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Perfluoroalkylethyl acrylate

Perfluoroalkylethyl acrylate Structure
CAS No.
65605-70-1
Chemical Name:
Perfluoroalkylethyl acrylate
Synonyms
Fandachem PFAEA;PFAEA from Fandachem;Fandachem-cas-65605-70_1;Perfluoroalkylethyl acrylate;Perfluoroalkyl Ethyl Acrylates;4,4,5-Trifluoropentyl acrylate;PFAEA (Perfluoroalkylethylacrylate);Perfluoroalkylethyl Acrylate Forfluo;1H,1H,2H,2H-Perfluoroalkyl-1-acrylate;1H,1H,2H,2H-Perfluoroalkyl-1-acrylates
CBNumber:
CB51457934
Molecular Formula:
C6H7F3O2
Molecular Weight:
168.1137896
MOL File:
65605-70-1.mol
Modify Date:
2024/7/26 15:15:06

Perfluoroalkylethyl acrylate Properties

InChI InChI=1S/C6H7F3O2/c1-2-5(10)11-4-3-6(7,8)9/h2H,1,3-4H2
InChIKey NWBWGFFZPIVONT-UHFFFAOYSA-N
SMILES C(OCCC(F)(F)F)(=O)C=C
EPA Substance Registry System Poly(difluoromethylene), .alpha.-fluoro-.omega.-[2-[(1-oxo-2-propen-1-yl)oxy]ethyl]- (2-Propeonic acid, perfluoro-C6-14-alkylethyl esters, C8 rich) (65605-70-1)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H319
Precautionary statements  P264-P280-P305+P351+P338-P337+P313P

Perfluoroalkylethyl acrylate Chemical Properties,Uses,Production

Description

Perfluoroalkylethyl acrylate is an important monomer for the synthesis of fluoropolymers, and is also a key step in the synthesis of fluorine-containing finishing agents.

Uses

Perfluoroalkylethyl acrylate is a polymer that can be used as an important monomer for the synthesis of fluoropolymers.

Synthesis

Using p-toluenesulfonic acid as catalyst, Perfluoroalkylethyl acrylate was synthesized.
Experimental procedure: Add polyfluoroalcohol, acrylic acid, and solvent to a dry four-necked flask equipped with a stirrer, reflux condenser, thermometer and water separator, and add p-toluenesulfonic acid after stirring evenly. The temperature is raised to reflux, and the reaction is carried out for a period of time until the water collected in the water separator reaches the theoretical amount. The solvent and excess acrylic acid were evaporated, and 5% (mass fraction) sodium bicarbonate solution was added dropwise to the cooled reaction solution until the pH was about 7-8. Filtration yielded a milky white solid. After vacuum drying, vacuum distillation was performed to collect Perfluoroalkylethyl acrylate at 82-134°C under 199.3Pa.

Perfluoroalkylethyl acrylate Preparation Products And Raw materials

Raw materials

Preparation Products

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Poly(difluoromethylene), α-fluoro-ω-[2- [(1-oxo-2-propenyl)oxy]ethyl]- Perfluoroalkylethyl acrylate Perfluoroalkyl Ethyl Acrylates Poly(difluoroMethylene),a-fluoro-w-[2-[(1-oxo-2-propen-1-yl)oxy]ethyl]- PFAEA (Perfluoroalkylethylacrylate) 1H,1H,2H,2H-Perfluoroalkyl-1-acrylates 2-(Perfluoroalkyl)Ethyl Acrylates, Mixture 1H,1H,2H,2H-Perfluoroalkyl-1-acrylate Perfluoroalkylethyl acrylate ISO 9001:2015 REACH Perfluoroalkylethyl Acrylate Forfluo High Quality Perfluoroalkyl Ethyl Acryl Ates CAS No. 65605-70-1 4,4,5-Trifluoropentyl acrylate Poly(difluoromethylene), α-fluoro-ω-[2-[(1-oxo-2-propen-1-yl)oxy]ethyl]- 2-Perfluoroethyl ethyl acrylate,mixture Perfluoroalkylethyl acrylate (Fandachem) PFAEA from Fandachem 2-(Perfluoroalkyl)Ethyl Acrylates (Fandachem) 2-Perfluoroethyl ethyl acrylate mixture (FandaChem) Fandachem Perfluoroalkylethyl acrylate Fandachem PFAEA Fandachem 2-(Perfluoroalkyl)Ethyl Acrylates Fandachem 2-Perfluoroethyl ethyl acrylate mixture PFAEA manufacturer supplier China Fandachem Fandachem-cas-65605-70_1 65605-70-1 C9H7F9O2C2F4n CF2multC5H7FO2 Polymers