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4-Bromo-2,6-di-tert-butylphenol

4-Bromo-2,6-di-tert-butylphenol Structure
CAS No.
1139-52-2
Chemical Name:
4-Bromo-2,6-di-tert-butylphenol
Synonyms
4-BROMO-2,6-DI-TERT-PHENOL;4-BROMO-2,6-DI-T-BUTYLPHENOL;4-BROMO-2,6-DI-TERT-BUTYLPHENOL;2,6-DI-TERT-BUTYL-4-BROMOPHENOL;2,6-Bis(tert-butyl)-4-bromophenol;4-Bromo-2,6-di-tert-butylphenol 98%;4-Bromo-2,6-di-tert-butylphenol,98%;4-Bromo-2,6-di-tert-butylphenol >4-Bromo-2,6-di-tert-butylphenol;4-Bromo-2,6-bis(1,1-dimethylethyl)phenol
CBNumber:
CB3734405
Molecular Formula:
C14H21BrO
Molecular Weight:
285.22
MOL File:
1139-52-2.mol
MSDS File:
SDS
Modify Date:
2023/4/23 13:52:06

4-Bromo-2,6-di-tert-butylphenol Properties

Melting point 78-83 °C (dec.)(lit.)
Boiling point 128 °C / 4mmHg
Density 1.2457 (rough estimate)
refractive index 1.5130 (estimate)
storage temp. Inert atmosphere,Room Temperature
solubility soluble in Methanol
form powder to crystal
pka 11.23±0.40(Predicted)
color White to Orange to Green
BRN 2051052
CAS DataBase Reference 1139-52-2(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36-37/39
WGK Germany  3
Hazard Note  Irritant
HS Code  29081990

4-Bromo-2,6-di-tert-butylphenol price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 394378 4-Bromo-2,6-di-tert-butylphenol 98% 1139-52-2 25G ₹2620 2022-06-14 Buy
Sigma-Aldrich(India) 394378 4-Bromo-2,6-di-tert-butylphenol 98% 1139-52-2 100G ₹7290 2022-06-14 Buy
TCI Chemicals (India) B1758 4-Bromo-2,6-di-tert-butylphenol min. 98.0 % 1139-52-2 25G ₹12700 2022-05-26 Buy
ALFA India ALF-A13876-14 4-Bromo-2,6-di-tert-butylphenol, 98% 1139-52-2 25g ₹2312 2022-05-26 Buy
Product number Packaging Price Buy
394378 25G ₹2620 Buy
394378 100G ₹7290 Buy
B1758 25G ₹12700 Buy
ALF-A13876-14 25g ₹2312 Buy

4-Bromo-2,6-di-tert-butylphenol Chemical Properties,Uses,Production

Chemical Properties

yellow to brown crystals

Uses

4-Bromo-2,6-di-tert-butylphenol may be used in the following studies:

  • As a terminating comonomer phenol in the phase transfer catalyzed (PTC) polymerization of 4-bromo-2,6-dimethylphenol.
  • Synthesis of 1,1-[1,10-decanediylbis(oxy)]bis[(2,6-ditertbutyl-4-bromo)benzene], a monomer, which forms poly(p-phenylenevinylene) derivatives by reaction with 1,10-dibromodecane.
  • As a reactant in the synthesis of 2,6-di-tert-butyl-phenolnorbornene (NArOH), a norbornene comonomer bearing an antioxidant hindered phenol.
  • As a catalyst with methyl aluminium to form methylaluminum bis(4-bromo-2,6-di-tert-butylphenoxide) (MABR) which may be utilized for the transformation of various epoxides to carbonyl compounds.

General Description

4-Bromo-2,6-di-tert-butylphenol is a 4-substituted-2,6-di-tert-butylphenol. It is synthesized by the bromination of 2,6-di-tert-butylphenol. The structure was confirmed by 1H NMR. Its photolysis reaction in benzene solution has been investigated. The photochemical reaction of 4-bromo-2,6-di-tert-butylphenol single crystals doped with 2,6-di-tert-butyl-p-quinone has been studied by EPR spectroscopy.

4-Bromo-2,6-di-tert-butylphenol Preparation Products And Raw materials

Global( 138)Suppliers
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2,6-DI-TERT-BUTYL-4-BROMOPHENOL 4-BROMO-2,6-DI-T-BUTYLPHENOL 4-BROMO-2,6-DI-TERT-BUTYLPHENOL 4-BROMO-2,6-DI-TERT-PHENOL Phenol, 4-bromo-2,6-bis(1,1-dimethylethyl)- 4-Bromo-2,6-bis(1,1-dimethylethyl)phenol 4-Bromo-2,6-di-tert-butylphenol,98% 4-Bromo-2,6-di-tert-butylphenol 98% 4-Bromo-2,6-di-tert-butylphenol 2,6-Bis(tert-butyl)-4-bromophenol 4-Bromo-2,6-di-tert-butylphenol > 1139-52-2 BrC6H2CCH332OH C14H21BrO C14H21OBr Building Blocks Oxygen Compounds Phenols Organic Building Blocks Organic Building Blocks Oxygen Compounds Phenols Aromatic Phenols API intermediates