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ChemicalBook > Product Catalogue >Chemical Reagents >Silane reagent >N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE

N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE

N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE Structure
  • ₹8140.4
  • Product name: N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE
  • CAS: 7688-51-9
  • MF: C9H23NSi2
  • MW: 201.46
  • EINECS:231-699-2
  • MDL Number:MFCD00545193
  • Synonyms:1,1,1-Trimethyl-N-2-propenyl-N-(trimethylsilyl)silanamine;Allylbis(trimethylsilyl)amine;α,α,α-Trimethyl-N-(2-propenyl)-N-(trimethylsilyl)silanamine;Einecs 231-699-2;N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE;N-allyl-1,1,1-trimethyl-N-(trimethylsilyl)silylamine ;2-ALLYL-1,1,1,3,3,3-HEXAMETHYLDISILAZAN&;N,N'-bis(trimethylsilyl)allylamine
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Selected condition:

Brand

  • Sigma-Aldrich(India)

Package

  • 5G
  • ManufacturerSigma-Aldrich(India)
  • Product number578932
  • Product descriptionN-Allyl-N,N-bis(trimethylsilyl)amine 97%
  • Packaging5G
  • Price₹8140.4
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 578932 N-Allyl-N,N-bis(trimethylsilyl)amine 97% 5G ₹8140.4 2022-06-14 Buy

Properties

Boiling point :72 °C/15 mmHg (lit.)
Density :0.816 g/mL at 25 °C (lit.)
refractive index :n20/D 1.440(lit.)
Flash point :109 °F
form :liquid
Specific Gravity :0.817
Hydrolytic Sensitivity :8: reacts rapidly with moisture, water, protic solvents

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

N-Allyl-N,N-bis(trimethylsilyl)amine or N,N-bis(trimethylsilyl)prop-2-en-1-amine (AHMDS) can be used as a nucleophilic reagent to prepare:
  • Complex bicyclic scaffolds by reacting with aryl aldehydes via imine formation followed by efficient multicomponent reactions.
  • Dithiasuccinoyl (Dts) heterocycle by reacting with bisthiocarbamoyl chloride.
  • Allyl selenide by reacting with aryl selenium salt in the presence of a ruthenium catalyst; Allyl selenide is utilized as a key intermediate in organic synthesis.


AHMDS can also be used as a reagent in hydrosilylation and hydroboration reaction. It may be also used as an electrolyte additive.

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