ChemicalBook > Product Catalog >Chemical Reagents >Silane reagent >N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE

N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE

N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE Structure
CAS No.
7688-51-9
Chemical Name:
N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE
Synonyms
Einecs 231-699-2;Ditrimethylsilyl allylamine;Allylbis(trimethylsilyl)amine;N,N'-bis(trimethylsilyl)allylamine;N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE;Prop-2-en-1-ylbis(trimethylsilyl)amine;N-Allyl-N,N-bis(trimethylsilyl)amine 97%;2-ALLYL-1,1,1,3,3,3-HEXAMETHYLDISILAZAN&;N,N-bis(trimethylsilyl)prop-2-en-1-amine;N-allyl-1,1,1-trimethyl-N-(trimethylsilyl)silylamine
CBNumber:
CB4498643
Molecular Formula:
C9H23NSi2
Molecular Weight:
201.46
MOL File:
7688-51-9.mol
MSDS File:
SDS
Modify Date:
2023/4/23 13:52:06

N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE Properties

Boiling point 72 °C/15 mmHg (lit.)
Density 0.816 g/mL at 25 °C (lit.)
refractive index n20/D 1.440(lit.)
Flash point 109 °F
form liquid
Specific Gravity 0.817
Hydrolytic Sensitivity 8: reacts rapidly with moisture, water, protic solvents

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS07
Signal word  Warning
Hazard statements  H226-H315-H319-H335
Precautionary statements  P210-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  10-36/37/38
Safety Statements  16-26-36/37
RIDADR  UN 1993 3/PG 3
WGK Germany  3

N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE price More Price(1)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 578932 N-Allyl-N,N-bis(trimethylsilyl)amine 97% 7688-51-9 5G ₹8140.4 2022-06-14 Buy
Product number Packaging Price Buy
578932 5G ₹8140.4 Buy

N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE Chemical Properties,Uses,Production

Uses

N-Allyl-N,N-bis(trimethylsilyl)amine or N,N-bis(trimethylsilyl)prop-2-en-1-amine (AHMDS) can be used as a nucleophilic reagent to prepare:

  • Complex bicyclic scaffolds by reacting with aryl aldehydes via imine formation followed by efficient multicomponent reactions.
  • Dithiasuccinoyl (Dts) heterocycle by reacting with bisthiocarbamoyl chloride.
  • Allyl selenide by reacting with aryl selenium salt in the presence of a ruthenium catalyst; Allyl selenide is utilized as a key intermediate in organic synthesis.


AHMDS can also be used as a reagent in hydrosilylation and hydroboration reaction. It may be also used as an electrolyte additive.

N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE Preparation Products And Raw materials

Raw materials

Preparation Products

1,1,1-Trimethyl-N-2-propenyl-N-(trimethylsilyl)silanamine Allylbis(trimethylsilyl)amine α,α,α-Trimethyl-N-(2-propenyl)-N-(trimethylsilyl)silanamine Einecs 231-699-2 N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE N-allyl-1,1,1-trimethyl-N-(trimethylsilyl)silylamine 2-ALLYL-1,1,1,3,3,3-HEXAMETHYLDISILAZAN& N,N'-bis(trimethylsilyl)allylamine Prop-2-en-1-ylbis(trimethylsilyl)amine Silanamine, 1,1,1-trimethyl-N-2-propen-1-yl-N-(trimethylsilyl)- N-Allyl-N,N-bis(trimethylsilyl)amine 97% N,N-bis(trimethylsilyl)prop-2-en-1-amine N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silanamine Ditrimethylsilyl allylamine 7688-51-9 CH2CHCH2NHSiCH332 C9H23NSi2 Organometallic Reagents Organosilicon Others