ChemicalBook > Product Catalog >Organic Chemistry >Amides >2,2-Bis[4-(4-aminophenoxy)phenyl]propane

2,2-Bis[4-(4-aminophenoxy)phenyl]propane

CAS No.: 13080-86-9

Chemical Name:: 2,2-Bis[4-(4-aminophenoxy)phenyl]propane

Synonyms: BAPP;2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]PROPANE;4-BAPOPP;4,4'-(4,4'-Isopropyl;2,2’-bis(4-aminophenoxyphenyl)propane;2,2'-Bis(4-aminophenoxyphenyl) propane;2,2-Bis[4-(4-aminophenoxy)phenyl]propan;2,2-Bis[p-(4-aMinophenoxy)phenyl]propane;2,2'-Bis[4-(4-aminophenoxy)pheny]propane;2,2-Bis[p-(p-aminophenoxy)phenyl]propane

CBNumber:: CB3780578

Molecular Formula:: C27H26N2O2

Molecular Weight:: 410.51

MOL File:: 13080-86-9.mol

MSDS File:: SDS

Modify Date:: 2024/5/22 10:01:29

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2,2-Bis[4-(4-aminophenoxy)phenyl]propane Properties

Melting point	127-130 °C(lit.)
Boiling point	587.1±50.0 °C(Predicted)
Density	1.178±0.06 g/cm3(Predicted)
vapor pressure	0-0Pa at 20-25℃
storage temp.	Keep in dark place,Inert atmosphere,Room temperature
pka	5.16±0.10(Predicted)
form	Solid:particulate/powder
Water Solubility	Very slightly soluble in water. Soluble in acetone, Dimethyl sulfoxide(DMSO).
InChI	InChI=1S/C27H26N2O2/c1-27(2,19-3-11-23(12-4-19)30-25-15-7-21(28)8-16-25)20-5-13-24(14-6-20)31-26-17-9-22(29)10-18-26/h3-18H,28-29H2,1-2H3
InChIKey	KMKWGXGSGPYISJ-UHFFFAOYSA-N
SMILES	C(C1=CC=C(OC2=CC=C(N)C=C2)C=C1)(C1=CC=C(OC2=CC=C(N)C=C2)C=C1)(C)C
LogP	4.3-4.9 at 35℃ and pH7
CAS DataBase Reference	13080-86-9(CAS DataBase Reference)
EPA Substance Registry System	Benzenamine, 4,4'-[(1-methylethylidene)bis(4,1-phenyleneoxy)]bis- (13080-86-9)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H302-H315-H319-H335

Precautionary statements

P261-P264-P270-P301+P312-P302+P352-P305+P351+P338

Hazard Codes

Xn,Xi

Risk Statements

22-36/37/38

Safety Statements

26-36

WGK Germany

RTECS

CY1062500

TSCA

Yes

HS Code

29222990

NFPA 704

	1
2		0

2,2-Bis[4-(4-aminophenoxy)phenyl]propane price More Price(5)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich(India)	476331	4,4′-(4,4′-Isopropylidenediphenyl-1,1′-diyldioxy)dianiline 98%	13080-86-9	50G	₹6256.85	2022-06-14	Buy
TCI Chemicals (India)	B1551	2,2-Bis[4-(4-aminophenoxy)phenyl]propane	13080-86-9	25G	₹2500	2022-05-26	Buy
ALFA India	ALF-H55057-22	2,2-Bis[4-(4-aminophenoxy)phenyl]propane, 98%	13080-86-9	100g	₹10518	2022-05-26	Buy
TCI Chemicals (India)	B1551	2,2-Bis[4-(4-aminophenoxy)phenyl]propane	13080-86-9	250G	₹13600	2022-05-26	Buy
ALFA India	ALF-H55057-14	2,2-Bis[4-(4-aminophenoxy)phenyl]propane, 98%	13080-86-9	25g	₹2637	2022-05-26	Buy

Product number	Packaging	Price	Buy
476331	50G	₹6256.85	Buy
B1551	25G	₹2500	Buy
ALF-H55057-22	100g	₹10518	Buy
B1551	250G	₹13600	Buy
ALF-H55057-14	25g	₹2637	Buy

2,2-Bis[4-(4-aminophenoxy)phenyl]propane Chemical Properties,Uses,Production

Description

2,2-Bis[4-(4-aminophenoxy)phenyl]propane (BAPP), also known as 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline, is a diamino monomer with a diphenoxy-phenyl core. Since the molecule has two amine groups at both ends, it can be cross-linked with carboxylic acids or carboxylic dianhydrides to synthesize polyimides. It is commonly as a monomer for the preparation of polyimides in application of batteries, fuel cells, low dielectric materials and OLEDs.

Chemical Properties

4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline (2,2-Bis[4-(4-aminophenoxy)phenyl]propane) is white solid

Uses

4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline is used for preparation polyimide and epoxy resin material.

Application

2,2-Bis[4-(4-aminophenoxy)phenyl] propane (BAPP) can be used for:
(1) Preparation of polyimides. The glass transition temperature of this new polyimide is about 225-230°C. It has the typical yield of thermoplastic polymers. It has a typical thermoplastic polymer yield behaviour, which is very different from other polyimides. The elongation at break was 6% and 29% for polyamide and polyimide, respectively.
(2) Curing epoxy resin (ER) and poly(?-caprolactone) (PCL) for the preparation of crystalline thermoset blends.
(3) Constructing dental resin composites.

Synthesis

2,2‐Bis[4‐(4‐aminophenoxy)phenyl] propane (BAPP), as a monomer to prepare polyimide, was synthesized from Bisphenol A and p‐chloronitrobenzene via the nucleophilic substitution reaction^[1].

References

[1] CUILI KONG. Synthesis, Structures and Properties of Polyimide Based on 2,2′‐Bis(4‐aminophenoxy phenyl) Propane[J]. Journal of Macromolecular Science, Part A, 2006. DOI:10.1080/10601320600941086.

2,2-Bis[4-(4-aminophenoxy)phenyl]propane Preparation Products And Raw materials

Raw materials

1,1'-Isopropylidenebis(p-phenyleneoxy)bis(4-nitrobenzene)

Preparation Products

2,2-Bis[4-(4-aminophenoxy)phenyl]propane Suppliers

Global( 297)Suppliers

Supplier	Tel	Country	ProdList	Advantage	Inquiry
A.J Chemicals	91-9810153283	New Delhi, India	6124	58	Inquiry
TCI Chemicals (India) Pvt. Ltd.	1800 425 7889	New Delhi, India	6778	58	Inquiry
Alfa Aesar	1 800 209 7001	Maharashtra, India	6913	58	Inquiry
Shanghai Daeyeon Chemicals Co., Ltd	021-64478606 +8615900664856	China	2062	58	Inquiry
CHINATECH(TIANJIN) CHEMICAL CO.,LTD.	+86-18222270857 +86-18222265956	China	64	58	Inquiry
Heynova (Shanghai) New Material Technology CO., Ltd	+86-17821320848; +8617821320848	China	433	58	Inquiry
Hebei Mojin Biotechnology Co., Ltd	+8613288715578	China	12455	58	Inquiry
Henan Bao Enluo International TradeCo.，LTD	+86-17331933971 +86-17331933971	China	2503	58	Inquiry
Hangzhou ICH Biofarm Co., Ltd	+86-0571-28186870; +undefined8613073685410	China	985	58	Inquiry
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	China	20296	58	Inquiry

Supplier	Advantage
A.J Chemicals	58
TCI Chemicals (India) Pvt. Ltd.	58
Alfa Aesar	58
Shanghai Daeyeon Chemicals Co., Ltd	58
CHINATECH(TIANJIN) CHEMICAL CO.,LTD.	58
Heynova (Shanghai) New Material Technology CO., Ltd	58
Hebei Mojin Biotechnology Co., Ltd	58
Henan Bao Enluo International TradeCo.，LTD	58
Hangzhou ICH Biofarm Co., Ltd	58
Henan Fengda Chemical Co., Ltd	58

Synthesis and Application of 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline
4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline can be used in new polyester materials.
Sep 13，2022

2,2-Bis[4-(4-aminophenoxy)phenyl]propane Spectrum

4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline(13080-86-9)MS 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline(13080-86-9)¹HNMR 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline(13080-86-9)¹³CNMR 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline(13080-86-9)IR1 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline(13080-86-9)IR2

13080-86-9(2,2-Bis[4-(4-aminophenoxy)phenyl]propane)Related Search:

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4,4'-((Propane-2,2-diylbis(4,1-phenylene))bis(oxy))dianiline 2,2'-Di-[4-(4-aminophenyloxy)phenyl]-propane 4,4'-(4,4'-Isopropyl 2,2-Bis[4-(4-aminophenoxy)phenyl]propan 2,2-Bis[p-(4-aMinophenoxy)phenyl]propane 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline 98% 4,4'-(4,4'-isopropylidenediphenyl-1,1'-diyldioxy),BAPP 4,4’-((1-methylethylidene)bis(4,1-phenyleneoxy)bis-benzenamin 4,4’-((1-methylethylidene)bis(4,1-phenyleneoxy)bisbenzenamine) 4,4’-(4,4’-isopropylidenediphenyl-1,1’-diyldioxy) 2,2'-Bis(4-aminophenoxyphenyl)propane(BAPP) 2,2'-BIS[4-(4-AMINOPHENOXY)PHENYL]PROPANE 4,4'-ISOPROPYLIDENEBIS[(4-AMINOPHENOXY)BENZENE] 4,4'-[ISOPROPYLIDENEBIS(P-PHENYLENEOXY)]DIANILINE 4,4'-(4,4'-ISOPROPYLIDENEDIPHENYL-1,1'-DIYLDIOXY)DIANILINE 2,2’-bis(4-aminophenoxyphenyl)propane 2,2'-Bis(4-[4-amonophenoxy]phenyl)propane 2,2’-Bis[4-(4-aminophenoxy)Phenyl]Propane(BAPP) Benzenamine, 4,4'-[(1-methylethylidene) bis(4,1-phenyleneoxy)]bis- 2,2''-BIS[4-(4-AMINOPHENOXY)PHENYL]PROPANE 99.0% 2,2'-Bis[4-(4-aminophenoxy)pheny]propane 4-BAPOPP 2,2-Bis[p-(p-aminophenoxy)phenyl]propane 4,4'-[2,2-Propanediylbis(4,1-phenyleneoxy)]bisaniline 4,4'-[Isopropylidenebis(1,4-phenyleneoxy)]bisaniline 4,4'-[Isopropylidenebis(p-phenyleneoxy)]bis(benzenamine) 4,4'-[Propane-2,2-diylbis(p-phenyleneoxy)]bisaniline 4,4′-(4,4′-Isopropylidenediphenyl-1,1′-diyldioxy)dianiline,2,2-Bis[4-(4-aminophenoxy)phenyl]propane 4,4’-[(1-methylethylidene)bis(4,1-phenyleneoxy)]bis-benzenamin 4,4’-[(1-methylethylidene)bis(4,1-phenyleneoxy)]bis-Benzenamine 4,4’-isopropylidenebis(4,1-phenyleneoxy)dianiline Bisphenol A Bis(4-aminophenyl) Ether (BAPP) 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline (BAPP) 2,2-Bis[4-(4-aminophenoxy)phenyl]propane > BAPP 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]PROPANE BAPP2.2 bis (4- (4-aminophenoxy) phenyl) propane 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldi 2,2'-Bis(4-aminophenoxyphenyl) propane (BAPP) 4,4'-((Propane-2,2-diylbis(4,1-phenylene))bis(oxy))dianiline 2,2'-Bis(4-aminophenoxyphenyl) propane 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline (BAPP) 2,2'-Bis[4-(4- aMinophenoxy)phenyl]propane(BAPP) 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldi 13080-86-9 CH32CC6H4OC6H4NH22 Reagent for High-Performance Polymer Research Bisphenol A type Compounds (for High-Performance Polymer Research) fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, functional materials API fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis Organics Miscellaneous Bisphenol A type Compounds (for High-Performance Polymer Research) Functional Materials Reagent for High-Performance Polymer Research 13080-86-9