aqueous solution that can cause destruction or irreversible alterations in human skin tissue at the site of contact. Has a severe corrosion rate on steel.

Air & Water Reactions

Deliquescent. Water soluble.

Reactivity Profile

Aqueous solutions of LANTHANUM CHLORIDE contain moderate concentrations of hydrogen ions and react as acids to neutralize bases. Does not usually react as either oxidizing agents or reducing agents but such behavior is not impossible. May catalyze organic reactions.

Health Hazard

TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.

Lanthanum(III) chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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Lanthanum chloride anhydrous≥ 99.99% (Assay) LANTHANUM(+3)CHLORIDE LANTHANUM, AA STANDARD Lanthanum (III) chloride, anhydrous LANTHANUM CHLORIDE, ANHYDROUS, BEADS, -10 MESH, 98% Lanthanum chloride (LaCl3) lanthanumchloride(lacl3) lanthanumchloride,anhydrous LanthanuM(III) chloride, lithiuM chloride coMplex 0.6M (15wt% 2wt%) in tetrahydrofuran LanthanuM(III) chloride anhydrous, beads, -10 Mesh, >=99.99% trace Metals basis Lanthanum(III) chloride, anhydrous, ampuled under argon, 99.9% trace rare earth metals basis Lanthanum(III) chloride anhydrous, beads, -10 mesh, 99.9% trace metals basis LANTHANIUMCHLORIDE LANTHANUM(III) CHLORIDE, ANHYDROUS, BEADS, -10 MESH, 99.99+ % METALS BASIS LANTHANUM CHLORIDE, 99.9% Lanthanumtrichloride ultradry Lanthanum chloride, 99.90% LANTHANUM CHLORIDE, ANHYDROUS 99.9% Lanthanum(III)chloride,anhydrous(99.9%-La)(REO) lanthanum(iii) chloride, ultra dry Lanthanum(III) chloride, ultra dry, 99.99% (metals basis) Lanthanum(III) chloride, anhydrous, 99.9% (REO) Lanthanum(III) chloride, ultra dry, 99.99% (REO) Lanthanum(III) chloride, ultra dry, 99.9% (REO) Lanthanum chloride, Releasing Agent Solution, Specpure(R) Lanthanum (III) chloride, ultra dry, 99.99% (REO), 2-8mm lump Lanthanum(III) chloride, ultra dry (REO) LanthanuM chloride, 99.9% 10GR LanthanuM(III) chloride, anhydrous, LaCl3 LANTHANUM CHLORIDE 7HYD Anhydrous Lanthanum Chloride anthanum(III) chL Lanthanum(III) chloride,99.99% Lanthanum(III) , anhydrous Lanthanum(III) chloride, anhydrous, beads, -10 mesh, ≥99.9% Lanthanum chloride, Releasing Agent Solution, Specpure&trade LANTHANUM CHLORIDE LANTHANUM (III) CHLORIDE LaCl3 Lanthanum chloride anhydrous Lanthanum chloride (LaCl3) (8CI, 9CI, ACI) Lanthanum(lll) chloride 10099-58-8 1LaasLa2O3in2HCl H14ClLaO7 Catalysis and Inorganic Chemistry Lanthanum Rare-Earth Metals metal halide Catalysis and Inorganic Chemistry Chemical Synthesis Crystal Grade Inorganics Lanthanum Salts LanthanumMetal and Ceramic Science Salts Inorganics Other Metal