ChemicalBook > Product Catalog >Organic Chemistry >Organometallic compounds >Organic palladium >Allylpalladium(II) Chloride Dimer
Allylpalladium(II) Chloride Dimer
- CAS No.
- 12012-95-2
- Chemical Name:
- Allylpalladium(II) Chloride Dimer
- Synonyms
- ALLYLPALLADIUM CHLORIDE DIMER;[PdCl(C3H5)]2;[PdCl(allyl)]2;Allylpalladium(II) chloride;allylpaladium;Bis(allyl)dichlorodipalladium;oride dimer;Bis(pi-allylpallad;allyl-chloro-palladium;Allylpalladium chloride
- CBNumber:
- CB4156701
- Molecular Formula:
- C6H10Cl2Pd2
- Molecular Weight:
- 365.89
- MOL File:
- 12012-95-2.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/4/23 13:52:06
| Melting point | 120°C (dec.) |
|---|---|
| storage temp. | 2-8°C |
| form | Crystals or Crystalline Powder |
| color | Yellow to green-yellow |
| Water Solubility | decomposes |
| Sensitive | Air Sensitive |
| BRN | 4124623 |
| NIST Chemistry Reference | [Pd(Cl)(C3H5)]2(12012-95-2) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315 | |||||||||
| Precautionary statements | P264-P280-P302+P352-P332+P313-P362+P364 | |||||||||
| Hazard Codes | Xi,Xn | |||||||||
| Risk Statements | 36/37/38-40 | |||||||||
| Safety Statements | 26-36-36/37 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | RT3510000 | |||||||||
| F | 1-10 | |||||||||
| TSCA | No | |||||||||
| HS Code | 28439090 | |||||||||
| NFPA 704 |
|
Allylpalladium(II) Chloride Dimer price More Price(8)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 683396 | [Pd(allyl)Cl]2 Umicore | 12012-95-2 | 500MG | ₹6404.7 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 705020 | Allylpalladium chloride dimer ChemDose™ tablet | 12012-95-2 | 10TABLETS | ₹7036.25 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 683396 | [Pd(allyl)Cl]2 Umicore | 12012-95-2 | 5G | ₹30203.1 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 222380 | Allylpalladium(II) chloride dimer 98% | 12012-95-2 | 500MG | ₹4473.3 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 222380 | Allylpalladium(II) chloride dimer 98% | 12012-95-2 | 1G | ₹8469.3 | 2022-06-14 | Buy |
Allylpalladium(II) Chloride Dimer Chemical Properties,Uses,Production
Chemical Properties
Allylpalladium(II) chloride dimer is a yellow powder with the formula [(η3-C3H5)PdCl]2. This compound is an important catalyst used in organic synthesis. It is one of the most widely used transition metal allyl complexes.
Uses
Allylpalladium(II) chloride dimer is used as an important catalyst in Heck reaction. It reacts with cyclopentadienyl anion to give cyclopentadienyl allyl palladium. It acts as a precatalyst for asymmetric and cross-coupling catalysis. Further, it is used in the preparation of 1,4-diallyl-1,2-dihydroisoquinolines. It is also employed as a catalyst for greener Buchwald-Hartwig coupling reaction and involved in the synthesis of cationic palladium catalysts. In addition, it takes part in preparation of -heterocyclic carbene-palladium-eta3-allyl chloride complex, which is an efficient catalyst for the Suzuki-Miyaura cross-coupling reactions in synthetic chemistry.
General Description
Allylpalladium(II) chloride dimer is employed as catalyst in Heck reaction. It also participates as catalyst in the tandem nucleophilic allylation-alkoxyallylation reaction of the alkynylaldehydes with allyl chloride and allyltributylstannane.
Purification Methods
It crystallises from benzene and is soluble in MeOH, Et2O and CHCl3. [Hüttel et al. Chem Ber 94 766 1961, Dent et al. J Chem Soc 1585 1964, Armstrong J Org Chem 31 618 1966.]
Allylpalladium(II) Chloride Dimer Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 303)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| Omkar Lab | +91-9130062553 +91-9326135973 | Maharashtra, India | 47 | 58 | Inquiry |
| Johnson Matthey Chemicals India Pvt Ltd | +91-9820622275 +91-9711869003 | Maharashtra, India | 69 | 58 | Inquiry |
| CHEMSWORTH | +91-261-2397244 | New Delhi, India | 6707 | 30 | Inquiry |
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
| CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6351 | 58 | Inquiry |
| Johnson Matthey Chemicals India Pvt., Ltd. | 91-22-27415601 Ext 675 | Maharashtra, India | 47 | 58 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
| Souvenier Chemicals | 08048372762Ext 645 | Mumbai, India | 396 | 58 | Inquiry |
| Reax Chemicals | 08048372701Ext 416 | Hyderabad, India | 4223 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| Omkar Lab | 58 |
| Johnson Matthey Chemicals India Pvt Ltd | 58 |
| CHEMSWORTH | 30 |
| A.J Chemicals | 58 |
| CLEARSYNTH LABS LTD. | 58 |
| Johnson Matthey Chemicals India Pvt., Ltd. | 58 |
| TCI Chemicals (India) Pvt. Ltd. | 58 |
| Alfa Aesar | 58 |
| Souvenier Chemicals | 58 |
| Reax Chemicals | 58 |
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DI-MU-CHLOROBIS[(ETA-ALLYL)PALLADIUM(II)]
ALLYLPALLADIUM(II) CHLORIDE DIMER
allylpaladiumchloridedimer
Bis(pi-allyl)dichlorodipalladium
Bis(pi-allylpalladium chloride)
Diallyldichlorodipalladium
Di-mu-chlorodi-pi-allyldipalladium
Di-pi-allyldi-mu-chlorodipalladium
Bis(allylchloropalladium)
Palladium, di-m-chlorobis(h3-2-propenyl)di-
(pi-allyl)palladium(II)chloridedimer Can be used to form catalysts in situ by separate addition of ligand. 120 dec.
Allylpalladium chloride dimer,98%
di-μ-chloro-bis(η-allyl)palladium
Allylpalladium chloride dimer, min. 98%
AllylpalladiuM chloride diMer, 98% 500MG
AllylpalladiuM(II) chloride diMer, Pd 56.0% Min
AllylpalladiuM(II) chloride diMer 98%
Allylpalladium(Ⅱ) chloride dimer
Allylchloropalladium dimer
Bis(allyl)dichloropalladium
Allylpalladium chloride dimer ChemDose? tablet
Allylpalladium chloride dimer ChemDose(TM) tablet
Allylpalladium chloride dimer ChemDose(R) tablet
Bis(allyl)dichlorodipalladium(II)
Di-ì-chlorobis[(?-allyl)palladium(II)]
Allylpalladium(II) chloride dimer (58% Pd) for synthesis
Palladium allyl chloride dimer
Palladium chloride, allyl- (dimer)
Palladium, di-mu-chlorobis(eta3-2-propenyl)di-
Palladium, di-pi-allyldi-mu-chlorodi-
Palladiumchloride,allyl-(dimer)
pi-Allylpalladium chloride
pi-Allylpalladium chloride dimer
di-mu-chloro-bis(eta-allyl)palladium
Allylpalladium(II) chloride dimer,98%
Allylpalladiumchloridedimer,99%
Allylpalladium(II) chloride dimer, Pd 56.5% min
CHLOROALLYLPALLADIUM(II) - DIMER
Diallyldipalladiumdichloride
Bis(pi-allylpallad
Allylpalladium Chloride Dimer ([PdCl(allyl)]2)
bis(chloro(prop-2-en-1-yl)palladium)
oride dimer
Allylpalladium(II) Chloride Dimer >
Di-μ-chlorobis[(η-allyl)palladium(Ⅱ)]
Allylpalladium(II) chloride dimer，Pd 58.2%
Allylpalladium chloride dimer ISO 9001：2015 REACH
allyl-chloro-palladium
TIANFU-CHEM --Allylpalladium chloride dimer
ALLYLPALLADIUM CHLORIDE DIMER
allylpaladium
Bis(allyl)dichlorodipalladium
[PdCl(allyl)]2
[PdCl(C3H5)]2
Allylpalladium(II) chloride
Bis(η 3 -allyl)di( μ -chloro)dipalladium(II)
Allylpalladium(II)chloride dimmer
Di-μ-chlorobis(η3-2-propenyl)dipalladium