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liriodenine

liriodenine Structure
CAS No.
475-75-2
Chemical Name:
liriodenine
Synonyms
Nsc93681;Iiriodenine;Micheline b;liriodenine;Oxoushinsunin;Spermatheridin;Oxoushinsunine;Spermatheridine;Liriodenine (6CI);8H-Benzo[G]-1,3-benzodioxolo[6,5,4-de]quinolin-8-one
CBNumber:
CB41399691
Molecular Formula:
C17H9NO3
Molecular Weight:
275.26
MOL File:
475-75-2.mol
MSDS File:
SDS
Modify Date:
2023/7/14 17:38:45

liriodenine Properties

Melting point 282°C
Boiling point 531.0±19.0 °C(Predicted)
Density 1.501±0.06 g/cm3(Predicted)
solubility Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
form powder
pka 2.67±0.20(Predicted)
color Yellow

SAFETY

Risk and Safety Statements

liriodenine Chemical Properties,Uses,Production

Description

Isolated from the heartwood extract of Liriodendron tulip/era, this base may be purified by crystallization from CHCI3. It contains one methylenedioxy group and a keto group, forming a crystalline oxime, m.p. 271°C. The structure has been confirmed by synthesis, the synthetic alkaloid having a higher melting point of 287°C.

Uses

Liriodenine is an isoquinoline alkaloid found in extracts of medicinal Asian vegetation such as Michelia alba and Liriodendron chinense.

Definition

ChEBI: An oxoaporphine alkaloid that is 4,5,6,6a-tetradehydronoraporphin-7-one substituted by a methylenedioxy group across positions 1 and 2. It is isolated from Annona glabra and has been shown to exhibit antimicrobial and cytotoxic activities.

References

Buchanan, Dickey.,J. Org. Chern., 25, 1389 (1960)
Taylor., Tetrahedron, 14,42 (1961)

liriodenine Preparation Products And Raw materials

Raw materials

Preparation Products

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liriodenine 8H-Benzo[G]-1,3-benzodioxolo[6,5,4-de]quinolin-8-one Micheline b Noraporphin-7-one, 4,5,6,6A-tetradehydro-1,2-(methylenedioxy)- Nsc93681 Oxoushinsunin Oxoushinsunine Spermatheridin Spermatheridine Iiriodenine Liriodenine (6CI) 475-75-2