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DICHLOROTRIPHENYLPHOSPHORANE

DICHLOROTRIPHENYLPHOSPHORANE Structure
CAS No.
2526-64-9
Chemical Name:
DICHLOROTRIPHENYLPHOSPHORANE
Synonyms
TRIPHENYLPHOSPHINE DICHLORIDE;Triphenyldichlorophosphorane;DICHLOROTRIPHENYLPHOSPHORANE;DICHLORO TRIPHENYL PHOSPHINE;Dichloride Triphenylphosphine;Triphenyldichlorophosphorus(V);Phosphorane,dichlorotriphenyl-;Dichlorotriphenylphosphorane 95%;dichloro(triphenyl)-λ5-phosphane;Dichlorotriphenyl-lambda5-phosphane
CBNumber:
CB5136171
Molecular Formula:
C18H15Cl2P
Molecular Weight:
333.19
MOL File:
2526-64-9.mol
MSDS File:
SDS
Modify Date:
2023/5/15 10:43:59

DICHLOROTRIPHENYLPHOSPHORANE Properties

Melting point 85 °C (dec.) (lit.)
Flash point 68 °F
solubility Chloroform (Soluble), Dichloromethane (Slightly)
form Solid
color White to Light Yellow
Water Solubility Reacts with water.
Sensitive Moisture Sensitive
Stability Extremely Moisture Sensitive, Hygroscopic

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS05,GHS08
Signal word  Danger
Hazard statements  H228-H314-H350
Precautionary statements  P210-P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  F,T
Risk Statements  45-11-34
Safety Statements  53-26-36/37/39-45-16
RIDADR  UN 2925 4.1/PG 2
WGK Germany  3
HazardClass  8
PackingGroup  II
NFPA 704
1
3 0

DICHLOROTRIPHENYLPHOSPHORANE price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 378755 Dichlorotriphenylphosphorane 95% 2526-64-9 25G ₹5044.45 2022-06-14 Buy
Sigma-Aldrich(India) 378755 Dichlorotriphenylphosphorane 95% 2526-64-9 100G ₹14732.83 2022-06-14 Buy
Product number Packaging Price Buy
378755 25G ₹5044.45 Buy
378755 100G ₹14732.83 Buy

DICHLOROTRIPHENYLPHOSPHORANE Chemical Properties,Uses,Production

Uses

Dichlorotriphenylphosphorane may be used in the synthesis of the following:

  • tertiary benzanilide derivatives
  • N-phosphodipeptides
  • dialkyl phosphorochloridites based on the reaction of trialkyl phosphites
  • naphthalene ring-based calix[3]amide, via reaction with 6-amino-2-naphthoic acid
  • C2v-symmetrical cyclic tetramers of aromatic amides

General Description

Dichlorotriphenylphosphorane (Triphenylphosphine dichloride, PPh3Cl2) is a phosphorous halide. Stability and reactivity of dichlorotriphenylphosphorane have been studied by solid state 31P NMR spectroscopy. It participates in the conversion of carboxylic esters to acid halides and mechanism of this cleavage has been investigated. Modified method has been proposed in which dichlorotriphenylphosphorane participates in the synthesis of tertiary amides.

DICHLOROTRIPHENYLPHOSPHORANE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 94)Suppliers
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ALS INDIA LIFE SCIENCES +91-8977036379 +91-8977036379 Hyderabad, India 1879 58 Inquiry
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DICHLOROTRIPHENYLPHOSPHORANE Spectrum

DICHLORO TRIPHENYL PHOSPHINE DICHLOROTRIPHENYLPHOSPHORANE Triphenyldichlorophosphorus(V) Dichlorotriphenylphosphorane,Triphenylphosphine dichloride Dichlorotriphenylphosphorane 95% dichloro(triphenyl)-λ5-phosphane Phosphorane,dichlorotriphenyl- ichloro(triphenyl)-λsup5sup-phosphane Dichloride Triphenylphosphine TRIPHENYLPHOSPHINE DICHLORIDE Triphenyldichlorophosphorane Dichlorotriphenyl-lambda5-phosphane dichloro(triphenyl)-λ5-phosphane 2526-64-9 C18H15Cl2P C6H53PCl2 Building Blocks Organic Building Blocks Phosphorus Compounds Phosphorus Halides Building Blocks Chemical Synthesis Organic Building Blocks Phosphorus Compounds Phosphorus Halides