Tetraethyl orthocarbonate
![Tetraethyl orthocarbonate Structure](CAS/GIF/78-09-1.gif)
- CAS No.
- 78-09-1
- Chemical Name:
- Tetraethyl orthocarbonate
- Synonyms
- TETRAETHOXYMETHANE;ethyl orthocarbonate;Tetraethyl orthocarb;Four ethyl carbonate;Tetraethyl-2-carbonate;Ethane, 1,1‘,1‘‘,1‘‘‘-;triethoxymethoxy-ethane;TRIETHYL ORTHOCARBONATE;Tetraehtylorthocarbonate;Teraethyl orthocarbonate
- CBNumber:
- CB4702616
- Molecular Formula:
- C9H20O4
- Molecular Weight:
- 192.25
- MOL File:
- 78-09-1.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/7/26 17:49:17
Melting point | 222 °C |
---|---|
Boiling point | 159 °C (lit.) |
Density | 0.919 g/mL at 25 °C (lit.) |
refractive index |
n |
Flash point | 127 °F |
storage temp. | Inert atmosphere,Room Temperature |
solubility | soluble in Chloroform, Methanol |
form | clear liquid |
color | Colorless to Almost colorless |
Specific Gravity | 0.919 |
Water Solubility | Insoluble |
Sensitive | Moisture Sensitive |
BRN | 1747401 |
CAS DataBase Reference | 78-09-1(CAS DataBase Reference) |
NIST Chemistry Reference | Ethane, 1,1',1'',1'''-[methanetetrayltetrakis(oxy)]tetrakis-(78-09-1) |
EPA Substance Registry System | Ethane, 1,1',1'',1'''-[methanetetrayltetrakis(oxy)]tetrakis- (78-09-1) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() ![]() GHS02,GHS07 |
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Signal word | Warning | |||||||||
Hazard statements | H315-H319-H226 | |||||||||
Precautionary statements | P241-P280a-P303+P361+P353-P501a-P210-P233-P240-P241+P242+P243-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P370+P378-P403+P235-P501 | |||||||||
Hazard Codes | Xi,F | |||||||||
Risk Statements | 10-36/37/38 | |||||||||
Safety Statements | 37/39-26-16-36-24/25 | |||||||||
RIDADR | UN 3272 3/PG 3 | |||||||||
WGK Germany | 3 | |||||||||
F | 21 | |||||||||
HazardClass | 3 | |||||||||
PackingGroup | III | |||||||||
HS Code | 29209010 | |||||||||
NFPA 704 |
|
Tetraethyl orthocarbonate price More Price(4)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 163627 | Tetraethyl orthocarbonate 97% | 78-09-1 | 5G | ₹2608.83 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 163627 | Tetraethyl orthocarbonate 97% | 78-09-1 | 25G | ₹9959 | 2022-06-14 | Buy |
TCI Chemicals (India) | T1107 | Tetraethoxymethane min. 97.0 % | 78-09-1 | 5ML | ₹3400 | 2022-05-26 | Buy |
TCI Chemicals (India) | T1107 | Tetraethoxymethane min. 97.0 % | 78-09-1 | 25ML | ₹7800 | 2022-05-26 | Buy |
Tetraethyl orthocarbonate Chemical Properties,Uses,Production
Chemical Properties
clear colorless liquid
Uses
Tetraethyl Orthocarbonate is used in the synthesis of chemokine receptor-5 inhibitors against HIV-1, benzobisoxazoles and in the preparation of organic semiconductors. It is also employed in the synthesis of 2,7-dimethylene-1,4,6,9-tetraoxaspiro[4,4]nonane and in the synthesis of cross linked poly(orthocarbonate)s used as organic solvent absorbent.
Purification Methods
Likely impurities are hydrolysis products. Shake the orthocarbonate with brine (saturated NaCl, dilute with a little Et2O if amount of material is small) and dry (MgSO4). The organic layer is filtered off and evaporated, and the residue is distilled through a helices packed fractionating column with a total reflux partial take-off head. All distillations can be done at atmospheric pressure in an inert atmosphere (e.g. N2). [Roberts & McMahon Org Synth Coll Vol IV 457 1963, Connolly & Dyson J Chem Soc 828 1937, Tieckelmann & Post J Org Chem 13 266 1948, for review see Kantlehner et al. Justus Liebigs Ann Chem 507 207 1982, Beilstein 3 IV 6.]
Tetraethyl orthocarbonate Preparation Products And Raw materials
Raw materials
Preparation Products
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chevron_rightSupplier | Tel | Country | ProdList | Advantage | Inquiry |
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Dr Prem's Molecules Pvt. Ltd. | +91 9825310038 | New Delhi, India | 547 | 50 | Inquiry |
OCEAN TRADING CORPORATION | +91(22) 24921669 | New Delhi, India | 6211 | 58 | Inquiry |
CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6351 | 58 | Inquiry |
A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
Oceanic Pharmachem Pvt., Ltd. (OPPL) | 91-22-42128600 | Maharashtra, India | 947 | 58 | Inquiry |
Arham Enterprise | 07942547822 | Mumbai, India | 54 | 58 | Inquiry |
Shree Sadguru Enterprise | 08046076695 | Gujarat, India | 126 | 58 | Inquiry |
ENBRIDGE PHARMTECH CO., LTD. | +8613812269233 | China | 303 | 58 | Inquiry |
Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | China | 12456 | 58 | Inquiry |
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