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Methyl propiolate

Methyl propiolate Structure
CAS No.
922-67-8
Chemical Name:
Methyl propiolate
Synonyms
4-Methoxy-4-oxobut-2-ynoic acid;PROPYNOIC ACID, METHYL ESTER;HCequivCCOOCH3;METHYL PROPYNOATE;METHYL PROPIOLATE;Methyl propinoate;METHYPROPIOLATE,99%;Methyl propargylate;MethylPropiolate>Sucrose Impurity 14
CBNumber:
CB3155439
Molecular Formula:
C4H4O2
Molecular Weight:
84.07
MOL File:
922-67-8.mol
MSDS File:
SDS
Modify Date:
2024/7/29 18:03:56

Methyl propiolate Properties

Melting point 171-173 °C
Boiling point 103-105 °C (lit.)
Density 0.945 g/mL at 25 °C (lit.)
refractive index n20/D 1.408(lit.)
Flash point 50 °F
storage temp. Inert atmosphere,2-8°C
solubility Chloroform (Sparingly), Methanol (Sparingly)
form Liquid
Specific Gravity 0.9450
color Clear colorless
Water Solubility Not miscible in water.
BRN 605462
Stability Stable. Highly flammable. Incompatible with strong oxidizing agents, bases, acids.
InChIKey IMAKHNTVDGLIRY-UHFFFAOYSA-N
CAS DataBase Reference 922-67-8(CAS DataBase Reference)
NIST Chemistry Reference 2-Propynoic acid, methyl ester(922-67-8)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS07
Signal word  Danger
Hazard statements  H225-H315-H319-H335
Precautionary statements  P210-P233-P240-P241-P303+P361+P353-P305+P351+P338
Hazard Codes  F,Xi
Risk Statements  11-36/37/38-36
Safety Statements  26-36-36/37/39-23-16-33-7/9
RIDADR  UN 3272 3/PG 2
WGK Germany  3
RTECS  UE0050000
19
Hazard Note  Highly Flammable/Harmful
HazardClass  3
PackingGroup  II
HS Code  29161980
NFPA 704
3
2 0

Methyl propiolate price More Price(8)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 171859 Methyl propiolate 99% 922-67-8 2.5G ₹3150.08 2022-06-14 Buy
Sigma-Aldrich(India) 171859 Methyl propiolate 99% 922-67-8 10G ₹8270.3 2022-06-14 Buy
Sigma-Aldrich(India) 171859 Methyl propiolate 99% 922-67-8 50G ₹22093.83 2022-06-14 Buy
ALFA India ALF-A14743-22 Methyl propiolate, 99% 922-67-8 100g ₹31463 2022-05-26 Buy
ALFA India ALF-A14743-14 Methyl propiolate, 99% 922-67-8 25g ₹13518 2022-05-26 Buy
Product number Packaging Price Buy
171859 2.5G ₹3150.08 Buy
171859 10G ₹8270.3 Buy
171859 50G ₹22093.83 Buy
ALF-A14743-22 100g ₹31463 Buy
ALF-A14743-14 25g ₹13518 Buy

Methyl propiolate Chemical Properties,Uses,Production

Chemical Properties

colourless to light yellow liquid

Uses

Methyl propiolate was used in the synthesis of polysubstituted 3-arylaminoacrylate and tetrahydropyrimidin-2-one derivatives. It was also used as a thiol derivatizing agent for capillary electrophoresis.

Purification Methods

Purify the propiolate by fractional distillation and collecting the middle fraction, note that propiolic acid has a high b [144o(dec)/760mm]. [Beilstein 2 IV 1688.] LACHRYMATORY.

Global( 408)Suppliers
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