ChemicalBook > Product Catalog >Organic Chemistry >Hydrocarbons and derivatives >Aromatic hydrocarbons >1,1,4,4-Tetramethyl-1,2,3,4-tetrahydronaphthalene

1,1,4,4-Tetramethyl-1,2,3,4-tetrahydronaphthalene

1,1,4,4-Tetramethyl-1,2,3,4-tetrahydronaphthalene Structure
CAS No.
6683-46-1
Chemical Name:
1,1,4,4-Tetramethyl-1,2,3,4-tetrahydronaphthalene
Synonyms
1,1,4,4-Tetramethyltetralin;1,1,4,4-TETRAMETHYL-1,2,3,4-TETRAHYDRONAPHTHALENE;NSC 17400;1,1,4,4-tetramethyl-2,3-dihydronaphthalene;1,2,3,4-TETRAHYDRO-1,1,4,4-TETRAMETHYLNAPHTHALENE;1,2,3,4-tetrahydro-1,1,4,4-tetramethyl-naphthalen;1,1,4,4-Tetramethyl-1,2,3,4-tetrahydro-naphthalen;naphthalene,1,2,3,4-tetrahydro-1,1,4,4-tetramethyl-;1,1,4,4-tetramethyl-1,2,3,4-tetrahydronaphthaline, tech;1,2,3,4-Tetrahydro-1,1,4,4-tetramethylnaphthalene, 97+%
CBNumber:
CB4396352
Molecular Formula:
C14H20
Molecular Weight:
188.31
MOL File:
6683-46-1.mol
MSDS File:
SDS
Modify Date:
2023/12/28 13:07:02

1,1,4,4-Tetramethyl-1,2,3,4-tetrahydronaphthalene Properties

Melting point 115-120℃
Boiling point 63 °C
Density 0.9482 g/cm3(Temp: 27 °C)
refractive index 1.5278 (589.3 nm 27℃)
storage temp. 2-8°C
form liquid
color Clear, pale yellow
InChI InChI=1S/C14H20/c1-13(2)9-10-14(3,4)12-8-6-5-7-11(12)13/h5-8H,9-10H2,1-4H3
InChIKey CCQKWSZYTOCEIB-UHFFFAOYSA-N
SMILES C1(C)(C)C2=C(C=CC=C2)C(C)(C)CC1
EPA Substance Registry System Naphthalene, 1,2,3,4-tetrahydro-1,1,4,4-tetramethyl- (6683-46-1)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P305+P351+P338
Hazard Codes  Xi
Risk Statements  20/21-36/37/38
Safety Statements  23-26-36/37/39
HS Code  2902900000
NFPA 704
1
2 0

1,1,4,4-Tetramethyl-1,2,3,4-tetrahydronaphthalene Chemical Properties,Uses,Production

Uses

1,1,4,4-Tetramethyl-1,2,3,4-tetrahydronaphthalene can be used as an intermediate to participate in a variety of chemical reactions and is used in the synthesis of a variety of compounds and drugs. For example, 6-lodo-1,1,4,4-tetramethyl-l,2,3,4-tetrahydronaphthalene, 6-bromo-1,1,4,4-tetramethyl-1,2,3,4-tetrahydronaphthalene and 1,1,4,4-tetramethyl-6-nitro-1,2,3,4- tetrahydronaphthalene and others.

Preparation

2,5-dichloro-2,5- dimethylhexane (300 mg, 1.64 mmol, 1 eq) was dissolved in dry benzene (25 mL). Then added AlCl(22.0 mg, 0.164 mmol, 0.1 eq) to the solution, which was stirred at reflux for 16 hours. The reaction was stopped with 3M HCl (5 mL) and extracted with hexanes (10 mL x 3). The combined organic layer was washed with brine, dried with Na2S04, filtered, and concentrated in vacuo. Finally, the crude was purified by flash chromatography (100% hexanes) to obtained the colourless oil (1,1,4,4-Tetramethyl-1,2,3,4-tetrahydronaphthalene).Yield=91%
1,2,3,4-TETRAHYDRO-1,1,4,4-TETRAMETHYLNAPHTHALENE

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1,2,3,4-TETRAHYDRO-1,1,4,4-TETRAMETHYLNAPHTHALENE NSC 17400 1,2,3,4-tetrahydro-1,1,4,4-tetramethyl-naphthalen naphthalene,1,2,3,4-tetrahydro-1,1,4,4-tetramethyl- 1,2,3,4-Tetrahydro-1,1,4,4-tetramethylnaphthalene, 97+% 1,1,4,4-tetramethyl-1,2,3,4-tetrahydronaphthaline, tech 1,2,3,4-TETRAHYDRO-1,1,4,4-TETRAMETHYLNAPHTHALENE, TECH. 1,1,4,4-Tetramethyl-1,2,3,4-tetrahydronaphthalene, Tech. TIANFU-CHEM 1,2,3,4-TETRAHYDRO-1,1,4,4-TETRAMETHYLNAPHTHALENE 6683-46-1 1,1,4,4-tetramethyl-2,3-dihydronaphthalene 1,1,4,4-Tetramethyltetralin 1,1,4,4-TETRAMETHYL-1,2,3,4-TETRAHYDRONAPHTHALENE 1,1,4,4-Tetramethyl-1,2,3,4-tetrahydro-naphthalen 6683-46-1