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CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)

CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Structure
  • ₹12465.3 - ₹39316.2
  • Product name: CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)
  • CAS: 92390-26-6
  • MF: C18H27ClRu5*
  • MW: 379.93
  • EINECS:
  • MDL Number:MFCD07369035
  • Synonyms:Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium(II),98%;Ruthenium,chloro[(1,2,5,6-h)-1,5-cyclooctadiene][(1,2,3,4,5-h)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]-;1,5-Cyclooctadiene, ruthenium complex;Chloro(1,5-cyclooctadiene)(η5-pentamethylcyclopentadienyl)ruthenium;Chloro(1，5-cyclooctadiene)(pentamethylcyclopent...;Chloro(pentaMethylcyclopentadienyl)(cyclooctadiene)rutheniuM;CHLORO(PENTAMETHYLCYCLOPENTADIENYL)(CYC&;CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)
Price2 Properties Safety Information Description
2 prices
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Brand

  • Sigma-Aldrich(India)

Package

  • 250MG
  • 1G
  • ManufacturerSigma-Aldrich(India)
  • Product number667234
  • Product descriptionChloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II)
  • Packaging250MG
  • Price₹12465.3
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number667234
  • Product descriptionChloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II)
  • Packaging1G
  • Price₹39316.2
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 667234 Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II) 250MG ₹12465.3 2022-06-14 Buy
Sigma-Aldrich(India) 667234 Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II) 1G ₹39316.2 2022-06-14 Buy

Properties

Melting point :143-147℃
storage temp. :-20°C
color :brown microxtls
Stability :store cold
InChIKey :JBVMVFXUVNUNNG-ONEVTFJLSA-M

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H261 In contact with water releases flammable gas Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 2
Category 3		 Danger
Warning		 GHS hazard pictograms P231+P232, P280, P370+P378,P402+P404, P501
Precautionary statements:
P231+P232 Handle under inert gas. Protect from moisture.
P422 Store contents under …

Description

Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II) is a homogeneous catalyst for the formation of carbon-carbon and carbon-heteroatom bonds.
It can be used:
  • To catalyze cyclotrimerization of alkynylboronates, propargyl alcohols, and terminal alkynes to form arylboronate, which in turn undergoes palladium(II)-catalyzed carbonylation to form highly substituted phthalides.
  • To catalyze C-C coupling of norbornenes and norbornadiene with alkynes?to form [2 + 2] cycloadducts.
  • In combination with 2-diphenylphosphinoethylamine-potassium tertiary butoxide to form a ternary catalyst system that can catalyze fast racemization of chiral non-racemic sec-alcohols.
  • To synthesize new organoruthenium complexes with phosphorus-based ligands such as bis(phosphino)amines.
  • To catalyze the addition of organic disulfides to alkenes leading to vic-dithioethers.

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Suppliers and manufacturers

career henan chemical co
CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)
₹1.00 /1KG
CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) CAS:92390-26-6
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