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N-METHYL-N,O-BIS(TRIMETHYLSILYL)HYDROXYLAMINE

N-METHYL-N,O-BIS(TRIMETHYLSILYL)HYDROXYLAMINE Structure
CAS No.
22737-33-3
Chemical Name:
N-METHYL-N,O-BIS(TRIMETHYLSILYL)HYDROXYLAMINE
Synonyms
Methylbistrimethylsilylhydroxylamine;N-METHYL-N,O-BIS(TRIMETHYLSILYL)HYDROXYLAMINE;N-trimethylsilyl-N-trimethylsilyloxymethanamine;Silanamine, N,1,1,1-tetramethyl-N-[(trimethylsilyl)oxy]-
CBNumber:
CB4256876
Molecular Formula:
C7H21NOSi2
Molecular Weight:
191.42
MOL File:
22737-33-3.mol
MSDS File:
SDS
Modify Date:
2023/6/8 17:06:37

N-METHYL-N,O-BIS(TRIMETHYLSILYL)HYDROXYLAMINE Properties

Boiling point 155.3±23.0 °C(Predicted)
Density 1.4146 g/cm3
storage temp. Refrigerator
solubility sol benzene, toluene, CH2Cl2, CHCl3.
form clear liquid
pka 5.95±0.70(Predicted)
color Colorless to Light yellow to Light orange

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05,GHS02
Signal word  Danger
Hazard statements  H314-H226
Precautionary statements  P501-P240-P210-P233-P243-P241-P242-P264-P280-P370+P378-P303+P361+P353-P301+P330+P331-P363-P304+P340+P310-P305+P351+P338+P310-P403+P235-P405
RIDADR  UN 2920 8/3/PG II
HS Code  2931.90.9010
HazardClass  8/3
PackingGroup  II
NFPA 704
2
1 0

N-METHYL-N,O-BIS(TRIMETHYLSILYL)HYDROXYLAMINE price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemicals (India) M1077 N-Methyl-N,O-bis(trimethylsilyl)hydroxylamine min. 97.0 % 22737-33-3 1ML ₹8900 2022-05-26 Buy
TCI Chemicals (India) M1077 N-Methyl-N,O-bis(trimethylsilyl)hydroxylamine min. 97.0 % 22737-33-3 5ML ₹40900 2022-05-26 Buy
Product number Packaging Price Buy
M1077 1ML ₹8900 Buy
M1077 5ML ₹40900 Buy

N-METHYL-N,O-BIS(TRIMETHYLSILYL)HYDROXYLAMINE Chemical Properties,Uses,Production

Physical properties

bp 40–41 °C/10 mmHg; n20 D 1.4146.2

Uses

As bis-trimethylsilylated N-methylhydroxylamine N-Methyl-N,O-bis(trimethylsilyl)- hydroxylamine can convert aldehydes and ketones to N-methyl nitrones with regio- and chemoselectivity; source of methylnitrene by pyrolysis; source of the trimethylsilyl(methyl)aminyl radical by photolysis.

Preparation

It is obtained in 52% yield by reaction of Nmethylhydroxylamine with chlorotrimethylsilane (2.0 equiv) and triethylamine (3.3 equiv) in ether at 25 °C.

N-METHYL-N,O-BIS(TRIMETHYLSILYL)HYDROXYLAMINE Preparation Products And Raw materials

Raw materials

Preparation Products

N-METHYL-N,O-BIS(TRIMETHYLSILYL)HYDROXYLAMINE Suppliers

Global( 31)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
Dayang Chem (Hangzhou) Co.,Ltd. 571-88938639 +8617705817739 China 52861 58 Inquiry
PT CHEM GROUP LIMITED +86-85511178 +86-85511178 China 35426 58 Inquiry
GIHI CHEMICALS CO.,LIMITED +8618058761490 China 49999 58 Inquiry
Aladdin Scientific +1-+1(833)-552-7181 United States 52927 58 Inquiry
ABCR GmbH & CO. KG 49 721 95061 0 Germany 6846 75 Inquiry
United States Biological 800.520.3011 or 781.639.5092 United States 6256 80 Inquiry
Shanghai Haohong Scientific Co., Ltd. 400-400-8210725 China 39953 58 Inquiry
Fluorochem Ltd. +44 1457 868921 United Kingdom 6406 74 Inquiry
VWR International 800 932 5000 United Kingdom 6554 82 Inquiry
N-METHYL-N,O-BIS(TRIMETHYLSILYL)HYDROXYLAMINE Methylbistrimethylsilylhydroxylamine Silanamine, N,1,1,1-tetramethyl-N-[(trimethylsilyl)oxy]- N-trimethylsilyl-N-trimethylsilyloxymethanamine 22737-33-3 C7H21NOSi2 Silicon Compounds (for Synthesis) Hydroxylamines Trimethylsilylazide, etc. Hydroxylamines (N-Substituted) Protection & Derivatization Reagents (for Synthesis) Hydroxylamines (O-Substituted) Si (Classes of Silicon Compounds) Si-N Compounds Hydroxylamines Hydroxylamines (N-Substituted) Hydroxylamines (O-Substituted) Protection & Derivatization Reagents (for Synthesis) Si (Classes of Silicon Compounds) Silicon Compounds (for Synthesis) Si-N Compounds Synthetic Organic Chemistry Trimethylsilylazide, etc.