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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organic palladium >Allylpalladium(II) Chloride Dimer

Allylpalladium(II) Chloride Dimer

Allylpalladium(II) Chloride Dimer Structure
  • ₹4473.3 - ₹36907.5
  • Product name: Allylpalladium(II) Chloride Dimer
  • CAS: 12012-95-2
  • MF: C6H10Cl2Pd2
  • MW: 365.89
  • EINECS:234-579-8
  • MDL Number:MFCD00044874
  • Synonyms:DI-MU-CHLOROBIS[(ETA-ALLYL)PALLADIUM(II)];ALLYLPALLADIUM(II) CHLORIDE DIMER;allylpaladiumchloridedimer ;Bis(pi-allyl)dichlorodipalladium;Bis(pi-allylpalladium chloride);Diallyldichlorodipalladium;Di-mu-chlorodi-pi-allyldipalladium;Di-pi-allyldi-mu-chlorodipalladium
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Brand

  • Sigma-Aldrich(India)
  • TCI Chemicals (India)

Package

  • 500MG
  • 1G
  • 5G
  • 10TABLETS
  • ManufacturerSigma-Aldrich(India)
  • Product number222380
  • Product descriptionAllylpalladium(II) chloride dimer 98%
  • Packaging5G
  • Price₹36907.5
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number683396
  • Product description[Pd(allyl)Cl]2 Umicore
  • Packaging5G
  • Price₹30203.1
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number222380
  • Product descriptionAllylpalladium(II) chloride dimer 98%
  • Packaging1G
  • Price₹8469.3
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number705020
  • Product descriptionAllylpalladium chloride dimer ChemDose™ tablet
  • Packaging10TABLETS
  • Price₹7036.25
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number683396
  • Product description[Pd(allyl)Cl]2 Umicore
  • Packaging500MG
  • Price₹6404.7
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number222380
  • Product descriptionAllylpalladium(II) chloride dimer 98%
  • Packaging500MG
  • Price₹4473.3
  • Updated2022-06-14
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberA1479
  • Product descriptionAllylpalladium(II) Chloride Dimer
  • Packaging1G
  • Price₹26000
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberA1479
  • Product descriptionAllylpalladium(II) Chloride Dimer
  • Packaging500MG
  • Price₹14700
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 222380 Allylpalladium(II) chloride dimer 98% 5G ₹36907.5 2022-06-14 Buy
Sigma-Aldrich(India) 683396 [Pd(allyl)Cl]2 Umicore 5G ₹30203.1 2022-06-14 Buy
Sigma-Aldrich(India) 222380 Allylpalladium(II) chloride dimer 98% 1G ₹8469.3 2022-06-14 Buy
Sigma-Aldrich(India) 705020 Allylpalladium chloride dimer ChemDose™ tablet 10TABLETS ₹7036.25 2022-06-14 Buy
Sigma-Aldrich(India) 683396 [Pd(allyl)Cl]2 Umicore 500MG ₹6404.7 2022-06-14 Buy
Sigma-Aldrich(India) 222380 Allylpalladium(II) chloride dimer 98% 500MG ₹4473.3 2022-06-14 Buy
TCI Chemicals (India) A1479 Allylpalladium(II) Chloride Dimer 1G ₹26000 2022-05-26 Buy
TCI Chemicals (India) A1479 Allylpalladium(II) Chloride Dimer 500MG ₹14700 2022-05-26 Buy

Properties

Melting point :120°C (dec.)
storage temp. :2-8°C
form :Crystals or Crystalline Powder
color :Yellow to green-yellow
Water Solubility :decomposes
Sensitive :Air Sensitive
BRN :4124623
NIST Chemistry Reference :[Pd(Cl)(C3H5)]2(12012-95-2)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
Precautionary statements:
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P332+P313 IF SKIN irritation occurs: Get medical advice/attention.

Description

Allylpalladium(II) chloride dimer is used as an important catalyst in Heck reaction. It reacts with cyclopentadienyl anion to give cyclopentadienyl allyl palladium. It acts as a precatalyst for asymmetric and cross-coupling catalysis. Further, it is used in the preparation of 1,4-diallyl-1,2-dihydroisoquinolines. It is also employed as a catalyst for greener Buchwald-Hartwig coupling reaction and involved in the synthesis of cationic palladium catalysts. In addition, it takes part in preparation of -heterocyclic carbene-palladium-eta-allyl chloride complex, which is an efficient catalyst for the Suzuki-Miyaura cross-coupling reactions in synthetic chemistry.

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